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US3998948A Expired / Lapsed US ⏱️ 0.0 years remaining

Surface active agent containing hydroxylated alkylsulfinyl chains and composition containing surface active agent having hydroxylated alkylthio and/or hydroxylated alkylsulfinyl chains

Assignee: L'Oréal SA
•
Filing: 1975-06-06
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Granted: 1976-12-21
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Expires: 1995-06-06
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Abstract

Abstract Compounds of the formula: <IMAGE> WHEREIN R is alkyl, alkenyl, alkylaryl or alkylpolyoxyalkylene, n is 1 - 20, one of A or B is hydrogen and the other is -CH2Z where Z is (R'S-) or <IMAGE> and where R' is alkyl or mono- or polyhydroxyalkyl. The compounds are obtained from compounds where -CH2Z is replaced by chloromethyl or bromomethyl by reaction with mercaptan and, if necessary, oxidation of the sulfur. The compounds are useful in pharmaceutical, cosmetic and cleansing compositions.

Inventors

  • 👤 Guy Vanlerberghe
  • 👤 Henri Sebag

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 02:03
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/46; C; C07; C07C; C07C317/00; A61Q; A61Q5/00; A61Q5/06; A61Q5/065; A61Q5/08; A61Q5/10

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 168 words
A composition utilizable in pharmacy, cosmetics or as a cleansing agent comprising in an aqueous or non-aqueous carrier at least one compound of the formula ##STR26## wherein R represents a member selected from the group consisting of alkyl containing 8-30 carbon atoms, alkenyl containing 8-18 carbon atoms, nonyl phenyl, alkyl polyoxyalkylene containing 14-60 carbon atoms and 1-10 oxygen atoms and cycloaliphatic which is the residue of alcohols derived from the hydrogenation of lanolin, one of A and B represents hydrogen and the other a member selected from the group consisting of --CH 2 Z, halomethyl and hydroxy with the proviso that at least 80% thereof be --CH 2 Z wherein Z is selected from the group consisting of R'S- and ##STR27## wherein R' is selected from the group consisting of alkyl, monohydroxyalkyl and polyhydroxyalkyl, containing 1-4 carbon atoms, and n ranges between 1 and about 20, said compound being present in an amount of 0.1 to 25 percent by weight based on the total weight of said composition.
Claim 2
Dependent Claim 168 words
A composition utilizable in pharmacy, cosmetics or as a cleansing agent comprising in an aqueous or non-aqueous carrier at least one compound of the formula ##STR26## wherein R represents a member selected from the group consisting of alkyl containing 8-30 carbon atoms, alkenyl containing 8-18 carbon atoms, nonyl phenyl, alkyl polyoxyalkylene containing 14-60 carbon atoms and 1-10 oxygen atoms and cycloaliphatic which is the residue of alcohols derived from the hydrogenation of lanolin, one of A and B represents hydrogen and the other a member selected from the group consisting of --CH 2 Z, halomethyl and hydroxy with the proviso that at least 80% thereof be --CH 2 Z wherein Z is selected from the group consisting of R'S- and ##STR27## wherein R' is selected from the group consisting of alkyl, monohydroxyalkyl and polyhydroxyalkyl, containing 1-4 carbon atoms, and n ranges between 1 and about 20, said compound being present in an amount of 0.1 to 25 percent by weight based on the total weight of said composition.
Claim 3
Dependent Claim 28 words
The composition of claim 1 wherein R is selected from the group consisting of alkyl, dodecyl, tetradecyl, cetyl, stearyl, polyoxypropylene stearyl, lanolin alcohol radical, nonyl phenyl and 2-octadodecyl.
Claim 4
Dependent Claim 20 words
The composition of claim 1 wherein Z is selected from the group consisting of dihydroxypropyl sulfinyl and hydroxyethyl sulfinyl group.
Claim 5
Dependent Claim 18 words
The composition of claim 3 in which at least 80% of the Z group are dihydroxypropyl sulfinyl radicals.
Claim 6
Dependent Claim 35 words
The composition of claim 1 which also includes an effective amount of a surfactant other than said compound of claim 1, said surfactant being selected from the group consisting of anionic, cationic and non-ionic surfactants.
Claim 7
Dependent Claim 167 words
