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US4005083A
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Metal complexes of azolyl ethers
Assignee: Bayer AG
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Filing: 1975-04-30
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Granted: 1977-01-25
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Expires: 1995-04-30
Abstract
Abstract Metal complexes of azolyl ethers of the formula <IMAGE> (I) in which M is a metal, X is halogen, nitro, nitrile, optionally substituted alkyl, optionally substituted aryl, cycloalkyl, amino, carboxyl, alkoxycarbonyl, alkylcarbonyloxy, alkoxy, alkylthio, halogenoalkoxy, halogenoalkylthio, aryloxy, arylcarbonyloxy, benzoyl, halogenobenzoyl, alkylcarbonylamino, dialkylamino, alkylsulfonyl, alkylsulfonyloxy, arylsulfonyl or arylsulfonyloxy, Az is an imidazolyl radical, a 1,2,4-triazolyl-(1) radical or a 1,2,4-triazolyl-(4) radical, B is CO or CH(OH), R is alkyl or optionally substituted aryl, A is an anion of an inorganic acid, A IS AN INTEGER FROM 0 TO 5, N IS 0 OR 1, M IS AN INTEGER FROM 1 TO 4, P IS AN INTEGER FROM 1 TO 6, AND K IS AN INTEGER FROM 0 TO 12, WHICH POSSESS FUNGICIDAL, BACTERICIDAL AND PLANT GROWTH-REGULATING PROPERTIES.
Inventors
- 👤 Karl Heinz Buchel
- 👤 Wolfgang Kramer
- 👤 Helmut Kaspers
- 👤 Hans Scheinpflug
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 08:46
CPC Classifications
C; C07; C07D; C07D231/00; C07D231/02; C07D231/10; C07D231/12; C07D233/00; C07D233/54; C07D233/56; C07D249/00; C07D249/02; C07D249/08
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
237 words
A metal complex of an azolyl ether of the formula ##STR164##in which M is copper, zinc, manganese, magnesium, tin iron or nickel, X is halogen, nitro, nitrile, amino, alkyl or cycloalkyl with in either case up to 6 carbon atoms, halogenoalkyl with 1 or 2 carbon atoms and up to 5 halogen atoms, hydroxymethyl, phenyl, halogenophenyl, phenyl-substituted phenyl, carboxyl, alkoxycarbonyl or alkylcarbonyloxy with in either case a total of up to 5 carbon atoms, alkoxy or alkylthio with in either case 1 or 2 carbon atoms, halogenoalkoxy or halogenoalkylthio with in either case 1 to 2 carbon atoms and up to 5 halogen atoms, phenoxy, benzoyloxy, chlorophenoxy, chlorobenzoyloxy, benzoyl, chlorobenzoyl, dialkylamino with a total of up to 6 carbon atoms, alkylcarbonyl amino with a total of up to 4 carbon atoms, alkylsulfonyl or alkylsulfonyloxy with in either case 1 or 2 carbon atoms, phenylsulfonyl and phenylsulfonyloxy, Az is an imidazolyl radical, a 1,2,4-triazolyl-(1) radical or a 1,2,4-triazolyl-(4) radical, B is CO or CH(OH), R is alkyl with up to 6 carbon atoms or optionally phenyl substituted in o- or p-position with halogen, nitro, nitrile or methyl, A is a chloride, bromide, iodide, nitrate, sulfate or phosphate anion, a is 0 or an integer from 1 to 4, n is 0 or 1, m is an integer from 1 to 4, p is an integer from 1 to 4, and k is an integer from 0 to 8.
Claim 2
Dependent Claim
237 words
A metal complex of an azolyl ether of the formula ##STR164##in which M is copper, zinc, manganese, magnesium, tin iron or nickel, X is halogen, nitro, nitrile, amino, alkyl or cycloalkyl with in either case up to 6 carbon atoms, halogenoalkyl with 1 or 2 carbon atoms and up to 5 halogen atoms, hydroxymethyl, phenyl, halogenophenyl, phenyl-substituted phenyl, carboxyl, alkoxycarbonyl or alkylcarbonyloxy with in either case a total of up to 5 carbon atoms, alkoxy or alkylthio with in either case 1 or 2 carbon atoms, halogenoalkoxy or halogenoalkylthio with in either case 1 to 2 carbon atoms and up to 5 halogen atoms, phenoxy, benzoyloxy, chlorophenoxy, chlorobenzoyloxy, benzoyl, chlorobenzoyl, dialkylamino with a total of up to 6 carbon atoms, alkylcarbonyl amino with a total of up to 4 carbon atoms, alkylsulfonyl or alkylsulfonyloxy with in either case 1 or 2 carbon atoms, phenylsulfonyl and phenylsulfonyloxy, Az is an imidazolyl radical, a 1,2,4-triazolyl-(1) radical or a 1,2,4-triazolyl-(4) radical, B is CO or CH(OH), R is alkyl with up to 6 carbon atoms or optionally phenyl substituted in o- or p-position with halogen, nitro, nitrile or methyl, A is a chloride, bromide, iodide, nitrate, sulfate or phosphate anion, a is 0 or an integer from 1 to 4, n is 0 or 1, m is an integer from 1 to 4, p is an integer from 1 to 4, and k is an integer from 0 to 8.
