US4001189A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Fibers of acid-dyeable polyester having tetramethylpiperidine groups attached through oxyalkalene linkages to ends of polymer chains
Assignee: EIDP Inc
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Filing: 1975-03-19
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Granted: 1977-01-04
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Expires: 1995-03-19
Abstract
Abstract Textile fibers or filaments prepared from polyesters modified with a minor proportion of 2,2,6,6-tetramethylpiperidine groups attached through oxyalkylene linkages to ends of linear polyester polymer chains have improved dyeability with acid dyes. A variety of alkylene oxide condensates of tetramethylpiperidine compounds are shown to have adequate heat-stability and compatibility for incorporating in polyesters under conditions of condensation polymerization to form desirable products.
Inventors
- 👤 Murty S. Tanikella
- 👤 Odorich Von Susani
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 04:10
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/685; C08G63/6854; C08G63/6856
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
82 words
Acid-dyeable textile fibers or filaments of polyester containing a minor proportion, sufficient to provide at least 0.02 weight percent nitrogen, of 2,2,6,6-tetramethylpiperidine groups attached through oxyalkylene linkages to carboxylate units at the ends of polyester chains, said linkages being through the 1 or 4 positions of the tetramethylpiperidine ring, the oxyalkylene linkages consisting of oxyethylene or oxyethylene and oxypropylene, and there being an average of at least about 10 oxyalkylene units per tetramethylpiperidine group of which at least 5 are oxyethylene units.
Claim 2
Dependent Claim
82 words
Acid-dyeable textile fibers or filaments of polyester containing a minor proportion, sufficient to provide at least 0.02 weight percent nitrogen, of 2,2,6,6-tetramethylpiperidine groups attached through oxyalkylene linkages to carboxylate units at the ends of polyester chains, said linkages being through the 1 or 4 positions of the tetramethylpiperidine ring, the oxyalkylene linkages consisting of oxyethylene or oxyethylene and oxypropylene, and there being an average of at least about 10 oxyalkylene units per tetramethylpiperidine group of which at least 5 are oxyethylene units.
Claim 3
Dependent Claim
20 words
Fibers or filaments as defined in claim 1 wherein the polyester comprises at least 85 mole percent ethylene terephthalate units.
Claim 4
Dependent Claim
37 words
Fibers or filaments as defined in claim 2 wherein said polyester contains alkylene oxide condensates of a 1-alkyl-2,2,6,6-tetramethyl-4-hydroxypiperidine, linked to terephthalate units at the ends of polyester chains, said 1-alkyl group having 1 to 4 carbon atoms.
Claim 5
Dependent Claim
37 words
Fibers or filaments as defined in claim 2 wherein said polyester contains alkylene oxide condensates of a 1-hydroxyalkyl-2,2,6,6-tetramethylpiperidine, linked to terephthalate units at the ends of polyester chains, said 1-hydroxyalkyl group having 1 to 4 carbon atoms.
Claim 6
Dependent Claim
20 words
Fibers or filaments as defined in claim 2 wherein the polyester comprises 2 to 10 weight percent ethylene adipate units.
Claim 7
Dependent Claim
27 words
Fibers of filaments as defined in claim 1 wherein the 2,2,6,6-tetramethylpiperidine groups provide 0.02 to 0.25 weight percent nitrogen, based on the weight of the modified polyester.
Claim 8
Dependent Claim
22 words
Fibers or filaments as defined in claim 1 wherein there are an average of 10 to 80 oxyalkylene units per tetramethylpiperidine group.
Claim 9
Dependent Claim
22 words
Fibers or filaments as defined in claim 1 wherein there are an average of 10 to 40 oxyalkylene units per tetramethylpiperidine group.
Claim 10
Dependent Claim
24 words
Fibers or filaments as defined in claim 1 wherein 2,2,6,6-tetramethylpiperidine groups are attached to said carboxylate units through the 4-position of the tetramethylpiperidine ring.
Claim 11
Dependent Claim
48 words
Fibers or filaments as defined in claim 1 wherein the polyester comprises at least 85 mole percent ethylene terephthalate units and contains oxyethylene condensates of 1,2,2,6,6-pentamethyl-4-hydroxypiperidine linked to terephthalate units at the ends of polyester chains, there being an average of about 20 oxyethylene units per pentamethylpiperidine group.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-04 | 1980-07-05 | 1981-01-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-04 | 1984-07-05 | 1985-01-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-04 | 1988-07-05 | 1989-01-04 | $7700.00 | Window Closed / Lapsed |