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US4001101A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrodeposition of epoxy compositions

Assignee: PPG Industries Inc
•
Filing: 1971-07-29
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Granted: 1977-01-04
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Expires: 1991-07-29
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Abstract

Abstract Synthetic resins which are water-dispersible epoxy resins having epoxy groups, chemically-bound quaternary ammonium base salts, can be dissolved or dispersed in water to provide aqueous coating compositions. Such compositions, in which these resins are the major resinous component, can be applied by electrodeposition and deposit on the cathode to provide coatings of improved properties, including a high degree of resistance to corrosion or staining.

Inventors

  • 👤 Joseph F. Bosso
  • 👤 Marco Wismer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 16:54
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4078; C08G59/50; C08G59/52; C08G59/56; C08G59/58; C08G59/62; C08G59/64; C09; C09D; C09D5/00; C09D5/44; C09D5/4419; C09D5/443; C09D5/4434; C09D5/4457

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 124 words
A method of coating a conductive substrate serving as a cathode which comprises passing electric current between an anode and said cathode in electrical contact with a water-dispersed composition comprising an aqueous dispersion comprising an ungelled, water-dispersible epoxy resin having in the resin molecule: a. at least one 1,2-epoxy group, b. at least about 0.05 percent by weight of chemically-bound nitrogen, at least one percent of which is in the form of a quaternary ammonium base salt of an acid having a dissociation constant greater than about 1 × 10 - 5 , c. said water-dispersed composition containing boron in the form of boric acid, an ester of boric acid or a compound which can be cleaved to form boric acid in aqueous medium.
Claim 2
Independent Claim 124 words
A method of coating a conductive substrate serving as a cathode which comprises passing electric current between an anode and said cathode in electrical contact with a water-dispersed composition comprising an aqueous dispersion comprising an ungelled, water-dispersible epoxy resin having in the resin molecule: a. at least one 1,2-epoxy group, b. at least about 0.05 percent by weight of chemically-bound nitrogen, at least one percent of which is in the form of a quaternary ammonium base salt of an acid having a dissociation constant greater than about 1 × 10 - 5 , c. said water-dispersed composition containing boron in the form of boric acid, an ester of boric acid or a compound which can be cleaved to form boric acid in aqueous medium.
Claim 3
Dependent Claim 18 words
A method as in claim 1 wherein the acid salt is in the form of an internal zwitterion.
Claim 4
Dependent Claim 14 words
A method as in claim 1 wherein the water dispersed composition contains boric acid.
Claim 5
Dependent Claim 20 words
A method as in claim 1 wherein the resin contains about 0.05 to about 16 percent by weight of nitrogen.
Claim 6
Dependent Claim 25 words
A method as in claim 4 wherein at least about 20 percent of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 7
Dependent Claim 25 words
A method as in claim 5 wherein at least about 50 percent of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 8
Dependent Claim 22 words
A method as in claim 6 wherein substantially all of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 9
Dependent Claim 94 words
A method as in claim 1 of coating a conductive substrate serving as a cathode which comprises passing electric current between an anode and said cathode in electrical contact with a water-dispersed composition comprising an ungelled water-dispersible epoxy resin having in the resin molecule: a. at least one 1,2-epoxy group, b. from about 0.05 to about 16 percent by weight of chemically-bound nitrogen, said nitrogen being present in the form of quaternary nitrogen or amino nitrogen; at least about one percent of said nitrogen being in the form of a quaternary ammonium base salt.
Claim 10
Dependent Claim 25 words
A method as in claim 8 wherein at least about 20 percent of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 11
Dependent Claim 25 words
A method as in claim 9 wherein at least about 50 percent of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 12
Dependent Claim 22 words
A method as in claim 10 wherein substantially all of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 13
Dependent Claim 14 words
A method as in claim 8 wherein the acid is an organic carboxylic acid.
Claim 14
Dependent Claim 25 words
A method as in claim 12 wherein at least about 20 percent of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 15
Dependent Claim 25 words
A method as in claim 13 wherein at least about 50 percent of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 16
Dependent Claim 22 words
A method as in claim 13 wherein substantially all of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 17
Dependent Claim 12 words
A method as in claim 12 wherein the acid is lactic acid.
Claim 18
Dependent Claim 25 words
A method as in claim 16 wherein at least about 20 percent of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 19
Dependent Claim 25 words
A method as in claim 17 wherein at least about 50 percent of the nitrogen is in the form of quaternary ammonium base salt groups.
Claim 20
Dependent Claim 22 words
A method as in claim 18 wherein substantially all of the nitrogen is in the form of quaternary ammonium base salt groups.

References Cited (Backward Citations)

US3301804A Cited
US3399128A Cited
US3640926A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-01-04 1980-07-05 1981-01-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-01-04 1984-07-05 1985-01-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-01-04 1988-07-05 1989-01-04 $7700.00 Window Closed / Lapsed

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