US4003976A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Converter for the purification of exhaust gases
Assignee: Toyota Central R&D Labs Inc
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Filing: 1975-08-29
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Granted: 1977-01-18
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Expires: 1995-08-29
Abstract
Abstract A converter for the purification of exhaust gases from internal combustion engines and the like which comprises a first converting layer of a catalyst of a sintered body structure selected from the group consisting of nickel oxide-copper oxide; manganese oxide-cerium oxide; manganese oxide-lanthanum oxide; manganese oxide-iron oxide; manganese oxide-niobium oxide; manganese oxide-nickel oxide; and either niobium oxide or yttrium oxide or mixtures of both with cobalt oxide; and a second converting layer of a catalyst selected from the group consisting of platinum; platinum-rhodium; platinum-palladium; and nickel oxide, chromium oxide, copper oxide, iron oxide and barium oxide; wherein the converter is constructed so that the exhaust gases pass through said first converting layer and then through said second converting layer. A copper-filled layer consisting of a copper-containing material may be further provided upstream of said first and second converting layers.
Inventors
- 👤 Noboru Komatsu
- 👤 Osami Kamigaito
- 👤 Takatoshi Suzuki
- 👤 Nobuyuki Yamamoto
- 👤 Haruo Doi
- 👤 Kazuya Sano
- 👤 Toshio Kandori
- 👤 Yukikazu Tsuzuki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 22:18
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9445; B01D53/945; B01D53/9404; B01D53/9409; B01D53/9413; B01D53/9418; B01D53/9431; B01D2255/00; B01D2255/10; B01D2255/102; B01D2255/1021; B01D2255/1025; B01D2255/20; B01D2255/204; B01D2255/2042; B01D2255/206; B01D2255/2061; B01D2255/2063; B01D2255/2065; B01D2255/207; B01D2255/20738; B01D2255/20753; B01D2255/20761; B01D2255/20784; B01D2255/90; B01D2255/902; B01D2255/9022; B01D53/9422; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/12
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
141 words
A method of reducing NO x in exhaust gases over a wide range of oxygen ratios while minimizing ammonia formation, which comprises: 1. passing said exhaust gas through a first layer of catalyst having a sintered body structure; said catalyst having a high conversion rate at low oxygen ratios, exhibiting a decrease in conversion rate as the oxygen ratio increases, the causing minimal formation of ammonia; and said catalyst being selected from the group consisting of: a. a particulate mixture of nickel oxide and copper oxide; b. a particulate mixture of manganese oxide and an oxide selected from the group consisting of cerium oxide, lanthanum oxide, iron oxide, niobium oxide, nickel oxide and mixtures thereof; and c. a particulate mixture of cobalt oxide and an oxide selected from the group consisting of yttrium oxide, niobium oxide and mixtures thereof; and 2.
Claim 2
Independent Claim
141 words
A method of reducing NO x in exhaust gases over a wide range of oxygen ratios while minimizing ammonia formation, which comprises: 1. passing said exhaust gas through a first layer of catalyst having a sintered body structure; said catalyst having a high conversion rate at low oxygen ratios, exhibiting a decrease in conversion rate as the oxygen ratio increases, the causing minimal formation of ammonia; and said catalyst being selected from the group consisting of: a. a particulate mixture of nickel oxide and copper oxide; b. a particulate mixture of manganese oxide and an oxide selected from the group consisting of cerium oxide, lanthanum oxide, iron oxide, niobium oxide, nickel oxide and mixtures thereof; and c. a particulate mixture of cobalt oxide and an oxide selected from the group consisting of yttrium oxide, niobium oxide and mixtures thereof; and 2.
