US4000106A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Processing aids for nitrile resins
Assignee: Standard Oil Co
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Filing: 1975-02-26
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Granted: 1976-12-28
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Expires: 1995-02-26
Abstract
Abstract Heat-stabilized, readily processable thermoplastic rubber-modified nitrile copolymer resins which have incorporated in them small amounts of a processing aid which is an alkyl ester of an organic dibasic acid.
Inventors
- 👤 Ralph E. Isley
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 20:00
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/10; C08K5/11; C08F; C08F279/00; C08F279/02; C08K5/12
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
230 words
The processable composition comprising an intimate mixture of from about 0.05 to about 2 parts by weight of at least one processing aid selected from the group consisting of the propyl, butyl, amyl, and hexyl phthalates, adipates, azelates, and sebacates, and 100 parts by weight of a polymer resulting from the polymerization of 100 parts by weight of A. at least 50% by weight of at least one nitrile having the structure ##STR7## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and B. up to 50% by weight based on the combined weight of (A) and (B) of an ester having the structure ##STR8## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms in the presence of from 1 to 40 parts by weight of C. a polymer of at least 50% by weight of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and up to 50% by weight of at least one member selected from the group consisting of styrene, an olefinically unsaturated nitrile having the structure ##STR9## wherein R has the foregoing designation, and an ester having the structure ##STR10## wherein R 1 and R 2 have the foregoing designations.
Claim 2
Dependent Claim
230 words
The processable composition comprising an intimate mixture of from about 0.05 to about 2 parts by weight of at least one processing aid selected from the group consisting of the propyl, butyl, amyl, and hexyl phthalates, adipates, azelates, and sebacates, and 100 parts by weight of a polymer resulting from the polymerization of 100 parts by weight of A. at least 50% by weight of at least one nitrile having the structure ##STR7## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and B. up to 50% by weight based on the combined weight of (A) and (B) of an ester having the structure ##STR8## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms in the presence of from 1 to 40 parts by weight of C. a polymer of at least 50% by weight of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and up to 50% by weight of at least one member selected from the group consisting of styrene, an olefinically unsaturated nitrile having the structure ##STR9## wherein R has the foregoing designation, and an ester having the structure ##STR10## wherein R 1 and R 2 have the foregoing designations.
Claim 3
Dependent Claim
9 words
The composition of claim 1 wherein (A) is acrylonitrile.
Claim 4
Dependent Claim
10 words
The composition of claim 2 wherein (B) is methyl acrylate.
Claim 5
Dependent Claim
14 words
The composition of claim 3 wherein (C) is a copolymer of butadiene and acrylonitrile.
Claim 6
Dependent Claim
12 words
The composition of claim 4 wherein the processing aid is dibutyl sebacate.
Claim 7
Dependent Claim
12 words
The composition of claim 4 wherein the processing aid is dibutyl phthalate.
Claim 8
Dependent Claim
12 words
The composition of claim 4 wherein the processing aid is di-n-hexyl azelate.
Claim 9
Dependent Claim
12 words
The composition of claim 4 wherein the processing aid is diallyl phthalate.
Claim 10
Dependent Claim
12 words
The composition of claim 4 wherein the processing aid is diisopropyl phthalate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-12-28 | 1980-06-28 | 1980-12-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-12-28 | 1984-06-28 | 1984-12-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-12-28 | 1988-06-28 | 1988-12-28 | $7700.00 | Window Closed / Lapsed |