US4011013A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Multifrequency excitation of gas rotational spectra
Assignee: Honeywell International Inc
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Filing: 1975-04-21
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Granted: 1977-03-08
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Expires: 1995-04-21
Abstract
Abstract A method and apparatus for spectroscopic gas analysis are provided. Plural beams of monochromatic radiation are directed through gaseous material. A tuning mechanism adjusts the frequency difference between the radiation beams to equal substantially and odd integral submultiple of the frequency difference between adjacent spectral components of the periodic spectrum for a preselected constituent of the gaseous material. Radiation scattered by the gaseous material is received by a primary interferometric mechanism adapted to transmit selectively a detectable signal composed of the periodic spectrum. The signal is received by a detecting means which indicates the intensity thereof.
Inventors
- 👤 Joseph John Barrett
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 03:36
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/10; H01S3/106; H01S3/1062; G; G01; G01J; G01J3/00; G01J3/28; G01J3/44; G02; G02F; G02F1/00; G02F1/01; G02F1/21
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
265 words
An apparatus for spectroscopically analyzing gas comprising: a. radiation source means for generating a plurality of spatially superimposed beams of monochromatic radiation; b. tuning means for adjusting the frequency difference between radiation beams of adjacent frequency to equal substantially an odd integral submultiple of the frequency difference between adjacent spectral components of the periodic spectrum for a preselected constituent of gaseous material; c. projecting means for directing said radiation beams through said gaseous material to produce scattered radiation, the scattered radiation produced by each of said radiation beams having spectral components periodic in frequency and the spectral components for said preselected constituent being superimposed to form, within the spectrum produced by combined scattering of said radiation beams, the periodic spectrum for said preselected constituent; d. primary interferometric means adapted to receive said scattered radiation for selectively separating said periodic spectrum therefrom and transmitting said periodic spectrum in the form of a detectable signal, said primary interferometric means having interference-producing means for providing a plurality of transmission windows regularly spaced in frequency, the frequency spacing between adjacent windows being adjusted to equal substantially the frequency differences between radiation beams of adjacent frequency; and e. frequency shifting means associated with said tuning means for displacing the frequencies of said radiation beams relative to the frequencies of said transmission windows so that the frequency of a given radiation beam is located substantially half-way between adjacent transmission windows of said primary interferometric means, whereby said detectable signal is a fringe derived from the superimposed spectral lines of said periodic spectrum and having an intensity substantially equal to their sum.
Claim 2
Independent Claim
265 words
An apparatus for spectroscopically analyzing gas comprising: a. radiation source means for generating a plurality of spatially superimposed beams of monochromatic radiation; b. tuning means for adjusting the frequency difference between radiation beams of adjacent frequency to equal substantially an odd integral submultiple of the frequency difference between adjacent spectral components of the periodic spectrum for a preselected constituent of gaseous material; c. projecting means for directing said radiation beams through said gaseous material to produce scattered radiation, the scattered radiation produced by each of said radiation beams having spectral components periodic in frequency and the spectral components for said preselected constituent being superimposed to form, within the spectrum produced by combined scattering of said radiation beams, the periodic spectrum for said preselected constituent; d. primary interferometric means adapted to receive said scattered radiation for selectively separating said periodic spectrum therefrom and transmitting said periodic spectrum in the form of a detectable signal, said primary interferometric means having interference-producing means for providing a plurality of transmission windows regularly spaced in frequency, the frequency spacing between adjacent windows being adjusted to equal substantially the frequency differences between radiation beams of adjacent frequency; and e. frequency shifting means associated with said tuning means for displacing the frequencies of said radiation beams relative to the frequencies of said transmission windows so that the frequency of a given radiation beam is located substantially half-way between adjacent transmission windows of said primary interferometric means, whereby said detectable signal is a fringe derived from the superimposed spectral lines of said periodic spectrum and having an intensity substantially equal to their sum.
Claim 3
Dependent Claim
50 words
An apparatus as recited in claim 1, wherein said radiation source means comprises a dye laser including a dye cell containing a dye material means for exciting said dye and a laser cavity comprised of an optical element and a partially transmitting output mirror for generating and transmitting laser radiation.
Claim 4
Dependent Claim
28 words
An apparatus as recited in claim 2, wherein said dye material emits radiation upon being excited, said radiation having frequencies within the transparency range of said gaseous material.
Claim 5
Dependent Claim
17 words
An apparatus as recited in claim 1, including detecting means for indicating the intensity of said signal.
Claim 6
Dependent Claim
43 words
An apparatus as recited in claim 4, including modulating means for modulating the phase difference between interfering rays of said radiation so as to vary the intensity of said fringe, the modulating range being no greater than the frequency spacing between adjacent orders.
Claim 7
Dependent Claim
24 words
An apparatus as recited in claim 5, wherein said modulating means has a modulating range of about 1/2 the frequency width of said fringe.
Claim 8
Dependent Claim
26 words
An apparatus as recited in claim 5, wherein said modulating means is a piezoelectric cylinder and said snychronous detection means is a phase sensitive detection system.
