US4008199A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Heat stabilized polyalkylene terephthalate resin composition
Assignee: Celanese Corp
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Filing: 1975-06-09
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Granted: 1977-02-15
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Expires: 1995-06-09
Abstract
Abstract The long term heat stabilized polyalkylene terephthalate resin composition comprises a polyalkylene terephthalate resin selected from the group consisting of polypropylene terephthalate and polybutylene terephthalate, 2 to 60 percent of the total composition of a reinforcing filler and stabilizing amounts of the combination of polyamide polymer, phenoxy resin and an organic phosphonate. The composition retains a higher degree of tensile strength after high temperature long-term aging than does any polyalkylene terephthalate composition of the prior art.
Inventors
- 👤 John S. Gall
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 22:42
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K5/51; C08K5/53; C08K5/5317; C08K5/5333; C08L; C08L67/00; C08L67/02; C08L71/00; C08L77/00
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
273 words
In a molding resin comprising a reinforcing filler and a polyalkylene terephthalate selected from the group consisting of the polymer reaction product of 1,3-propanediol and terephthalic acid or dimethyl terephthalate and the polymer reaction product of 1,4-butanediol and terephthalic acid or dimethyl terephthalate, said polyalkylene terephthalate having an intrinsic viscosity in the range of about 0.4 to about 1.2 deciliters per gram, as measured in an 8 weight percent solution, based on the polymer weight, of orthochlorophenol at 25° C.; the improvement comprising an intimate blend of said molding resin and the combination of stabilizing amounts of additives of each of a. a linear polyamide polymer having a relative viscosity in the range from 35 to 100 b. a thermoplastic phenoxy resin having a repeating structure: ##STR3## and an average molecular weight in a range from about 15,000 to about 75,000 c. an organic phosphonate of the formula: ##STR4## wherein n is 0 or 1 and a. when n is 1, each of R and R 1 is alkyl having from 12 to 24 carbon atoms and each of R 2 and R 3 is alkyl having from 1 to 6 carbon atoms, and R 4 is hydrogen; and b. when n is 0, R 2 , oh and R 3 are fixed, respectively, in the 3, 4 and 5 positions of the benzene ring portion of the benzylphosphonate; each of R and R 1 is alkyl of 14 to 30 carbon atoms, R 2 is alkyl of from 1 to 6 carbon atoms, R 3 is tertiary-butyl, and R 4 is a member selected from the group consisting of hydrogen and methyl.
Claim 2
Dependent Claim
273 words
In a molding resin comprising a reinforcing filler and a polyalkylene terephthalate selected from the group consisting of the polymer reaction product of 1,3-propanediol and terephthalic acid or dimethyl terephthalate and the polymer reaction product of 1,4-butanediol and terephthalic acid or dimethyl terephthalate, said polyalkylene terephthalate having an intrinsic viscosity in the range of about 0.4 to about 1.2 deciliters per gram, as measured in an 8 weight percent solution, based on the polymer weight, of orthochlorophenol at 25° C.; the improvement comprising an intimate blend of said molding resin and the combination of stabilizing amounts of additives of each of a. a linear polyamide polymer having a relative viscosity in the range from 35 to 100 b. a thermoplastic phenoxy resin having a repeating structure: ##STR3## and an average molecular weight in a range from about 15,000 to about 75,000 c. an organic phosphonate of the formula: ##STR4## wherein n is 0 or 1 and a. when n is 1, each of R and R 1 is alkyl having from 12 to 24 carbon atoms and each of R 2 and R 3 is alkyl having from 1 to 6 carbon atoms, and R 4 is hydrogen; and b. when n is 0, R 2 , oh and R 3 are fixed, respectively, in the 3, 4 and 5 positions of the benzene ring portion of the benzylphosphonate; each of R and R 1 is alkyl of 14 to 30 carbon atoms, R 2 is alkyl of from 1 to 6 carbon atoms, R 3 is tertiary-butyl, and R 4 is a member selected from the group consisting of hydrogen and methyl.
Claim 3
Dependent Claim
22 words
The composition of claim 1 wherein the polyalkylene terephthalate is the polymer reaction product of 1,4-butanediol and terephthalic acid or dimethyl terephthalate.
Claim 4
Dependent Claim
47 words
The composition of claim 2 wherein each of the combination of stabilizing amounts of additives range from about 0.01 to about 10 weight percent of the total molding compositions and the reinforcing filler ranges from about 2 to about 60 weight percent of the total molding composition.
Claim 5
Dependent Claim
51 words
The composition of claim 3 wherein each of the combination of stabilizing amounts of additives range from about 0.1 to about 2 weight percent of the total molding compositions, the reinforcing filler is glass fibers and the intrinsic viscosity of the polyalkylene terephthalate ranges from 0.5 to 1.0 deciliters per gram.
Claim 6
Dependent Claim
27 words
The composition of claim 4 wherein the linear polyamide polymer is polycarprolactam (nylon 6) having a relative viscosity in the range from about 45 to about 65.
Claim 7
Dependent Claim
21 words
The composition of claim 5 wherein the phenoxy resin has an average molecular weight ranging from about 20,000 to about 50,000.
Claim 8
Dependent Claim
12 words
The composition of claim 6 wherein the organic phosphonate is di-n-octadecyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-02-15 | 1980-08-16 | 1981-02-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-02-15 | 1984-08-16 | 1985-02-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-02-15 | 1988-08-16 | 1989-02-15 | $7700.00 | Window Closed / Lapsed |