Removal of sulfur oxides and particulate matter from waste gas streams

Claim 1

An apparatus suitable for use in the removal of sulfur oxides and particulate matter from waste gases which comprises: a. a contacting vessel having an inlet for waste gases containing sulfur oxides and particulate matter and an outlet for waste gas substantially free of sulfur oxides and particulate matter, an internal compartment containing a moving bed of supported, copper-containing acceptor for sulfur oxides, said internal compartment being defined by perforated walls disposed inside the contacting vessel, an inlet for fresh supported copper-containing acceptor in fluid communication with said internal compartment and an outlet for said acceptor loaded with sulfur oxides and particulate matter also in fluid communication with said internal compartment, and a means for directing the flow of said waste gases and said moving bed of acceptor cross-currently to one another, said waste gas flowing through the perforated walls of said internal compartment containing said moving bed of acceptor; b. a first purge vessel for removing particulate matter from the acceptor having a bottom inlet for purge gas and a top outlet for purge gas and particulate matter, a top inlet for acceptor material loaded with sulfur oxides and particulate matter connected to the loaded acceptor outlet of said contacting vessel and a bottom outlet for purged acceptor material, at least one perforated plate disposed in the vessel at an angle with the vertical for transporting the loaded acceptor material from its inlet to the outlet and a means for passing said purge gas through said perforated plate thereby stripping said particulate matter from said loaded acceptor during its transport on said perforated plate; c. a first vertical riser tube debouching into a first cyclone for removing sulfur oxides from the acceptor, having a bottom inlet for purged acceptor material connected to the bottom outlet of the first purge vessel and a bottom inlet for reducing gas, a first cyclone top outlet for sulfur oxide-containing gas and a first cyclone bottom outlet for reduced acceptor material; d. a second purge vessel with a bottom inlet and a top outlet for a purge gas, a top inlet for reduced acceptor material connected to the first cyclone bottom outlet and a bottom outlet for purged acceptor material and at least one perforated plate disposed in the vessel at an angle with the vertical for transporting acceptor material from its inlet to the outlet, and e. a second vertical riser tube debouching into a second cyclone for reactivating the acceptor having a bottom inlet for purged acceptor material connected to the bottom outlet of the second purge vessel and a bottom inlet for an oxygen-containing gas, a second cyclone top outlet for the oxygen-containing gas and a second cyclone bottom outlet for reactivated acceptor material connected to the acceptor inlet of the contacting vessel.

Claim 2

An apparatus suitable for use in the removal of sulfur oxides and particulate matter from waste gases which comprises: a. a contacting vessel having an inlet for waste gases containing sulfur oxides and particulate matter and an outlet for waste gas substantially free of sulfur oxides and particulate matter, an internal compartment containing a moving bed of supported, copper-containing acceptor for sulfur oxides, said internal compartment being defined by perforated walls disposed inside the contacting vessel, an inlet for fresh supported copper-containing acceptor in fluid communication with said internal compartment and an outlet for said acceptor loaded with sulfur oxides and particulate matter also in fluid communication with said internal compartment, and a means for directing the flow of said waste gases and said moving bed of acceptor cross-currently to one another, said waste gas flowing through the perforated walls of said internal compartment containing said moving bed of acceptor; b. a first purge vessel for removing particulate matter from the acceptor having a bottom inlet for purge gas and a top outlet for purge gas and particulate matter, a top inlet for acceptor material loaded with sulfur oxides and particulate matter connected to the loaded acceptor outlet of said contacting vessel and a bottom outlet for purged acceptor material, at least one perforated plate disposed in the vessel at an angle with the vertical for transporting the loaded acceptor material from its inlet to the outlet and a means for passing said purge gas through said perforated plate thereby stripping said particulate matter from said loaded acceptor during its transport on said perforated plate; c. a first vertical riser tube debouching into a first cyclone for removing sulfur oxides from the acceptor, having a bottom inlet for purged acceptor material connected to the bottom outlet of the first purge vessel and a bottom inlet for reducing gas, a first cyclone top outlet for sulfur oxide-containing gas and a first cyclone bottom outlet for reduced acceptor material; d. a second purge vessel with a bottom inlet and a top outlet for a purge gas, a top inlet for reduced acceptor material connected to the first cyclone bottom outlet and a bottom outlet for purged acceptor material and at least one perforated plate disposed in the vessel at an angle with the vertical for transporting acceptor material from its inlet to the outlet, and e. a second vertical riser tube debouching into a second cyclone for reactivating the acceptor having a bottom inlet for purged acceptor material connected to the bottom outlet of the second purge vessel and a bottom inlet for an oxygen-containing gas, a second cyclone top outlet for the oxygen-containing gas and a second cyclone bottom outlet for reactivated acceptor material connected to the acceptor inlet of the contacting vessel.