US4001190A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Acid-dyeable fibers of polyester modified with tetramethylpiperidine polyether glycols
Assignee: EIDP Inc
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Filing: 1975-03-19
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Granted: 1977-01-04
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Expires: 1995-03-19
Abstract
Abstract Textile fibers or filaments having improved dyeability are prepared from linear polyesters modified with a minor proportion of 2,2,6,6,-tetramethylpiperidine groups attached in the polymer chain through oxyalkylene linkages at the 1 and 4 positions of the piperidine ring. Alkylene oxide condensates of 2,2,6,6,-tetramethylpiperidine glycols are shown to have adequate heat-stability and compatibility for incorporating in polyesters under conditions of condensation polymerization to form modified polyesters suitable for melt-spinning into desirable products.
Inventors
- 👤 Murty S. Tanikella
- 👤 Odorich Von Susani
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 11:59
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/685; C08G63/6854; C08G63/6856
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
76 words
Acid dyeable polyester fibers or filaments comprising, as integral components in linear polyester chains, a minor proportion sufficient to provide at least 0.05 weight percent nitrogen, of 2,2,6,6-tetramethylpiperidine groups linked to dicarboxylate chain units through substituents at both the 1 and 4 positions of the piperidine ring which contain oxyethylene units, and the number of oxyethylene units in such linking substituents on tetramethylpiperidine groups in the polyester averages at least 10 oxyethylene units per tetramethylpiperidine group.
Claim 2
Dependent Claim
76 words
Acid dyeable polyester fibers or filaments comprising, as integral components in linear polyester chains, a minor proportion sufficient to provide at least 0.05 weight percent nitrogen, of 2,2,6,6-tetramethylpiperidine groups linked to dicarboxylate chain units through substituents at both the 1 and 4 positions of the piperidine ring which contain oxyethylene units, and the number of oxyethylene units in such linking substituents on tetramethylpiperidine groups in the polyester averages at least 10 oxyethylene units per tetramethylpiperidine group.
Claim 3
Dependent Claim
25 words
Fibers or filaments as defined in claim 1 wherein the tetramethylpiperidine groups provide 0.05 to 0.25 percent nitrogen based on the weight of the polyester.
Claim 4
Dependent Claim
20 words
Fibers or filaments as defined in claim 1 wherein the polyester comprises at least 85 mole percent ethylene terephthalate units.
Claim 5
Dependent Claim
23 words
Fibers or filaments as defined in Claim 3 wherein the polyester comprises up to 10 weight percent ethylene adipate or ethylene glutarate units.
Claim 6
Dependent Claim
22 words
Fibers or filaments as defined in claim 1 wherein there are an average of 10 to 80 oxyethylene units per tetramethylpiperidine group.
Claim 7
Dependent Claim
77 words
Fibers or filaments as defined in claim 1 wherein the tetramethylpiperidine groups and linking substituents are represented by the following formula: ##SPC3## wherein P represents a segment of a polyester chain having a terminal carbonyl group; --(OA) n -- and --(AO) m -- represent divalent groups of n and m oxyalkylene units which contain a total of at least 10 oxyethylene units, and R is a saturated aliphatic divalent hydrocarbon group of 2 to 18 carbon atoms.
Claim 8
Dependent Claim
28 words
Fibers or filaments as defined in claim 6 wherein said oxyalkylene units are a mixture of oxyethylene and oxypropylene units of which at least one-half are oxyethylene units.
Claim 9
Dependent Claim
19 words
Fibers or filaments as defined in claim 6 wherein the substituted tetramethylpiperidine is an alkylene oxide condensate of 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine.
Claim 10
Dependent Claim
19 words
Fibers or filaments as defined in claim 6 wherein the substituted tetramethylpiperidine is an alkylene oxide condensate of 1-(2-hydroxy-2-methylethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine.
Claim 11
Dependent Claim
31 words
Fibers or filaments as defined in claim 6 wherein the substituted tetramethylpiperidine is an ethylene oxide condensate of 1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine containing an average of about 20 ethylene oxide units per tetramethylpiperidine group.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-04 | 1980-07-05 | 1981-01-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-04 | 1984-07-05 | 1985-01-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-04 | 1988-07-05 | 1989-01-04 | $7700.00 | Window Closed / Lapsed |