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US4000106A Expired / Lapsed US ⏱️ 0.0 years remaining

Processing aids for nitrile resins

Assignee: Standard Oil Co
•
Filing: 1975-02-26
•
Granted: 1976-12-28
•
Expires: 1995-02-26
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Abstract

Abstract Heat-stabilized, readily processable thermoplastic rubber-modified nitrile copolymer resins which have incorporated in them small amounts of a processing aid which is an alkyl ester of an organic dibasic acid.

Inventors

  • 👤 Ralph E. Isley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:00
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/10; C08K5/11; C08F; C08F279/00; C08F279/02; C08K5/12

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 230 words
The processable composition comprising an intimate mixture of from about 0.05 to about 2 parts by weight of at least one processing aid selected from the group consisting of the propyl, butyl, amyl, and hexyl phthalates, adipates, azelates, and sebacates, and 100 parts by weight of a polymer resulting from the polymerization of 100 parts by weight of A. at least 50% by weight of at least one nitrile having the structure ##STR7## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and B. up to 50% by weight based on the combined weight of (A) and (B) of an ester having the structure ##STR8## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms in the presence of from 1 to 40 parts by weight of C. a polymer of at least 50% by weight of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and up to 50% by weight of at least one member selected from the group consisting of styrene, an olefinically unsaturated nitrile having the structure ##STR9## wherein R has the foregoing designation, and an ester having the structure ##STR10## wherein R 1 and R 2 have the foregoing designations.
Claim 2
Dependent Claim 230 words
The processable composition comprising an intimate mixture of from about 0.05 to about 2 parts by weight of at least one processing aid selected from the group consisting of the propyl, butyl, amyl, and hexyl phthalates, adipates, azelates, and sebacates, and 100 parts by weight of a polymer resulting from the polymerization of 100 parts by weight of A. at least 50% by weight of at least one nitrile having the structure ##STR7## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and B. up to 50% by weight based on the combined weight of (A) and (B) of an ester having the structure ##STR8## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms in the presence of from 1 to 40 parts by weight of C. a polymer of at least 50% by weight of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and up to 50% by weight of at least one member selected from the group consisting of styrene, an olefinically unsaturated nitrile having the structure ##STR9## wherein R has the foregoing designation, and an ester having the structure ##STR10## wherein R 1 and R 2 have the foregoing designations.
Claim 3
Dependent Claim 9 words
The composition of claim 1 wherein (A) is acrylonitrile.
Claim 4
Dependent Claim 10 words
The composition of claim 2 wherein (B) is methyl acrylate.
Claim 5
Dependent Claim 14 words
The composition of claim 3 wherein (C) is a copolymer of butadiene and acrylonitrile.
Claim 6
Dependent Claim 12 words
The composition of claim 4 wherein the processing aid is dibutyl sebacate.
Claim 7
Dependent Claim 12 words
The composition of claim 4 wherein the processing aid is dibutyl phthalate.
Claim 8
Dependent Claim 12 words
The composition of claim 4 wherein the processing aid is di-n-hexyl azelate.
Claim 9
Dependent Claim 12 words
The composition of claim 4 wherein the processing aid is diallyl phthalate.
Claim 10
Dependent Claim 12 words
The composition of claim 4 wherein the processing aid is diisopropyl phthalate.

References Cited (Backward Citations)

US3284396A Cited
US3426102A Cited
US3399106A Cited
US3586737A Cited
US3725332A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-28 1980-06-28 1980-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-28 1984-06-28 1984-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-28 1988-06-28 1988-12-28 $7700.00 Window Closed / Lapsed

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