Production of substitute natural gas from gasification of coal char

Claim 2

A process for the production of a gas comprising methane which comprises, in combination, the steps of a. gasifying a solid carbonaceous material at an elevated temperature in the presence of air and carbon dioxide to produce a raw process stream comprising carbon monoxide, carbon dioxide and nitrogen; b. cooling, cleaning and purifying said raw process stream to obtain a stream consisting essentially of carbon monoxide and nitrogen; c. separating carbon monoxide from said stream consisting essentially of carbon monoxide and nitrogen by contacting said stream in an absorption zone with an absorbent consisting essentially of an inert hydrocarbon diluent and at least one copper sulfonate, wherein said carbon monoxide is taken up in said absorbent, withdrawing from said absorption zone a stream consisting essentially of nitrogen and a stream consisting essentially of said absorbent and said carbon monoxide, passing said stream consisting essentially of absorbent and carbon monoxide to a desorption zone, separating in said desorption zone said carbon monoxide from said absorbent and withdrawing said carbon monoxide from said desorption zone; d. combining stream with said separated carbon monoxide and reacting the resulting CO/steam mixture in a catalytic methanation zone to produce an effluent gas stream consisting essentially of carbon dioxide, methane and hydrogen; and e. cooling said effluent gas stream and separating impurities therefrom to produce a product stream comprising methane.

Claim 3

The process of claim 1 wherein said copper sulfonate is the copper (I) salt of an organic sulfonic acid selected from the group consisting of: a. alkane sulfonic acids having from 4 to 6 carbon atoms per molecule, b. aromatic sulfonic acids having from 6 to 22 carbon atoms per molecule, and c. petroleum sulfonic acids.

Claim 4

The process of claim 2 wherein said salt is copper (I) dodecylbenzenesulfonate.

Claim 5

The process of claim 2 wherein said salt is copper (I) 2-ethylhexanesulfonate.

Claim 6

The process of claim 1 wherein said nitrogen is passed to an expansion motor wherein said nitrogen is adiabatically expanded to provide mechanical energy.

Claim 7

A process for the production of a gas comprising methane which comprises, in combination, the steps of a. gasifying a solid carbonaceous material at an elevated temperature in the presence of air and carbon dioxide to produce a raw process stream comprising carbon monoxide, carbon dioxide and nitrogen; b. cooling, cleaning and purifying said raw process stream to obtain a stream consisting essentially of carbon monoxide and nitrogen; c. separating carbon monoxide from said stream consisting essentially of carbon monoxide and nitrogen; d. combining steam with the separated carbon monoxide and reacting the resulting CO/steam mixture in a catalytic methanation zone by contacting said mixture with a methanation catalyst consisting essentially of nickel, a promoter selected from the group consisting of barium and uranium, and a calcium phosphate support having a Ca:P atomic ratio in the range of 1.4:1 to 2.3:1, wherein the components are present in approximate amounts as follows: ______________________________________ Calcium 5 to 35, Phosphorus 2 to 20, Nickel 10 to 50 and either Barium 1 to 20, or Uranium 2 to 40, ______________________________________ all said amounts expressed in terms of weight percent, based upon the weight of the total catalyst, thereby producing an effluent gas stream consisting essentially of carbon dioxide, methane and hydrogen; and e. cooling said effluent gas stream and separating impurities therefrom to produce a product stream comprising methane.

Claim 8

A process for the production of a gas comprising methane which comprises, in combination, the steps of a. gasifying a solid carbonaceous material at an elevated temperature in the presence of air and carbon dioxide to produce a raw process stream comprising carbon monoxide, carbon dioxide and nitrogen; b. cooling, cleaning and purifying said raw process stream to obtain a stream consisting essentially of carbon monoxide and nitrogen; c. separating carbon monoxide from said stream consisting essentially of carbon monoxide and nitrogen; d. combining steam with the separated carbon monoxide and reacting the resulting CO/steam mixture in a catalytic methanation zone by contacting said mixture with a methanation catalyst consisting essentially of nickel, a promoter selected from the group consisting of barium and uranium, and a calcium phosphate support having a Ca:P atomic ratio in the range of 1.4:1 to 2.3:1, wherein the components are present in approximate amounts as follows: ______________________________________ Calcium 5 to 35, Phosphorus 2 to 20, Nickel 10 to 50 and either Barium 1 to 20, or Uranium 2 to 40, ______________________________________ all said amounts expressed in terms of weight percent, based upon the weight of the total catalyst, thereby producing an effluent gas stream consisting essentially of carbon dioxide, methane and hydrogen; and e. cooling said effluent gas stream and separating impurities therefrom to produce a product stream comprising methane.

Claim 9

The process of claim 6 wherein said Ca:P ratio is in the range of 1.5:1 to 1.8:1.

Claim 10

The process of claim 6 wherein said Ca:P ratio is about 1.67:1.

Claim 11

The process of claim 6 wherein said components are present in the following approximate amounts: ______________________________________ Calcium 10 to 25, Phosphorus 5 to 15, Nickel 20 to 40, Barium 2.5 to 18 and Uranium 10 to 30. ______________________________________

Claim 12

The process of claim 6 wherein said catalyst promoter is barium.