Claim 9
Dependent Claim
40 words
An apparatus as recited in claim 1, wherein said radiation source means is provided with means for projecting radiation having a line width and frequency stability about equal to or less than the instrumental width of said primary interferometric means.
Claim 10
Dependent Claim
18 words
An apparatus as recited in claim 2, wherein said means for exciting said dye is a pulsed laser.
Claim 11
Dependent Claim
63 words
An apparatus as recited in claim 9, wherein said laser is associated with a time gated electronic detection system having (1) means for measuring the time interval required to send a pulse from said laser into a sample of said gaseous material and receive a return signal caused by light scattered therein and (2) means for measuring the amplitude of said return signal.
Claim 12
Dependent Claim
26 words
An apparatus as recited in claim 1, wherein said periodic spectrum is the spectrum produced by Raman scattering of a minor constituent of a gaseous material.
Claim 13
Dependent Claim
13 words
An apparatus as recited in claim 11, wherein said gaseous material is air.
Claim 14
Dependent Claim
30 words
An apparatus as recited in claim 2, wherein said radiation source means includes beam generating means for separating said radiation into a plurality of spatially superimposed beams of monochromatic radiation.
Claim 15
Dependent Claim
16 words
An apparatus as recited in claim 13, wherein said beam generating means is a Fabry-Perot interferometer.
Claim 16
Dependent Claim
38 words
An apparatus as recited in claim 13, wherein at least one of said beam generating means and said primary interferometric means is a solid etalon having temperature control means associated therewith for adjusting the optical path length thereof.
Claim 17
Dependent Claim
94 words
An apparatus as recited in claim 7 including means for applying to said cylinder a voltage having a square wave form, the limits of said voltage being adjusted so that the intensity of said fringe alternates between its maximum and minimum values, means for determining for each cycle of said voltage the difference in photon count between said maximum and minimum values of said modified fringe to produce a signal count, and means for accumulating said signal count for a preselected period of time over a preselected number of cycles of said square wave.
Claim 18
Dependent Claim
29 words
An apparatus as recited in claim 16 including means for varying the preselected time period and the preselected number of cycles inversely with the intensity of said modified fringe.
Claim 19
Dependent Claim
17 words
An apparatus as recited in claim 7 wherein said phase sensitive detection system is a lock-in amplifier.
Claim 20
Dependent Claim
25 words
An apparatus as recited in claim 5 wherein said modulating means is a piezoelectric cylinder and said synchronous detection means is a photon counting system.
Claim 21
Independent Claim
234 words
A method for spectroscopically analyzing gas comprising the steps of: a. generating a plurality of spatially superimposed beams of monochromatic radiation; b. adjusting the frequency difference between radiation beams of adjacent frequency to equal substantially an odd integral submultiple of the frequency difference between adjacent spectral components of the periodic spectrum for a preselected constituent of gaseous material; c. directing said radiation beams through said gaseous material to produce scattered radiation, the scattered radiation produced by each of said radiation beams having spectral components periodic in frequency and the spectral components for said preselected constituent being superimposed to form, within the spectrum produced by combined scattering of said radiation beams, the periodic spectrum for said preselected constituent; d. interferometrically separating said periodic spectrum from said scattered radiation by directing said scattered radiation through a plurality of transmission windows regularly spaced in frequency, the frequency spacing between adjacent windows being equal substantially to the frequency difference between radiation beams of adjacent frequency; e. displacing the frequencies of said radiation beams relative to the frequencies of said transmission windows so that the frequency of a given radiation beam is located substantially half-way between two given adjacent transmission windows; and f. transmitting said separated periodic spectrum in the form of a detectable signal, said signal being a fringe derived from said superimposed spectral lines of said periodic spectrum and having an intensity substantially equal to their sum.
Claim 22
Independent Claim
234 words
A method for spectroscopically analyzing gas comprising the steps of: a. generating a plurality of spatially superimposed beams of monochromatic radiation; b. adjusting the frequency difference between radiation beams of adjacent frequency to equal substantially an odd integral submultiple of the frequency difference between adjacent spectral components of the periodic spectrum for a preselected constituent of gaseous material; c. directing said radiation beams through said gaseous material to produce scattered radiation, the scattered radiation produced by each of said radiation beams having spectral components periodic in frequency and the spectral components for said preselected constituent being superimposed to form, within the spectrum produced by combined scattering of said radiation beams, the periodic spectrum for said preselected constituent; d. interferometrically separating said periodic spectrum from said scattered radiation by directing said scattered radiation through a plurality of transmission windows regularly spaced in frequency, the frequency spacing between adjacent windows being equal substantially to the frequency difference between radiation beams of adjacent frequency; e. displacing the frequencies of said radiation beams relative to the frequencies of said transmission windows so that the frequency of a given radiation beam is located substantially half-way between two given adjacent transmission windows; and f. transmitting said separated periodic spectrum in the form of a detectable signal, said signal being a fringe derived from said superimposed spectral lines of said periodic spectrum and having an intensity substantially equal to their sum.
References Cited (Backward Citations)
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1980-03-07 | 1980-09-06 | 1981-03-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-07 | 1984-09-06 | 1985-03-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-07 | 1988-09-06 | 1989-03-08 | $7700.00 | Window Closed / Lapsed |