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US4009318A Expired / Lapsed US ⏱️ 0.0 years remaining

Laminated glass body with opal phase produced between laminae

Assignee: Corning Glass Works
•
Filing: 1974-11-15
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Granted: 1977-02-22
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Expires: 1994-11-15
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Abstract

Abstract The instant invention relates to the production of composite glass articles involving the bringing together of two or more glasses, while in the molten state, into an integral unit. More particularly, the present invention is concerned with the manufacture of such articles wherein a reaction occurs at the interface between the laminae of molten glass such that an opal phase is spontaneously produced in situ thereat.

Inventors

  • 👤 Thomas H. Elmer
  • 👤 Arthur E. Hillman
  • 👤 Karl E. Hoekstra
  • 👤 Robert G. Howell
  • 👤 Herbert E. Rauscher
  • 👤 Charles C. Smith, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 18:10
CPC Classifications
C; C03; C03C; C03C4/00; C03C4/005; C03C17/00; C03C17/02; C03C21/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31536

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 364 words
A laminated glass article consisting of a base glass lamina and a lamina selected from the group consisting of a source glass lamina and a sink glass lamina with an in situ layer of opalization at the interface between said laminae, said base glass being selected from the group of composition fields, expressed in weight percent on the oxide basis: a. 2.5-25% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 2.5- 45% RO, wherein RO consists of CaO, SrO, and BaO and 50- 85% SiO.sub. 2, the sum of alkali metal oxide + RO + SiO.sub. 2 constituting at least 80% of the total composition; b. 5-70% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 5-55% TiO.sub. 2, and 20-70% SiO.sub. 2, the sum of alkali metal oxide + TiO.sub. 2 + SiO.sub. 2 constituting at least 50% of the total composition; c. 30-60% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 10-30% Al 2 O 3 , and 25-45% SiO.sub. 2, the sum of alkali metal oxide + Al.sub. 2 0 3 + SiO.sub. 2 constituting at least 80% of the total composition; c. 3-15% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 30% B 2 O 3 , 55-80% SiO.sub. 2, and 1-15% F, the sum of alkali metal oxide + B 2 O 3 + SiO.sub. 2 + F constituting at least 80% of the total composition; and e. 5-25% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 3-45% RO, wherein RO consists of MgO, CaO, SrO, and BaO, 45-85% SiO.sub. 2, and 0.5-5% F, the sum of alkali metal oxide + RO + SiO.sub. 2 + F constituting at least 80% of the total composition; said source glass being a lithium silicate composition containing at least 1% Li 2 O, and said sink glass being an alkali metal-free silicate composition.
Claim 2
Dependent Claim 364 words
A laminated glass article consisting of a base glass lamina and a lamina selected from the group consisting of a source glass lamina and a sink glass lamina with an in situ layer of opalization at the interface between said laminae, said base glass being selected from the group of composition fields, expressed in weight percent on the oxide basis: a. 2.5-25% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 2.5- 45% RO, wherein RO consists of CaO, SrO, and BaO and 50- 85% SiO.sub. 2, the sum of alkali metal oxide + RO + SiO.sub. 2 constituting at least 80% of the total composition; b. 5-70% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 5-55% TiO.sub. 2, and 20-70% SiO.sub. 2, the sum of alkali metal oxide + TiO.sub. 2 + SiO.sub. 2 constituting at least 50% of the total composition; c. 30-60% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 10-30% Al 2 O 3 , and 25-45% SiO.sub. 2, the sum of alkali metal oxide + Al.sub. 2 0 3 + SiO.sub. 2 constituting at least 80% of the total composition; c. 3-15% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 30% B 2 O 3 , 55-80% SiO.sub. 2, and 1-15% F, the sum of alkali metal oxide + B 2 O 3 + SiO.sub. 2 + F constituting at least 80% of the total composition; and e. 5-25% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 3-45% RO, wherein RO consists of MgO, CaO, SrO, and BaO, 45-85% SiO.sub. 2, and 0.5-5% F, the sum of alkali metal oxide + RO + SiO.sub. 2 + F constituting at least 80% of the total composition; said source glass being a lithium silicate composition containing at least 1% Li 2 O, and said sink glass being an alkali metal-free silicate composition.