Claim 13

The process of claim 6 wherein said catalyst promoter is uranium.

Claim 14

A process for the production of a gas comprising methane which comprises, in combination, the steps of a. gasifying a solid carbonaceous material at an elevated temperature in the presence of air and carbon dioxide to produce a raw process stream comprising carbon monoxide, carbon dioxide and nitrogen; b. cooling, cleaning and purifying said raw process stream to obtain a stream consisting essentially of carbon monoxide and nitrogen; c. separating carbon monoxide from said stream consisting essentially of carbon monoxide and nitrogen by contacting said stream in an absorption zone with an absorbent consisting essentially of an inert hydrocarbon diluent and at least one copper sulfonate, wherein said carbon monoxide is taken up in said absorbent, withdrawing from said absorption zone a stream consisting essentially of nitrogen and a stream consisting essentially of said absorbent and said carbon monoxide, passing said stream consisting essentially of absorbent and carbon monoxide to a desorption zone, separation in said desorption zone said carbon monoxide from said absorbent and withdrawing said carbon monoxide from said desorption zone; d. combining steam with the separated carbon monoxide and reacting the resulting CO/steam mixture in a catalytic methanation zone by contacting said mixture with a methanation catalyst consisting essentially of nickel, a promoter selected from the group consisting of barium and uranium, and a calcium phosphate support having a Ca:P atomic ratio in the range of 1.4:1 to 2.3:1, wherein the components are present in approximate amounts as follows: ______________________________________ Calcium 5 to 35, Phosphorus 2 to 20, Nickel 10 to 50, and either Barium 1 to 20, or Uranium 2 to 40, ______________________________________ all said amounts expressed in terms of weight percent, based upon the weight of the total catalyst, thereby producing an effluent gas stream consisting essentially of carbon dioxide, methane and hydrogen; and e. cooling said effluent gas stream and separating impurities therefrom to produce a product stream comprising methane.

Claim 15

A process for the production of a gas comprising methane which comprises, in combination, the steps of a. gasifying a solid carbonaceous material at an elevated temperature in the presence of air and carbon dioxide to produce a raw process stream comprising carbon monoxide, carbon dioxide and nitrogen; b. cooling, cleaning and purifying said raw process stream to obtain a stream consisting essentially of carbon monoxide and nitrogen; c. separating carbon monoxide from said stream consisting essentially of carbon monoxide and nitrogen by contacting said stream in an absorption zone with an absorbent consisting essentially of an inert hydrocarbon diluent and at least one copper sulfonate, wherein said carbon monoxide is taken up in said absorbent, withdrawing from said absorption zone a stream consisting essentially of nitrogen and a stream consisting essentially of said absorbent and said carbon monoxide, passing said stream consisting essentially of absorbent and carbon monoxide to a desorption zone, separation in said desorption zone said carbon monoxide from said absorbent and withdrawing said carbon monoxide from said desorption zone; d. combining steam with the separated carbon monoxide and reacting the resulting CO/steam mixture in a catalytic methanation zone by contacting said mixture with a methanation catalyst consisting essentially of nickel, a promoter selected from the group consisting of barium and uranium, and a calcium phosphate support having a Ca:P atomic ratio in the range of 1.4:1 to 2.3:1, wherein the components are present in approximate amounts as follows: ______________________________________ Calcium 5 to 35, Phosphorus 2 to 20, Nickel 10 to 50, and either Barium 1 to 20, or Uranium 2 to 40, ______________________________________ all said amounts expressed in terms of weight percent, based upon the weight of the total catalyst, thereby producing an effluent gas stream consisting essentially of carbon dioxide, methane and hydrogen; and e. cooling said effluent gas stream and separating impurities therefrom to produce a product stream comprising methane.

Claim 16

The process of claim 12 wherein said copper sulfonate is the copper (I) salt of organic sulfonic acid selected from the group consisting of: a. alkane sulfonic acid having from 4 to 6 carbon atoms per molecule, b. aromatic sulfonic acids having from 6 to 22 carbon atoms per molecule, and c. petroleum sulfonic acids.

Claim 17

The process of claim 13 wherein said salt is copper (I) dodecylbenzenesulfonate.

Claim 18

The process of claim 13 wherein said salt is copper (I) 2-ethylhexanesulfonate.

Claim 19

The process of claim 12 wherein said nitrogen is passed to an expansion motor wherein said nitrogen is adiabatically expanded to provide mechanical energy.

Claim 20

The process of claim 12 wherein said Ca:P ratio is in the range of 1.5:1 to 1.8:1.

Claim 21

The process of claim 12 wherein said Ca:P ratio is about 1.67:1.

Claim 22

The process of claim 12 wherein said components are present in the following approximate amounts: ______________________________________ Calcium 10 to 25, Phosphorus 5 to 15, Nickel 20 to 40, Barium 2.5 to 18, and Uranium 10 to 30. ______________________________________

Claim 23

The process of claim 12 wherein said catalyst promoter is barium.

Claim 24

The process of claim 12 wherein said catalyst promoter is uranium.