Claim 3
Dependent Claim
18 words
The compound according to claim 1 wherein such compound is mono[1-(1,2,4-triazolyl-(1))-1-(p-chlorophenoxy)-3,3-dimethylbutan-2-one]magnesium (II) chloride hexahydrate of the formula ##STR165##
Claim 4
Dependent Claim
18 words
The compound according to claim 1, wherein said compound is bis-[1-(1,2,4-triazolyl-(1))-1-(p-chlorophenoxy)-3,3-dimethyl-butan-2-one] copper (II) chloride of the formula ##STR166##
Claim 5
Dependent Claim
16 words
The compound according to claim 1, wherein said compound is tetra-[1-(1,2,4-triazolyl-(1))-1-(p-bromophenoxy)-3,3-dimethyl-butan-2-ol] copper(II) chloride of the formula
Claim 6
Dependent Claim
15 words
The compound according to claim 1, wherein said compound is bis-[1-1,2,4-triazolyl-(1)-1-(p-phenylphenoxy)-3,3-dimethyl-butan-2-one]zinc(II) chloride of the formula
Claim 7
Dependent Claim
14 words
The compound according to claim 1, wherein said compound is bis-[1-1,2,4-triazolyl-(1)-1-(2,4-dichlorophenoxy)-3,3-dimethyl-butan-2-one]copper(II)chloride of the formula
Claim 8
Dependent Claim
15 words
The compound according to claim 1, wherein said compound is tetra-[1-1,2,4-triazolyl-(1)-1-(p-chlorophenoxy)-3,3-dimethyl-butan-2-ol]copper(II) chloride of the formula
Claim 9
Dependent Claim
14 words
The compound according to claim 1, wherein said compound is bis-[1-1,2,4-triazolyl-(1)-1-(p-diphenoxy)-3,3-dimethyl-butan-2-ol]copper(II)chloride of the formula
Claim 10
Dependent Claim
15 words
The compound according to claim 1, wherein said compound is bis-[1-1,2,4-triazolyl-(1)-1-(2,4-dichlorophenoxy-3,3-dimethyl-butan-2-ol]zinc(II) chloride of the formula
Claim 11
Dependent Claim
22 words
A fungicidal composition containing as active ingredient a fungicidally effective amount of a compound according to claim 1 admixture with a diluent.
Claim 12
Dependent Claim
26 words
A method of combating fungi which comprises applying to the fungi or a fungus habitat a fungicidally effective amount of a compound according to claim 1.
Claim 13
Dependent Claim
40 words
The method according to claim 11 in which said compound is mono[1-(1,2,4-triazolyl-(1)-1-(p-chlorophenoxy)-3,3-dimethylbutan-2-one]magnesium (II) chloride hexahydrate; bis-[ 1-(1,2,4-triazolyl-(1)-1-(p-chlorophenoxy)-3,3-dimethyl-butan-2-one] copper (II) chloride; tetra-[1-(1,2,4-triazolyl-(1)-1-(p-bromophenoxy)-3,3-dimethyl-butan-2-ol] copper (II) chloride; bis-[1-1,2,4-triazolyl(1)-1-(p-phenylphenoxy)-3,3-dimethyl-butan-2-one]zinc (II) chloride; bis-[1-1,2,4-triazolyl-(1)-1-(2,4-dichlorophenoxy)-3,3-dimethyl-butan-2-one]copper (II) chloride; tetra-[1-1,2,4-triazolyl-(1)-1-(p-chlorophenoxy)-3,3-dimethyl-butan-2-one]copper (II) chloride; bis-[1-1,2,4-triazolyl-(1)-1-(p-diphenoxy)-3,3-dimethyl-butan-2-ol]copper (II) chloride; or bis-[1-1,2,4-triazolyl-(1)-1(2,4-dichlorophenoxy-3,3-dimethyl-butan-2-one]zinc (II) chloride.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-25 | 1980-07-26 | 1981-01-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-25 | 1984-07-26 | 1985-01-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-25 | 1988-07-26 | 1989-01-25 | $7700.00 | Window Closed / Lapsed |