Claim 3
Dependent Claim 44 words
A laminated glass article according to claim 1 (a) wherein said base glass consists essentially of about 5-20% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 2.5-25% CaO, and 60-85% SiO.sub. 2.
Claim 4
Dependent Claim 44 words
A laminated glass article according to claim 1 (a) wherein said base glass consists essentially of about 2.5-25% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 2.5-35% SrO, and 55-85% SiO.sub. 2.
Claim 5
Dependent Claim 44 words
A laminated glass article according to claim 1 (a) wherein said base glass consists essentially of about 2.5-25% of at least one alkali metal oxide selected from the group consisting of Na 2 O and K 2 O, 2.5-45% BaO, and 50-85% SiO.sub. 2.
Claim 6
Dependent Claim 38 words
A laminated glass article according to claim 1 (a) wherein said base glass contains up to 20% total of Al.sub. 2 O 3 , B 2 O 3 , CdO, P 2 O 5 , PbO, and ZnO.
Claim 7
Dependent Claim 28 words
A laminated glass article according to claim 1 (b) wherein said base glass consists essentially of about 5-45% Na 2 O, 25-55% TiO.sub. 2, and 15-70% SiO.sub. 2.
Claim 8
Dependent Claim 28 words
A laminated glass article according to claim 1 (b) wherein said base glass consists essentially of about 10-60% K 2 O, 15-50% TiO.sub. 2, and 15-70% SiO.sub. 2.
Claim 9
Dependent Claim 63 words
A laminated glass article according to claim 1 (b) containing up to 50% total of the following ingredients in the indicated proportion: up to 50% B 2 0 3 ; up to 35% Al.sub. 2 O 3 , BaO, CaO, PbO, and SrO; up to 30% P 2 O 5 and GeO.sub. 2 ; up to 15% ZnO; and up to 10% MgO.
Claim 10
Dependent Claim 44 words
A laminated glass article according to claim 1 (a) wherein said base glass is selected from the composition field alkali metal oxide, RO, and SiO.sub. 2, the source glass is a lithium silicate composition, and said opalization consists essentially of a liquid-liquid phase separation.
Claim 11
Dependent Claim 55 words
A laminated glass article according to claim 1 (a) wherein said base glass is selected from the composition field alkali metal oxide, RO, and SiO.sub. 2, the sink glass is an alkali metalfree silicate composition, and said opalization consists essentially of at least one of the following crystal phases, cristobalite and alkaline earth metal silicates.
Claim 12
Dependent Claim 56 words
A laminated glass article according to claim 1 (b) wherein said base glass is selected from the composition field alkali metal oxide, TiO.sub. 2, and SiO.sub. 2, the source glass is a lithium silicate glass, and said opalization consists essentially of at least one of the following crystal phases, cristobalite, sodium-aluminum-silicate, potassium-aluminum-silicate, rutile, anatase, and mullite.
Claim 13
Dependent Claim 57 words
A laminated glass article according to claim 1 (c) wherein said base glass is selected from the composition field alkali metal oxide, Al.sub. 2 O 3 , and SiO.sub. 2, the source glass is a lithium silicate glass, and said opalization consists esentially of at least one of the following crystal phases, cristobalite, sodium-aluminum-silicate, potassium-aluminum-silicate, and mullite.
Claim 14
Dependent Claim 48 words
A laminated glass article according to claim 1 (d) wherein said base glass is selected from the composition field alkali metal oxide, B 2 O 3 , SiO.sub. 2, and F, the source glass is a lithium silicate glass, and said opalization consists essentially of lithium fluoride crystals.
Claim 15
Dependent Claim 44 words
A laminated glass article according to claim 1 (e) wherein said base glass is selected from the composition field alkali metal oxide, RO, SiO.sub. 2, and F, the source glass is a lithium silicate glass, and said opalization consists essentially of lithium fluoride crystals.

References Cited (Backward Citations)

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US3504819A Cited
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US3597305A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-02-22 1980-08-23 1981-02-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-02-22 1984-08-23 1985-02-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-02-22 1988-08-23 1989-02-22 $7700.00 Window Closed / Lapsed

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