A composition utilizable in pharmacy, cosmetics or as a cleansing agent comprising in an aqueous or non-aqueous carrier a mixture of compounds having the formula ##STR28## wherein R represents a member selected from the group consisting of alkyl containing 8-30 carbon atoms, alkenyl containing 8-18 carbon atoms, nonyl phenyl, alkyl polyoxyalkylene containing 14-60 carbon atoms and 1-10 oxygen atoms and cycloaliphatic which is the residue of alcohols derived from the hydrogenation of lanolin, one of A and B represents hydrogen and the other a member selected from the group consisting of --CH 2 Z, halomethyl and hydroxy with the proviso that at least 80% thereof be --CH 2 Z wherein Z is selected from the group consisting of R'S- and ##STR29## wherein R' is selected from the group consisting of alkyl, monohydroxyalkyl and polyhydroxyalkyl, containing 1-4 carbon atoms and n ranges from 1-10, said mixture of compounds being present in an amount of 0.1 to 25 percent by weight based on the total weight of said composition.
Claim 8
Dependent Claim 167 words
A composition utilizable in pharmacy, cosmetics or as a cleansing agent comprising in an aqueous or non-aqueous carrier a mixture of compounds having the formula ##STR28## wherein R represents a member selected from the group consisting of alkyl containing 8-30 carbon atoms, alkenyl containing 8-18 carbon atoms, nonyl phenyl, alkyl polyoxyalkylene containing 14-60 carbon atoms and 1-10 oxygen atoms and cycloaliphatic which is the residue of alcohols derived from the hydrogenation of lanolin, one of A and B represents hydrogen and the other a member selected from the group consisting of --CH 2 Z, halomethyl and hydroxy with the proviso that at least 80% thereof be --CH 2 Z wherein Z is selected from the group consisting of R'S- and ##STR29## wherein R' is selected from the group consisting of alkyl, monohydroxyalkyl and polyhydroxyalkyl, containing 1-4 carbon atoms and n ranges from 1-10, said mixture of compounds being present in an amount of 0.1 to 25 percent by weight based on the total weight of said composition.
Claim 9
Dependent Claim 122 words
A mixture of compounds of the formula ##STR30## wherein R represents a member selected from the group consisting of alkyl containing 8-30 carbon atoms, alkenyl containing 8-18 carbon atoms, nonyl phenyl, alkyl polyoxyalkylene containing 14-60 carbon atoms and 1-10 oxygen atoms and cycloaliphatic which is the residue of alcohols derived from the hydrogenation of lanolin, one of A and B represents hydrogen and the other a member selected from the group consisting of --CH 2 Z, halomethyl and hydroxy with the proviso that at least 80% thereof be --CH 2 Z wherein Z is ##STR31## wherein R 1 is selected from the group consisting of alkyl, monohydroxyl alkyl and polyhydroxylalkyl, containing 1-4 carbon atoms and n ranges between 1 and about 20.
Claim 10
Dependent Claim 122 words
A mixture of compounds of the formula ##STR30## wherein R represents a member selected from the group consisting of alkyl containing 8-30 carbon atoms, alkenyl containing 8-18 carbon atoms, nonyl phenyl, alkyl polyoxyalkylene containing 14-60 carbon atoms and 1-10 oxygen atoms and cycloaliphatic which is the residue of alcohols derived from the hydrogenation of lanolin, one of A and B represents hydrogen and the other a member selected from the group consisting of --CH 2 Z, halomethyl and hydroxy with the proviso that at least 80% thereof be --CH 2 Z wherein Z is ##STR31## wherein R 1 is selected from the group consisting of alkyl, monohydroxyl alkyl and polyhydroxylalkyl, containing 1-4 carbon atoms and n ranges between 1 and about 20.
Claim 11
Dependent Claim 15 words
The compounds of claim 7 wherein Z represents a dihydroxypropyl sulfinyl or hydroxyethyl sulfinyl group.
Claim 12
Dependent Claim 27 words
The compounds of claim 7 wherein R is selected from the group consisting of oleyl, dodecyl, tetradecyl, cetyl, stearyl, polyoxypropylene stearyl, lanolin alcohol radical, nonyl-phenyl and 2-octyldodecyl.

References Cited (Backward Citations)

SU175958A1 Cited
US2588771A Cited
US2776997A Cited
US2926118A Cited
US3739031A Cited
US3427248A Cited
US3661851A Cited
US3662003A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-21 1980-06-21 1980-12-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-21 1984-06-21 1984-12-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-21 1988-06-21 1988-12-21 $7700.00 Window Closed / Lapsed

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