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US3998908A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the manufacture of stabilized polyester-polycarbonate copolymers

Assignee: DuPont de Nemours Deutschland GmbH
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Filing: 1974-11-18
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Granted: 1976-12-21
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Expires: 1994-11-18
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Abstract

Abstract The melt phase reaction and/or solid phase reaction for the manufacture of polyesters is accelerated by adding a polycarbonate and a phosphorus containing stabilizer to the reaction mixture before completion of the reaction.

Inventors

  • 👤 Lothar Buxbaum

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 17:13
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/64; C08L; C08L67/00; C08L67/02

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 175 words
An improved process for the manufacture of thermoplastic polyesters containing carbonate groups and a stabilizer containing phosphorus from linear polyester precondensates which still contain hydroxyl groups, characterized in that linear polyesters containing hydroxyl groups and having a relative viscosity of at least 1.30, measured at 30° C on a 1% strength solution in equal parts of phenol and tetrachloroethane, are allowed to react with 0.01 to 45% by weight, based on the total amount, of a polycarbonate built up from diols of which the hydroxyl groups are bonded to one or different aromatic radicals and which polycarbonate has a degree of polycondensation of at least 10, in the melt phase or solid phase, at a temperature of 170° to 320° C and in vacuo, in a stream of inert gas, or in vacuo and a stream of inert gas wherein the improvement comprises increasing the relative viscosity of said thermoplastic polyesters by adding 1 to 15% by weight, based on the polyester precondensate, of a stabilizer containing phosphorus simultaneously with the addition of the polycarbonate.
Claim 2
Dependent Claim 175 words
An improved process for the manufacture of thermoplastic polyesters containing carbonate groups and a stabilizer containing phosphorus from linear polyester precondensates which still contain hydroxyl groups, characterized in that linear polyesters containing hydroxyl groups and having a relative viscosity of at least 1.30, measured at 30° C on a 1% strength solution in equal parts of phenol and tetrachloroethane, are allowed to react with 0.01 to 45% by weight, based on the total amount, of a polycarbonate built up from diols of which the hydroxyl groups are bonded to one or different aromatic radicals and which polycarbonate has a degree of polycondensation of at least 10, in the melt phase or solid phase, at a temperature of 170° to 320° C and in vacuo, in a stream of inert gas, or in vacuo and a stream of inert gas wherein the improvement comprises increasing the relative viscosity of said thermoplastic polyesters by adding 1 to 15% by weight, based on the polyester precondensate, of a stabilizer containing phosphorus simultaneously with the addition of the polycarbonate.
Claim 3
Dependent Claim 46 words
A process according to claim 1, characterised in that a polyester precondensate is employed which contains at least 80 mol % of terephthalic acid radicals and at least 80 mol % of radicals of an aliphatic diol with 2 to 10 carbon atoms or of 1,4-dihydroxymethylcyclohexane.
Claim 4
Dependent Claim 18 words
A process according to claim 2, characterised in that the aliphatic diol contains 2 to 4 carbon atoms.
Claim 5
Dependent Claim 27 words
A process according to claim 2, characterised in that the polyester precondensate is built up from terephthalic acid and linear alkylenediols with 2 to 4 carbon atoms.
Claim 6
Dependent Claim 23 words
A process according to claim 1, characterised in that the polyester precondensate contains co-condensed diol radicals which possess secondary or phenolic alcohol groups.
Claim 7
Dependent Claim 27 words
A process according to claim 1, characterised in that the polyester precondensate contains at least 50% of hydroxyl end groups, based on the total end groups present.
Claim 8
Dependent Claim 20 words
A process according to claim 1, characterised in that the polyester precondensate has a relative viscosity of 1.5 to 3.5.
Claim 9
Dependent Claim 20 words
A process according to claim 7, characterised in that the polyester precondensate has a relative viscosity of 1.6 to 2.5.
Claim 10
Dependent Claim 16 words
A process according to claim 1, characterised in that 2,2-(4,4'-dihydroxydiphenyl)-propane polycarbonate is used as the polycarbonate.
Claim 11
Dependent Claim 20 words
A process according to claim 1, characterised in that the degree of polycondensation of the polycarbonate is at least 100.
Claim 12
Dependent Claim 19 words
A process according to claim 1, characterised in that 0.01 to 30% by weight of a polycarbonate are added.
Claim 13
Dependent Claim 19 words
A process according to claim 11, characterised in that 0.1 to 20% by weight of a polycarbonate are added.
Claim 14
Dependent Claim 19 words
A process according to claim 12, characterised in that 0.1 to 3% by weight of a polycarbonate are added.
Claim 15
Dependent Claim 22 words
A process according to claim 1, characterised in that the reaction in the melt phase is carried out continuously in an extruder.
Claim 16
Dependent Claim 17 words
A process according to claim 1, characterised in that polyester scrap is employed as the polyester precondensate.
Claim 17
Dependent Claim 18 words
A process according to claim 1 wherein the stabilizer containing phosphorus is a triaryl phosphate or triaryl phosphite.
Claim 18
Dependent Claim 27 words
A process according to claim 1 wherein the stabilizer containing phosphorus is selected from the group consisting of triphenyl phosphate, tris-nonylphenyl phosphate, triphenyl phosphite and bis(n-octadecyl) 3,5-di-tert-butyl-4-hydroxybenzylphosphonate.

References Cited (Backward Citations)

US3000849A Cited
US3218372A Cited
GB964485A Cited
US3281505A Cited
US3426100A Cited
FR1589020A Cited
BE722208A Cited
US3557053A Cited
US3563848A Cited
US3746758A Cited
US3752866A Cited
US3819759A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-21 1980-06-21 1980-12-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-21 1984-06-21 1984-12-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-21 1988-06-21 1988-12-21 $7700.00 Window Closed / Lapsed

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