US3998655A
Expired / Lapsed
US
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Method for cleansing vinyl chloride polymerization reactors
Assignee: Societa Italiana Resine SpA SIR
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Filing: 1975-07-23
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Granted: 1976-12-21
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Expires: 1995-07-23
Abstract
Abstract Incrustations of vinyl chloride polymers and copolymers are removed from the polymerization reactors by dissolving said incrustations at a temperature above 60° C in a solvent chosen from the substituted amides up to a polymeric compound content in the resulting solution not exceeding 7% by weight, concentrating the resulting solution to a 10-30 wt. % polymeric compound content by evaporating a mixture of solvent and water, extruding the concentrated solution into an aqueous coagulating bath and recovering the spun product. The solvent is recovered by fractional distillation of the vaporized mixture and of the solvent-enriched coagulating bath.
Inventors
- 👤 Gianni Benetta
- 👤 Francesco Testa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 06:14
CPC Classifications
B; B08; B08B; B08B3/00; B08B3/04; B08B3/08
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
185 words
A method for cleansing reactors used for polymerizing and copolymerizing vinyl chloride, which comprises: dissolving polymeric incrustations including residual water, formed during polymerization and copolymerization of vinyl chloride on the inner walls of the reactors and on the relative equipments, with a solvent chosen from among the substituted amides, by contacting said incrustations with the solvent at a temperature above 60° C, said dissolving being carried out until the content in polymeric compound in the solution resulting from said dissolving reaches a value not exceeding 7% by weight; concentrating the resulting solution by evaporation of a mixture of solvent and water, thereby to obtain a residual solution having a concentration in polymeric compound of from 10 to 30% by weight; subjecting the vaporized mixture to fractional distillation, thereby to recover the solvent present in said mixture for further dissolution operations; extruding the residual solution in the form of threads into an aqueous coagulating bath, thus extracting the solvent from said threads, and recovering the polymeric compound in the form of a spun product and the extracted solvent by fractional distillation from the solvent-enriched coagulating bath.
Claim 2
Independent Claim
185 words
A method for cleansing reactors used for polymerizing and copolymerizing vinyl chloride, which comprises: dissolving polymeric incrustations including residual water, formed during polymerization and copolymerization of vinyl chloride on the inner walls of the reactors and on the relative equipments, with a solvent chosen from among the substituted amides, by contacting said incrustations with the solvent at a temperature above 60° C, said dissolving being carried out until the content in polymeric compound in the solution resulting from said dissolving reaches a value not exceeding 7% by weight; concentrating the resulting solution by evaporation of a mixture of solvent and water, thereby to obtain a residual solution having a concentration in polymeric compound of from 10 to 30% by weight; subjecting the vaporized mixture to fractional distillation, thereby to recover the solvent present in said mixture for further dissolution operations; extruding the residual solution in the form of threads into an aqueous coagulating bath, thus extracting the solvent from said threads, and recovering the polymeric compound in the form of a spun product and the extracted solvent by fractional distillation from the solvent-enriched coagulating bath.
Claim 3
Dependent Claim
33 words
The method of claim 1, wherein said substituted amides have a boiling point higher than 100° C, are miscible with water in any proportion and completely separable from the latter by fractional distillation.
Claim 4
Dependent Claim
21 words
The method of claim 1, wherein said substituted amides are selected from the group consisting of dimethylformamide, dimethylacetamide and substituted carbamides.
Claim 5
Dependent Claim
20 words
The method of claim 1, wherein said substituted amides are selected from the group consisting of dimethylformamide, dimethylacetamide and tetramethylurea.
Claim 6
Dependent Claim
22 words
The method of claim 1, wherein the solvent is contacted with the incrustations at a temperature of from 60° to 110° C.
Claim 7
Dependent Claim
22 words
The method of claim 1, wherein the solvent is contacted with the incrustations at a temperature of from 80° to 110° C.
Claim 8
Dependent Claim
27 words
The method of claim 1, wherein a tin mercaptide is present in the solvent in an amount of from 0.05 to 0.5% by weight before said dissolving.
Claim 9
Dependent Claim
31 words
The method of claim 1, wherein the dissolving is carried out until the content of polymeric compound in the resulting solution reaches a value of from 3 to 7% by weight.
Claim 10
Dependent Claim
23 words
The method of claim 1, wherein the fractional distillation is carried out at a pressure in the range from 1 to 0.2 atmospheres.
Claim 11
Dependent Claim
14 words
The method of claim 9, wherein the fractional distillation is carried out under reflux.
Claim 12
Dependent Claim
42 words
The method of claim 1, wherein the fractional distillation is carried out in a column having from 10 to 50 plates, feeding the said mixture at a point situated between the third and the seventh plate from the bottom of the column.
Claim 13
Dependent Claim
48 words
The method of claim 1, wherein the residual solution is extruded through a spinneret of from 100 to 500 microns in hole diameter into an aqueous coagulating bath at a temperature of from 20° C to 100° C, at an extrusion speed of from 1 to 8 m/minute.
Claim 14
Dependent Claim
22 words
The method of claim 1, wherein the residence time of the threads in the coagulating bath is from 5 to 60 seconds.
Claim 15
Dependent Claim
26 words
The method of claim 1, wherein said substituted amide solvent is miscible in water in any proportion and is completely separable from water by fractional distillation.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-12-21 | 1980-06-21 | 1980-12-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-12-21 | 1984-06-21 | 1984-12-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-12-21 | 1988-06-21 | 1988-12-21 | $7700.00 | Window Closed / Lapsed |