US3998908A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the manufacture of stabilized polyester-polycarbonate copolymers
Assignee: DuPont de Nemours Deutschland GmbH
•
Filing: 1974-11-18
•
Granted: 1976-12-21
•
Expires: 1994-11-18
Abstract
Abstract The melt phase reaction and/or solid phase reaction for the manufacture of polyesters is accelerated by adding a polycarbonate and a phosphorus containing stabilizer to the reaction mixture before completion of the reaction.
Inventors
- 👤 Lothar Buxbaum
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 17:13
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/64; C08L; C08L67/00; C08L67/02
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
175 words
An improved process for the manufacture of thermoplastic polyesters containing carbonate groups and a stabilizer containing phosphorus from linear polyester precondensates which still contain hydroxyl groups, characterized in that linear polyesters containing hydroxyl groups and having a relative viscosity of at least 1.30, measured at 30° C on a 1% strength solution in equal parts of phenol and tetrachloroethane, are allowed to react with 0.01 to 45% by weight, based on the total amount, of a polycarbonate built up from diols of which the hydroxyl groups are bonded to one or different aromatic radicals and which polycarbonate has a degree of polycondensation of at least 10, in the melt phase or solid phase, at a temperature of 170° to 320° C and in vacuo, in a stream of inert gas, or in vacuo and a stream of inert gas wherein the improvement comprises increasing the relative viscosity of said thermoplastic polyesters by adding 1 to 15% by weight, based on the polyester precondensate, of a stabilizer containing phosphorus simultaneously with the addition of the polycarbonate.
Claim 2
Dependent Claim
175 words
An improved process for the manufacture of thermoplastic polyesters containing carbonate groups and a stabilizer containing phosphorus from linear polyester precondensates which still contain hydroxyl groups, characterized in that linear polyesters containing hydroxyl groups and having a relative viscosity of at least 1.30, measured at 30° C on a 1% strength solution in equal parts of phenol and tetrachloroethane, are allowed to react with 0.01 to 45% by weight, based on the total amount, of a polycarbonate built up from diols of which the hydroxyl groups are bonded to one or different aromatic radicals and which polycarbonate has a degree of polycondensation of at least 10, in the melt phase or solid phase, at a temperature of 170° to 320° C and in vacuo, in a stream of inert gas, or in vacuo and a stream of inert gas wherein the improvement comprises increasing the relative viscosity of said thermoplastic polyesters by adding 1 to 15% by weight, based on the polyester precondensate, of a stabilizer containing phosphorus simultaneously with the addition of the polycarbonate.
Claim 3
Dependent Claim
46 words
A process according to claim 1, characterised in that a polyester precondensate is employed which contains at least 80 mol % of terephthalic acid radicals and at least 80 mol % of radicals of an aliphatic diol with 2 to 10 carbon atoms or of 1,4-dihydroxymethylcyclohexane.
Claim 4
Dependent Claim
18 words
A process according to claim 2, characterised in that the aliphatic diol contains 2 to 4 carbon atoms.
Claim 5
Dependent Claim
27 words
A process according to claim 2, characterised in that the polyester precondensate is built up from terephthalic acid and linear alkylenediols with 2 to 4 carbon atoms.
Claim 6
Dependent Claim
23 words
A process according to claim 1, characterised in that the polyester precondensate contains co-condensed diol radicals which possess secondary or phenolic alcohol groups.
Claim 7
Dependent Claim
27 words
A process according to claim 1, characterised in that the polyester precondensate contains at least 50% of hydroxyl end groups, based on the total end groups present.
Claim 8
Dependent Claim
20 words
A process according to claim 1, characterised in that the polyester precondensate has a relative viscosity of 1.5 to 3.5.
Claim 9
Dependent Claim
20 words
A process according to claim 7, characterised in that the polyester precondensate has a relative viscosity of 1.6 to 2.5.
Claim 10
Dependent Claim
16 words
A process according to claim 1, characterised in that 2,2-(4,4'-dihydroxydiphenyl)-propane polycarbonate is used as the polycarbonate.
Claim 11
Dependent Claim
20 words
A process according to claim 1, characterised in that the degree of polycondensation of the polycarbonate is at least 100.
Claim 12
Dependent Claim
19 words
A process according to claim 1, characterised in that 0.01 to 30% by weight of a polycarbonate are added.
Claim 13
Dependent Claim
19 words
A process according to claim 11, characterised in that 0.1 to 20% by weight of a polycarbonate are added.
Claim 14
Dependent Claim
19 words
A process according to claim 12, characterised in that 0.1 to 3% by weight of a polycarbonate are added.
Claim 15
Dependent Claim
22 words
A process according to claim 1, characterised in that the reaction in the melt phase is carried out continuously in an extruder.
Claim 16
Dependent Claim
17 words
A process according to claim 1, characterised in that polyester scrap is employed as the polyester precondensate.
Claim 17
Dependent Claim
18 words
A process according to claim 1 wherein the stabilizer containing phosphorus is a triaryl phosphate or triaryl phosphite.
Claim 18
Dependent Claim
27 words
A process according to claim 1 wherein the stabilizer containing phosphorus is selected from the group consisting of triphenyl phosphate, tris-nonylphenyl phosphate, triphenyl phosphite and bis(n-octadecyl) 3,5-di-tert-butyl-4-hydroxybenzylphosphonate.
References Cited (Backward Citations)
US3000849A
Cited
US3218372A
Cited
GB964485A
Cited
US3281505A
Cited
US3426100A
Cited
FR1589020A
Cited
BE722208A
Cited
US3557053A
Cited
US3563848A
Cited
US3746758A
Cited
US3752866A
Cited
US3819759A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-12-21 | 1980-06-21 | 1980-12-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-12-21 | 1984-06-21 | 1984-12-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-12-21 | 1988-06-21 | 1988-12-21 | $7700.00 | Window Closed / Lapsed |