Claim 3
Dependent Claim
75 words
thereafter passing said exhaust gas through a second layer of catalyst; said catalyst having a low conversion rate and producing large amounts of ammonia at low oxygen ratios, and exhibiting higher conversion rates while producing lesser amounts of ammonia as the oxygen ratio increases; and said catalyst being selected from the group consisting of: d. a platinum-rhodium catalyst; e. a platinum catalyst; f. a platinum-palladium catalyst; and g. a nickel oxide-chromium oxide-copper oxide-iron oxide-barium oxide
Claim 4
Dependent Claim
75 words
thereafter passing said exhaust gas through a second layer of catalyst; said catalyst having a low conversion rate and producing large amounts of ammonia at low oxygen ratios, and exhibiting higher conversion rates while producing lesser amounts of ammonia as the oxygen ratio increases; and said catalyst being selected from the group consisting of: d. a platinum-rhodium catalyst; e. a platinum catalyst; f. a platinum-palladium catalyst; and g. a nickel oxide-chromium oxide-copper oxide-iron oxide-barium oxide
Claim 5
Dependent Claim
47 words
catalyst. 2. The process of claim 1, which further comprises: passing said exhaust gas through a copper-filled layer consisting essentially of a copper containing material selected from the group consisting of copper, copper oxide and mixtures thereof prior to passage through said first and second converting layers.
Claim 6
Dependent Claim
30 words
The process of claim 1, wherein said catalyst of a sintered body structure of the first converting layer is in the shape of beads, granules, pellets, plates or a honeycomb.
Claim 7
Dependent Claim
25 words
The process of claim 1, wherein the diameter of said oxide particles of the catalyst of the first converting layer ranges from 3 to 5μ.
Claim 8
Dependent Claim
18 words
The process of claim 1, wherein said catalyst of the second converting layer is supported on a carrier.
Claim 9
Dependent Claim
15 words
The process of claim 2, wherein said copper-containing material is of a sintered body structure.
Claim 10
Dependent Claim
22 words
The process of claim 2, wherein said copper-containing material is in the shape of splinters, beads, granules, chips, plates or a screen.
Claim 11
Dependent Claim
14 words
The process of claim 2, wherein said copper-containing material is supported on a carrier.
Claim 12
Dependent Claim
27 words
The process of claim 2, wherein said copper-containing material is admixed with a material selected from the group consisting of cerium oxide, lanthanum oxide and mixtures thereof.
Claim 13
Dependent Claim
20 words
The process of claim 1, wherein said first converting layer consists of a catalyst of sintered nickel oxide-copper oxide beads.
Claim 14
Dependent Claim
23 words
The process of claim 10, wherein said second converting layer consists of nickel oxide-chromium oxide-copper oxide-iron oxide-barium oxide catalyst supported on a carrier.
Claim 15
Dependent Claim
15 words
The process of claim 10, wherein said second converting layer consists of a platinum-rhodium catalyst.
Claim 16
Dependent Claim
15 words
The process of claim 10, wherein said second converting layer consists of a platinum catalyst.
Claim 17
Dependent Claim
54 words
The process of claim 1, wherein said first converting layer consists of a catalyst of sintered beads of manganese oxide with one material selected from the group consisting of cerium oxide, lanthanum oxide, iron oxide, niobium oxide and nickel oxide, and said second converting laayer consists of a platinum catalyst supported on a carrier.
Claim 18
Dependent Claim
47 words
The process of claim 1, wherein said converting layer consists of a catalyst of sintered beads of cobalt oxide with one material selected from the group consisting or yttrium oxide and niobium oxide, and said second converting layer consists of a platinum-palladium catalyst supported on a carrier.
Claim 19
Dependent Claim
51 words
The process of claim 2, wherein said copper-filled layer consists of sintered copper-copper oxide beads, said first converting layer consists of a sintered nickel oxide-copper oxide catalyst and said second converting layer consists of either a nickel oxide-chromium oxide-copper oxide-iron oxide-barium oxide catalyst or a platinum-rhodium catalyst supported on a carrier.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-18 | 1980-07-19 | 1981-01-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-18 | 1984-07-19 | 1985-01-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-18 | 1988-07-19 | 1989-01-18 | $7700.00 | Window Closed / Lapsed |