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US4011081A Expired / Lapsed US ⏱️ 0.0 years remaining

Direct-positive double exposure process utilizing a primitive, unfogged silver halide emulsion containing an electron acceptor

Assignee: Eastman Kodak Co
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Filing: 1975-03-03
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Granted: 1977-03-08
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Expires: 1995-03-03
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Abstract

Abstract Processes are disclosed for obtaining positive images in an unfogged, primitive, silver halide emulsion wherein a photographic element comprising a support and said emulsion are imagewise-exposed with a low-intensity light, given an over-all flash exposure with a high-intensity light and developed in a silver halide developer. In one aspect, the silver halide emulsions of this invention are primitive, unfogged, silver halide emulsions which comprise an electron acceptor.

Inventors

  • 👤 Paul B. Gilman
  • 👤 John V. Morgan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 04:53
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/485; G03C1/48538

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 229 words
A process for producing a direct-positive image in a silver halide photographic element comprising 1. imagewise exposing for at least 0.01 second at an intensity of at least 1 × 10.sup. -12 watt/cm 2 a photographic element comprising a support and coated theron at least one layer of a primitive, silver halide emulsion which contains 1 mg to 2 grams per mole of silver of an electron-accepting compound having a cathode halfwave potential more positive than -1.0 volt and an anodic halfwave potential more positive than +0.4 volt, said emulsion being derived from precipitation of an alkali metal halide and a water soluble silver salt in contact with a peptizer and in the absence of chemical or physical sensitizing conditions, the silver halide emulsion in the absence of exposure exhibiting a density of less than 0.3 when processed for 5 minutes at 27° C in a photographic developer having the following composition: ______________________________________ water 500.0 cc N-methyl-p-amino-phenol sulfate 2.0 g sodium sulfite 90.0 g hydroquinone 8.0 g sodium carbonate, monohydrated 52.5 g potassium bromide 5.0 g water to make 1.0 liter ______________________________________ 2. exposing said imagewise-exposed silver halide emulsion to an overall flash for less than 0.05 second at an intensity at least 10 times greater than the imagewise exposure and 3. developing said photographic element in silver halide surface-image developer which is substantially free of silver halide solvent.
Claim 2
Dependent Claim 229 words
A process for producing a direct-positive image in a silver halide photographic element comprising 1. imagewise exposing for at least 0.01 second at an intensity of at least 1 × 10.sup. -12 watt/cm 2 a photographic element comprising a support and coated theron at least one layer of a primitive, silver halide emulsion which contains 1 mg to 2 grams per mole of silver of an electron-accepting compound having a cathode halfwave potential more positive than -1.0 volt and an anodic halfwave potential more positive than +0.4 volt, said emulsion being derived from precipitation of an alkali metal halide and a water soluble silver salt in contact with a peptizer and in the absence of chemical or physical sensitizing conditions, the silver halide emulsion in the absence of exposure exhibiting a density of less than 0.3 when processed for 5 minutes at 27° C in a photographic developer having the following composition: ______________________________________ water 500.0 cc N-methyl-p-amino-phenol sulfate 2.0 g sodium sulfite 90.0 g hydroquinone 8.0 g sodium carbonate, monohydrated 52.5 g potassium bromide 5.0 g water to make 1.0 liter ______________________________________ 2. exposing said imagewise-exposed silver halide emulsion to an overall flash for less than 0.05 second at an intensity at least 10 times greater than the imagewise exposure and 3. developing said photographic element in silver halide surface-image developer which is substantially free of silver halide solvent.
Claim 3
Dependent Claim 14 words
A process according to claim 1 wherein said electron-accepting compound is a polymethine dye.
Claim 4
Dependent Claim 19 words
A process according to claim 1 wherein said image-wise exposure is a low-intensity exposure of 0.05 second or longer.
Claim 5
Dependent Claim 26 words
A process according to claim 1 wherein said electron-accepting compound is chosen from the class consisting of phenosafranine; 6,6',7,7'-tetrachloro-1,1',3,3'-tetraphenyl-1H-imidazo[4,5-b]quinoxalinocarbocyanine p-toluenesulfonate; 3,3'-diethyl-8,9-diaza thiocarbocyanine iodide; and 1,1',3,3'-tetraethyl-1H-imidazo[4,5-b]quinoxalinocarbocyanine chloride.

References Cited (Backward Citations)

US2263002A Cited
US3501307A Cited
US3761276A Cited
US3736140A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-07 1980-09-06 1981-03-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-07 1984-09-06 1985-03-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-07 1988-09-06 1989-03-08 $7700.00 Window Closed / Lapsed

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