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US4007130A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst regeneration method

Assignee: BP Chemicals Ltd
•
Filing: 1975-12-29
•
Granted: 1977-02-08
•
Expires: 1995-12-29
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Abstract

Abstract A method for treating catalyst solution comprising the complex reaction product formed on mixing of a rhodium component or an iridium component and a halogen component in the presence of carbon monoxide to remove metallic corrosion products and recover rhodium or iridium and halogen values therefrom.

Inventors

  • 👤 Harry S. Leach
  • 👤 Thomas C. Singleton
  • 👤 Yu Wen Wei

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 19:08
CPC Classifications
B; B01; B01J; B01J31/00; B01J31/16; B01J31/20; B01J23/00; B01J23/90; B01J23/96; B01J31/40; B01J31/4015; B01J31/4023; B01J31/4038; B01J31/4046; B01J2231/00; B01J2231/30; B01J2231/34; B01J2531/00; B01J2531/02; B01J2531/0202; B01J2531/0208; B01J2531/0211; B01J2531/80; B01J2531/82; B01J2531/822; B01J2531/827; B01J31/02; B01J31/06; B01J31/08; B01J31/10

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 61 words
A process for the regeneration of a spent catalyst solution comprising the complex reaction product formed from a rhodium or iridium component, an iodine component and carbon monoxide and containing metallic corrosion products which comprises intimately contacting said spent catalyst solution with a cation exchange resin in its hydrogen form and recovering said catalyst solution free of said metallic corrosion products.
Claim 2
Dependent Claim 61 words
A process for the regeneration of a spent catalyst solution comprising the complex reaction product formed from a rhodium or iridium component, an iodine component and carbon monoxide and containing metallic corrosion products which comprises intimately contacting said spent catalyst solution with a cation exchange resin in its hydrogen form and recovering said catalyst solution free of said metallic corrosion products.
Claim 3
Dependent Claim 22 words
The process of claim 1 wherein said complex reaction product is formed from a rhodium component, an iodine component and carbon monoxide.
Claim 4
Dependent Claim 14 words
The process of claim 2 wherein said resin is a strong-acid cation exchange resin.
Claim 5
Dependent Claim 20 words
The process of claim 3 wherein said contacting is effected at a temperature from about 0° to about 120° C.
Claim 6
Dependent Claim 23 words
The process of claim 4 wherein said contacting is effected by passing the spent catalyst solution through a fixed-bed column of said resin.
Claim 7
Dependent Claim 29 words
The process of claim 5 wherein the rate of flow of said catalyst solution through said resin bed is from about one to about 20 bed volumes per hour.
Claim 8
Dependent Claim 19 words
The process of claim 6 wherein said resin has been regenerated after exhaustion by washing with a mineral acid.
Claim 9
Dependent Claim 11 words
The process of claim 7 wherein said acid is hydriodic acid.
Claim 10
Dependent Claim 14 words
The process of claim 8 wherein the concentration of hydriodic acid is about 20%.

References Cited (Backward Citations)

US3197416A Cited
US3192151A Cited
US3887489A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-02-08 1980-08-09 1981-02-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-02-08 1984-08-09 1985-02-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-02-08 1988-08-09 1989-02-08 $7700.00 Window Closed / Lapsed

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