Adhesive material and articles incorporating same

Claim 2

Release agent comprising the reaction product of a composition comprising in admixture: a. a di (omega-organofunctional) dimethylsiloxane oligomer represented by the formula: ##STR3## wherein R is an olefin hydrocarbon radical having at least two carbon atoms and n is an integer from 5 to 100; b. a difunctional organic compound capable of reacting with the active hydrogen of the terminal groups of the dimethylsiloxane oligomer selected from the group consisting of aromatic and aliphatic diisocyanates and diisocyanate prepolymers resulting from the reaction of a difunctional organic compound containing active hydrogen groups with a large excess of diisocyanate; and c. when said difunctional organic compound is selected from the group of aromatic and aliphatic diisocyanates, a second difunctional organic compound containing active hydrogen groups.

Claim 3

Release agent according to claim 1 wherein R is propylene, and n is about 25.

Claim 4

Release agent according to claim 2 wherein the first named difunctional organic compound is an aromatic diisocyanate.

Claim 5

Release agent according to claim 3 wherein the diisocyanate is 2,4-toluene diisocyanate.

Claim 6

Release agent according to claim 1 wherein the said second difunctional organic compound is selected from the group consisting of hexamethylene diol, triethylene glycol, OH-terminated polytetramethylene glycol of 1000 molecular weight, OH-terminated poly(ethylene adipate) of 300-3000 molecular weight, methylene-bis(4-aniline), propylene diamine, NH 2 -terminated polyoxyethylene of 1500 molecular weight, hexamethylene dithiol, and thiol-terminated polyoxypropylene of 200-2000 molecular weight.

Claim 7

Release agent according to claim 4 wherein the second difunctional compound is triethylene glycol.

Claim 8

Release agent according to claim 1 wherein the release agent is the reaction product of a composition comprising in admixture: a. from 20 to 95% by weight of a di (omega-organofunctional) dimethylsiloxane oligomer represented by the formula: ##STR4## having a molecular weight of 3000 and wherein R is propylene; b. toluene-2,4 diisocyanate in the range of from 5 to 75% by weight of the composition; and c. triethylene glycol in the range of 0 to 70% by weight of the composition.

Claim 9

Release agent according to claim 7 wherein the components of the reaction mixture are present in the proportions indicated below: ______________________________________ COMPONENTS GRAMS ______________________________________ mercapto silicone polymer 150.0 2,4 toluene diisocyanate 53.9 triethylene glycol 37.5 ______________________________________ and the reaction product has an intrinsic viscosity of 0.12 and a critical surface tension of 19 dynes/cm.

Claim 10

Release composition comprising as a major ingredient a film former and as a minor ingredient a release agent in accordance with claim 1, the surface tension of the film former being greater than that of the release agent.

Claim 11

Release composition according to claim 9 wherein the difference between the surface tension of the film former and the release agent is at least 15 dynes/cm.

Claim 12

Release composition according to claim 10 wherein the film former is an epoxy resin.

Claim 13

Pressure-sensitive adhesive material comprising a backing member having a front side and a back side, a pressure-sensitive adhesive mass on the front side, and a back size on the back side of the backing member comprising a release agent comprising the reaction product of a composition in accordance with claim 1.

Claim 14

Pressure-sensitive adhesive material according to claim 12 wherein the backing member is a polyester film.

Claim 15

Pressure-sensitive adhesive material according to claim 13 wherein the adhesive material is in the form of a tape in roll form, said composition providing satisfactory unwind characteristics and release from an adhesive mass of high adhesion characteristics.

Claim 16

Composition of matter for use as a release agent comprising a linear block copolymer having the recurring unit: ##STR5## wherein R is an olefin hydrocarbon radical having at least two carbon atoms, R 1 is a divalent radical selected from the group consisting of aliphatic and aromatic radicals, X is a member selected from the group consisting of O, S, and NH, R 2 is a member selected from the group consisting of divalent radicals selected from the group consisting of alkyl, and alkylaryl, polyethers, and polyesters, n is an integer from 1 to 100, and a and b are integers chosen so as to provide a copolymer having a molecular weight as defined by intrinsic viscosity of at least 0.05, the ratio of b/a is in the range of from 0 to 3, and the polysiloxane block is present in an amount from 30 to 95% of the copolymer.

Claim 17

Composition of matter for use as a release agent comprising a linear block copolymer having the recurring unit: ##STR5## wherein R is an olefin hydrocarbon radical having at least two carbon atoms, R 1 is a divalent radical selected from the group consisting of aliphatic and aromatic radicals, X is a member selected from the group consisting of O, S, and NH, R 2 is a member selected from the group consisting of divalent radicals selected from the group consisting of alkyl, and alkylaryl, polyethers, and polyesters, n is an integer from 1 to 100, and a and b are integers chosen so as to provide a copolymer having a molecular weight as defined by intrinsic viscosity of at least 0.05, the ratio of b/a is in the range of from 0 to 3, and the polysiloxane block is present in an amount from 30 to 95% of the copolymer.