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US4003939A Expired / Lapsed US ⏱️ 0.0 years remaining

Addition of sulfenyl halides to olefins and acetylenes

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1975-07-10
•
Granted: 1977-01-18
•
Expires: 1995-07-10
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Abstract

Abstract Acylthiosulfenyl halides, phosphorylsulfenyl halides, and thiophosphorylsulfenyl halides are added to monoolefins, multiolefins and acetylenic compounds. 1,2-Markownikov oriented adducts are the principal products when conjugated diolefins are employed as the starting feedstock. Anti-Markownikov adducts are obtained as major products when unsymmetrical monoolefins and nonconjugated multiolefins are used as the starting material. The addition reactions are conducted at low temperatures.

Inventors

  • 👤 Wolfgang H. Mueller
  • 👤 Alexis A. Oswald
  • 👤 Daniel N. Hall

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 09:15
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/06; C07F9/16; C07F9/165; C07F9/1651; C07C; C07C327/00; C07C327/20; C07C327/22; C07C327/26; C07F9/173

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 36 words
Compounds selected from the group of compounds represented by the general formula: ##STR39## wherein R 1 is selected from the group consisting of C 1 -C 14 alkyl radicals and C 6 -C 16 aryl radicals.
Claim 2
Dependent Claim 36 words
Compounds selected from the group of compounds represented by the general formula: ##STR39## wherein R 1 is selected from the group consisting of C 1 -C 14 alkyl radicals and C 6 -C 16 aryl radicals.

References Cited (Backward Citations)

US3427330A Cited
US3428665A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-01-18 1980-07-19 1981-01-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-01-18 1984-07-19 1985-01-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-01-18 1988-07-19 1989-01-18 $7700.00 Window Closed / Lapsed

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