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US4008267A Expired / Lapsed US ⏱️ 0.0 years remaining

3,3'-Di(sulfonyloxy-group-containing)substituted benzidine derivatives

Assignee: Phadia AB
•
Filing: 1974-10-16
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Granted: 1977-02-15
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Expires: 1994-10-16
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Abstract

Abstract Disclosed are benzidine derivatives substituted in each of the 3,3'-positions by the substituent ##STR1## wherein W is hydrogen or an alkali metal, the subscript n is zero when A is the divalent branched chain alkylene having from 2 to about 7 carbon atoms, and n is one when A is straight chain divalent alkylene with 3 or 4 carbons. Also disclosed are the corresponding derivatives wherein the sulfonyl group is replaced by the carbonyl group. Further disclosed are chromogen-reactive indicator compositions having as their chromogen constituent one of the foregoing benzidine derivatives. These compositions (1) are useful to test for a substance for which there exists a specific oxygen-oxidoreductase, such as a sugar, an amino acid, uric acid, and the like, and thus (2) contain also a peroxidase, a hydrogen-peroxide-oxidoreductase, and a specific oxygen-oxidoreductase for the specific material in the testing of which the composition is to be used.

Inventors

  • 👤 Nils Ake Jonsson
  • 👤 Ferenc Merenyl
  • 👤 Lars-Erik Westlund

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 01:11
CPC Classifications
C; C07; C07D; C07D223/00; C07D223/14; C07D223/16; C12; C12Q; C12Q1/00; C12Q1/26; C12Q1/28; C12Q2326/00; C12Q2326/10

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 54 words
A 3,3'-disubstituted benzidine derivative having the general formula ##STR10## wherein (i) W is hydrogen or an alkali metal, and (ii) the subscript n is zero or one and zero when A is a divalent alkylene chain from 2 to about 7 carbons, and n is one when A is straight chain trimethylene or tetramethylene.
Claim 2
Dependent Claim 54 words
A 3,3'-disubstituted benzidine derivative having the general formula ##STR10## wherein (i) W is hydrogen or an alkali metal, and (ii) the subscript n is zero or one and zero when A is a divalent alkylene chain from 2 to about 7 carbons, and n is one when A is straight chain trimethylene or tetramethylene.
Claim 3
Dependent Claim 12 words
The 3,3'-disubstituted derivative as claimed in claim 1, wherein n is one.
Claim 4
Dependent Claim 12 words
The 3,3'-disubstituted derivative as claimed in claim 2, wherein W is hydrogen.
Claim 5
Dependent Claim 14 words
The 3,3'-disubstituted derivative as claimed in claim 2, wherein A is straight chain trimethylene.
Claim 6
Dependent Claim 13 words
The 3,3'-disubstituted derivative as claimed in claim 4, which is gamma,gamma'-(4,4'-diamino-3,3'-biphenyldioxy)dipropane sulfonic acid.
Claim 7
Dependent Claim 14 words
The 3,3'-disubstituted derivative as claimed in claim 2, wherein A is straight chain tetramethylene.
Claim 8
Dependent Claim 13 words
The 3,3'-disubstituted derivative as claimed in claim 6, which is delta,delta'-(4,4'-diamino-3,3'-biphenyldioxy)dibutane sulfonic acid.
Claim 9
Dependent Claim 12 words
The 3,3'-disubstituted derivative as claimed in claim 1, wherein n is zero.
Claim 10
Dependent Claim 13 words
The 3,3'-disubstituted derivative as claimed in claim 8, which is beta,beta'-(4,4'-diamino-3,3'-biphenyl)-diethane sulfonic acid.
Claim 11
Dependent Claim 13 words
An alkali metal salt of the 3,3'-disubstituted derivative as claimed in claim 1.
Claim 12
Dependent Claim 14 words
The sodium or potassium salt of the 3,3'-disubstituted derivative as claimed in claim 1.
Claim 13
Dependent Claim 3 words
Disodium beta,beta'-(4,4'-diamino-3,3'-biphenyl)diethane sulfonate.
Claim 14
Dependent Claim 3 words
Disodium beta,beta'-(4,4'-diamino-3,3'-biphenyl)diethane sulfonate.

References Cited (Backward Citations)

US3506580A Cited
US3496225A Cited
GB1313267A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-02-15 1980-08-16 1981-02-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-02-15 1984-08-16 1985-02-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-02-15 1988-08-16 1989-02-15 $7700.00 Window Closed / Lapsed

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