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US3999996A Expired / Lapsed US ⏱️ 0.0 years remaining

Compatible near-portion phototropic glass

Assignee: Schott AG
•
Filing: 1976-04-27
•
Granted: 1976-12-28
•
Expires: 1996-04-27
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Abstract

Abstract Glass as near-portion material for fusion with known phototropic far-portion glasses for multifocal spectacle lenses has a linear thermal expansion coefficient between 45 and 58 × 10 - 7 /° C, a refractive index of n d ≧1.60, a speed of crystallization of less than 0.5 μ/min., and the following composition: ______________________________________ SiO 2 10.0 - 20.0 % by weight B 2 O 3 15.0 - 23.0 % by weight PbO >26.0 - 30.0 % by weight ZnO 3.0 - 5.0 % by weight La 2 O 3 6.0 - 10.0 % by weight Al 2 O 3 12.0 - 17.0 % by weight ZrO 2 0.5 - 3.0 % by weight TiO 2 0.2 - 3.0 % by weight K 2 O 0.1 - 2.0 % by weight Na 2 O 0.1 - 2.0 % by weight Li 2 O 0.1 - 4.0 % by weight ______________________________________ With the provision that:______________________________________sum of SiO 2 + B 2 O 3 is 30.0 - 40.0 % by weightsum of the alkali oxides is 0.2 - 3.0 % by weightsum of Al 2 O 3 + La 2 O 3 is 19.0 - 27.0 % by weightsum of the alkaline earthoxides is 3.0 - 8.0 % by weight, MgO being less than 5 % by weight and BaO being 3 - 8 % by weightsum of ZnO + ZrO 2 + TiO 2 is 3.0 - 6.0 % by weightsum of the oxides of Bi,Ta, Nb, W is 0 - 5.0 % by weight.______________________________________

Inventors

  • 👤 Marga Faulstich
  • 👤 Georg Gliemeroth

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 09:50
CPC Classifications
C; C03; C03C; C03C4/00; C03C4/04; C03C4/06; C03C3/00; C03C3/04; C03C3/062; C03C3/07; C03C3/072; C03C3/074; G; G02; G02B; G02B5/00; G02B5/20; G02B5/22; G02B5/23; G02C; G02C7/00; G02C7/02; G02C7/06; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10S501/903

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 242 words
Glass, suitable as near-portion material for fusion with phototropic far-portion glass for multifocal spectacle lenses, having a linear thermal expansion coefficient between 45 and 58 × 10 - 7 /° C, a refractive index of n d ≧ 1.60, a speed of crystallization of less than 0.5 μ/min. and the following composition: ______________________________________ SiO.sub.2 10.0 - 20.0 % by weight B.sub.2 O.sub.3 15.0 - 23.0 % by weight PbO >26.0 - 30.0 % by weight ZnO 3.0 - 5.0 % by weight La.sub.2 O.sub.3 6.0 - 10.0 % by weight Al.sub.2 O.sub.3 12.0 - 17.0 % by weight ZrO.sub.2 0.5 - 3.0 % by weight TiO.sub.2 0.2 - 3.0 % by weight K.sub.2 O 0.1 - 2.0 % by weight Na.sub.2 O 0.1 - 2.0 % by weight Li.sub.2 O 0.1 - 4.0 % by weight ______________________________________ with the provision that: ______________________________________ sum of SiO.sub.2 + B.sub.2 O.sub.3 is 30.0 - 40.0 % by weight sum of the alkali oxides is 0.2 - 3.0 % by weight sum of Al.sub.2 O.sub.3 + La.sub.2 O.sub.3 is 19.0 - 27.0 % by weight sum of the alkaline earth oxides is 3.0 - 8.0 % by weight, MgO being less than 5 % by weight and BaO being 3 - 8 % by weight sum of ZnO + ZrO.sub.2 + TiO.sub.2 is 3.0 - 6.0 % by weight sum of the oxides of Bi, Ta, Nb, W is 0 - 5.0 % by weight. ______________________________________
Claim 2
Dependent Claim 242 words
Glass, suitable as near-portion material for fusion with phototropic far-portion glass for multifocal spectacle lenses, having a linear thermal expansion coefficient between 45 and 58 × 10 - 7 /° C, a refractive index of n d ≧ 1.60, a speed of crystallization of less than 0.5 μ/min. and the following composition: ______________________________________ SiO.sub.2 10.0 - 20.0 % by weight B.sub.2 O.sub.3 15.0 - 23.0 % by weight PbO >26.0 - 30.0 % by weight ZnO 3.0 - 5.0 % by weight La.sub.2 O.sub.3 6.0 - 10.0 % by weight Al.sub.2 O.sub.3 12.0 - 17.0 % by weight ZrO.sub.2 0.5 - 3.0 % by weight TiO.sub.2 0.2 - 3.0 % by weight K.sub.2 O 0.1 - 2.0 % by weight Na.sub.2 O 0.1 - 2.0 % by weight Li.sub.2 O 0.1 - 4.0 % by weight ______________________________________ with the provision that: ______________________________________ sum of SiO.sub.2 + B.sub.2 O.sub.3 is 30.0 - 40.0 % by weight sum of the alkali oxides is 0.2 - 3.0 % by weight sum of Al.sub.2 O.sub.3 + La.sub.2 O.sub.3 is 19.0 - 27.0 % by weight sum of the alkaline earth oxides is 3.0 - 8.0 % by weight, MgO being less than 5 % by weight and BaO being 3 - 8 % by weight sum of ZnO + ZrO.sub.2 + TiO.sub.2 is 3.0 - 6.0 % by weight sum of the oxides of Bi, Ta, Nb, W is 0 - 5.0 % by weight. ______________________________________
Claim 3
Dependent Claim 69 words
A material according to claim 1, further containing phototropicity-causing substances, as follows: ______________________________________ Ag.sub.2 O 0.1 - 1.8 % by weight CuO 0 - 0.05% by weight CoO 0 - 0.01% by weight ______________________________________ and halogens, which replace the oxygen in the anion portions, ______________________________________ Cl 0.2 - 4.5 % by weight Br + I 0 - 4.0 % by weight F 0 - 4.0 % by weight. ______________________________________
Claim 4
Dependent Claim 17 words
A glass according to claim 1 wherein the concentration of PbO is at least 26.4% by weight.
Claim 5
Dependent Claim 17 words
A glass according to claim 1 wherein the concentration of PbO is at least 26.6% by weight.
Claim 6
Dependent Claim 17 words
A glass according to claim 1 wherein the concentration of PbO is 26.8 to 29.5% by weight.
Claim 7
Dependent Claim 17 words
A glass according to claim 1 wherein the concentration of PbO is 26.8 to 29.3% by weight.
Claim 8
Dependent Claim 20 words
A glass according to claim 1 wherein the La 2 O 3 content is not more than 9.8% by weight.
Claim 9
Dependent Claim 20 words
A glass according to claim 1 wherein the La 2 O 3 content is not more than 9.7% by weight.
Claim 10
Dependent Claim 19 words
A glass according to claim 1 wherein the La 2 O 3 content is 6.5 to 9.5% by weight.
Claim 11
Dependent Claim 19 words
A glass according to claim 1 wherein the La 2 O 3 content is 6.9 to 9.0% by weight.

References Cited (Backward Citations)

US3765913A Cited
US3653933A Cited
US3801336A Cited
US3915723A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-28 1980-06-28 1980-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-28 1984-06-28 1984-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-28 1988-06-28 1988-12-28 $7700.00 Window Closed / Lapsed

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