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US4010211A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilization of polyether polyols

Assignee: Olin Corp
•
Filing: 1975-05-12
•
Granted: 1977-03-01
•
Expires: 1995-05-12
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Abstract

Abstract Polyether polyols and polyurethane foams are stabilized by the inclusion therein of a mixture of 2,6-di-tertiarybutyl-4-methyl phenol, a disubstituted diphenyl amine, and a select phenothiazine compound.

Inventors

  • 👤 Frank J. Preston
  • 👤 Peter P. Priga

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 23:51
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/17; C08K5/18; C08K5/04; C08K5/13; C08K5/36; C08K5/45; C08K5/46

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 143 words
In a polyether polyol composition which is stabilized against degradation by the inclusion therein of about 500-10,000 parts per million by weight of a mixture of (1) about 15-75 percent by weight of 2,6-di-tertiarybutyl-4-methyl phenol and (2) correspondingly about 85-25 percent by weight of p,p'-dioctyl diphenyl amine, said polyether polyol having a molecular weight of about 250-8,000 and being the product of reacting a polyhydric alcohol having 2-8 hydroxy groups with an alkylene oxide having a 1,2-epoxide ring and selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide and a mixture thereof, the improvement of including in said composition, as a partial replacement for said 2,6-di-tertiarybutyl-4-methyl phenol, about 25-600 parts, per million parts by weight of said polyether polyol, of a phenothiazine compound represented by the formula: ##STR2##in which each R is independently hydrogen or alkyl of 1-12 carbon atoms.
Claim 2
Dependent Claim 143 words
In a polyether polyol composition which is stabilized against degradation by the inclusion therein of about 500-10,000 parts per million by weight of a mixture of (1) about 15-75 percent by weight of 2,6-di-tertiarybutyl-4-methyl phenol and (2) correspondingly about 85-25 percent by weight of p,p'-dioctyl diphenyl amine, said polyether polyol having a molecular weight of about 250-8,000 and being the product of reacting a polyhydric alcohol having 2-8 hydroxy groups with an alkylene oxide having a 1,2-epoxide ring and selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide and a mixture thereof, the improvement of including in said composition, as a partial replacement for said 2,6-di-tertiarybutyl-4-methyl phenol, about 25-600 parts, per million parts by weight of said polyether polyol, of a phenothiazine compound represented by the formula: ##STR2##in which each R is independently hydrogen or alkyl of 1-12 carbon atoms.
Claim 3
Dependent Claim 29 words
The composition of claim 1 wherein said phenothiazine compound is selected from the group consisting of phenothiazine, 2-methylphenothiazine; 3-octylphenothiazine; 2,8-dimethylphenothiazine; 3,7-dimethylphenothiazine; 3,7-diethylphenothiazine; 3,7-dibutylphenothiazine; 3,7-dioctylphenothiazine; 2,8-dioctylphenothiazine and a mixture thereof.
Claim 4
Dependent Claim 15 words
The composition of claim 1 wherein phenothiazine or 3,7-dioctylphenothiazine is employed as the phenothiazine compound.
Claim 5
Dependent Claim 20 words
The composition of claim 2 wherein said polyhydric alcohol is an aliphatic diol, an aliphatic triol or a mixture thereof.
Claim 6
Dependent Claim 51 words
A composition as claimed in claim 4 which comprises, per every million parts by weight of said polyether polyol, (1) about 600-2,500 parts by weight of said 2,6-di-tertiarybutyl-4-methyl phenol, (2) about 400-1,800 parts by weight of said p,p'-dioctyl diphenyl amine, and (3) about 25-600 parts by weight of said phenothiazine compound.
Claim 7
Dependent Claim 11 words
The composition of claim 5 wherein said phenothiazine compound is 3,7-dioctylphenothiazine.

References Cited (Backward Citations)

US2786080A Cited
US3214397A Cited
US3437694A Cited
US3494880A Cited
US3468842A Cited
US3567664A Cited
US3637865A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-02-29 1980-08-30 1981-03-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-02-29 1984-08-30 1985-03-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-02-29 1988-08-30 1989-03-01 $7700.00 Window Closed / Lapsed

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