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US4005059A Expired / Lapsed US ⏱️ 0.0 years remaining

Copolymer of N-vinylcarbazole

Assignee: Bpifrance Financement SA
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Filing: 1974-04-30
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Granted: 1977-01-25
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Expires: 1994-04-30
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Abstract

Abstract There is described a novel copolymer comprising approximately equimolar proportions of N-vinylcarbazole and a copolymerisable ethylenically unsaturated carboxylic acid such as acrylic acid or methacrylic acid, which can be prepared by mixing the monomers in a wide range of relative proportions, alone or diluted in a solvent, and initiating copolymerisation by methods known to the art, and which can be cross-linked, e.g. by means of polyvalent metal cations; this cross-linking is reversible on treatment with strong acid. The copolymer has good thermal and mechanical properties and adhesive properties, e.g. for metals, and can be used to form protective coatings on metals and to form metal and metal/plastics laminates.

Inventors

  • 👤 Adolphe Chapiro
  • 👤 Zbigniew Mankowski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 18:16
CPC Classifications
C; C08; C08F; C08F226/00; C08F226/06; C08F226/12; C08F220/00; C08F220/02; C08F220/04; C08F220/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 25 words
A copolymer made up of units of N-vinyl-carbazole alternated with units of a polymerisable ethylenically unsaturated carboxylic acid selected from acrylic acid and methacrylic acid
Claim 2
Dependent Claim 25 words
A copolymer made up of units of N-vinyl-carbazole alternated with units of a polymerisable ethylenically unsaturated carboxylic acid selected from acrylic acid and methacrylic acid
Claim 3
Dependent Claim 23 words
An at least semi-finished product composed of a copolymer as set forth in claim 1 cross-linked with at least one polyvalent metal ion.
Claim 4
Dependent Claim 82 words
A process for the manufacture of a copolymer which comprises the steps of forming a mixture of the monomers N-vinylcarbazole and a polymerisable ethylenically unsaturated carboxylic acid selected from acrylic acid and methacrylic acid, the molar proportion of each monomer in said mixture being from 1 to 99% of the total of said monomers, diluting said mixture in a solvent, initiating copolymerisation of said mixture, and effecting cross-linking of the resultant copolymer with the aid of at least one polyvalent metal ion.
Claim 5
Dependent Claim 82 words
A process for the manufacture of a copolymer which comprises the steps of forming a mixture of the monomers N-vinylcarbazole and a polymerisable ethylenically unsaturated carboxylic acid selected from acrylic acid and methacrylic acid, the molar proportion of each monomer in said mixture being from 1 to 99% of the total of said monomers, diluting said mixture in a solvent, initiating copolymerisation of said mixture, and effecting cross-linking of the resultant copolymer with the aid of at least one polyvalent metal ion.

References Cited (Backward Citations)

US2072465A Cited
DE664231C Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-01-25 1980-07-26 1981-01-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-01-25 1984-07-26 1985-01-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-01-25 1988-07-26 1989-01-25 $7700.00 Window Closed / Lapsed

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