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US3995992A Expired / Lapsed US ⏱️ 0.0 years remaining

Transfer printing process for dyeing and printing organic material which can be dyed with cationic dyes

Assignee: Novartis AG
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Filing: 1974-09-30
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Granted: 1976-12-07
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Expires: 1994-09-30
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Abstract

Abstract A process for dyeing and printing organic material which can be dyed with cationic dyes by the transfer printing process, which comprises the use of a auxiliary carrier which contains at least one disperse and/or cationic dye that is converted into the vapor state at atmospheric pressure and at a temperature between 150° C and 220° C, and at least one organic compound as transfer promoter with a vapor pressure higher than 10.sup. -5 Torr at 200° C.

Inventors

  • 👤 Raymond DeFago
  • 👤 Paul Schaffluetzel
  • 👤 Jaroslav Haase

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 22:01
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/382; B41M5/385; C; C09; C09D; C09D11/00; C09D11/02; C09D11/03; D; D06; D06L; D06L4/00; D06L4/60; D06L4/643; D06P; D06P1/00; D06P1/44; D06P1/64; D06P1/642; D06P5/00; D06P5/003; D06P5/004; B41M5/3852; B41M5/3854; B41M5/388; B41M5/39; Y; Y10; Y10S; Y10S8/00; Y10S8/92; Y10S8/927

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 255 words
In a process for the dyeing or printing of organic material by the transfer printing process which comprises bringing the surface of an inert carrier sheet treated with a printing ink into contact with the surface of an organic material which can be dyed or printed with cationic dyes, subjecting the carrier and organic material to heat treatment for a time and at a temperature sufficient to achieve dyeing or printing of the organic material and separating the organic material from the said inert carrier, the improvement according to which the printing ink for treating the inert carrier comprises a dispersion or solution of at least one member of the group of disperse dyestuffs, cationic dyestuffs, and mixtures thereof said dyestuffs being from among those which are converted to the vapour state at atmospheric pressure and at a temperature of between 150° C and 220° C and at least one organic compound as transfer promotor having a vapour pressure higher than 10 - 5 Torr at 200° C and being selected from the group of a. A compound of the formula ##STR65## b. A compound of the formula ##STR66## wherein "alkylene" is of 1 to 4 carbon atoms, R represents alkyl of 1 to 4 carbon atoms, α-hydroxyethyl, α-acetoxyethyl, cyclohexyl, phenyl, methylphenyl, dimethylphenyl, chlorophenyl, or formyl, and c. A compound of the formula ##STR67## wherein X represents oxygen or sulfur, Y represents alkylene which bonds the group ##STR68## to a ring with 5 to 7 members, and "alkylene" is of 1 to 4 carbon atoms.
Claim 2
Dependent Claim 255 words
In a process for the dyeing or printing of organic material by the transfer printing process which comprises bringing the surface of an inert carrier sheet treated with a printing ink into contact with the surface of an organic material which can be dyed or printed with cationic dyes, subjecting the carrier and organic material to heat treatment for a time and at a temperature sufficient to achieve dyeing or printing of the organic material and separating the organic material from the said inert carrier, the improvement according to which the printing ink for treating the inert carrier comprises a dispersion or solution of at least one member of the group of disperse dyestuffs, cationic dyestuffs, and mixtures thereof said dyestuffs being from among those which are converted to the vapour state at atmospheric pressure and at a temperature of between 150° C and 220° C and at least one organic compound as transfer promotor having a vapour pressure higher than 10 - 5 Torr at 200° C and being selected from the group of a. A compound of the formula ##STR65## b. A compound of the formula ##STR66## wherein "alkylene" is of 1 to 4 carbon atoms, R represents alkyl of 1 to 4 carbon atoms, α-hydroxyethyl, α-acetoxyethyl, cyclohexyl, phenyl, methylphenyl, dimethylphenyl, chlorophenyl, or formyl, and c. A compound of the formula ##STR67## wherein X represents oxygen or sulfur, Y represents alkylene which bonds the group ##STR68## to a ring with 5 to 7 members, and "alkylene" is of 1 to 4 carbon atoms.
Claim 3
Dependent Claim 41 words
A process according to claim 1 wherein the transfer promotor is a compound from the group of (a) a compound of the formula ##STR69## wherein R represents ##STR70## b. a compound of the formula ##STR71## wherein X represents oxygen or sulphur.
Claim 4
Dependent Claim 35 words
A process according to claim 1 wherein the carrier and organic material are subjected to a heat treatment of 120° C to 210° C over the course of 5 to 6 seconds under mechanical pressure.
Claim 5
Dependent Claim 36 words
A process according to claim 1 wherein disperse dyes are employed which are transferred to at least 50% in less than 60 seconds under atmospheric pressure and at a temperature between 150° C and 220° C.
Claim 6
Dependent Claim 27 words
A process according to claim 1 wherein cationic dyes in the form of their salts with acids with a pK s value greater than 3 are employed.
Claim 7
Dependent Claim 15 words
A process according to claim 1 wherein the organic material comprises polyacrylonitrile or modacryl fibers.
Claim 8
Dependent Claim 34 words
A process according to claim 1 wherein the carrier and organic material to be dyed are subjected to a heat treatment of 60° to 190° C over the course of 5 to 30 seconds.
Claim 9
Dependent Claim 209 words
In a carrier for use in the transfer printing process said carrier comprising an inert sheet selected from the group consisting of paper, aluminum foil and steel having at least one face thereof treated with a printing ink, the improvement according to which the printing ink composition comprises a dispersion or solution of at least one member of the group of disperse dyestuffs, cationic dyestuffs and mixtures thereof said dyestuffs being from among those which are converted to the vapour state at atmospheric pressure and at a temperature of between 150° C and 220° C, and there is present in the composition at least one organic compound as transfer promotor having a vapour pressure higher than 10 - Torr at 200° C and being selected from the group of a. A compound of the formula ##STR72## b. A compound of the formula ##STR73## wherein "alkylene" is of 1 to 4 carbon atoms, R represents alkyl of 1 to 4 carbon atoms, α-hydroxyethyl, α-acetoxyethyl, cyclohexyl, phenyl, methylphenyl, dimethylphenyl, chlorophenyl, or formyl, and c. A compound of the formula ##STR74## wherein X represents oxygen or sulfur, Y represents alkylene which bonds the group ##STR75## to a ring with 5 to 7 members, and "alkylene" is of 1 to 4 carbon atoms.
Claim 10
Dependent Claim 209 words
In a carrier for use in the transfer printing process said carrier comprising an inert sheet selected from the group consisting of paper, aluminum foil and steel having at least one face thereof treated with a printing ink, the improvement according to which the printing ink composition comprises a dispersion or solution of at least one member of the group of disperse dyestuffs, cationic dyestuffs and mixtures thereof said dyestuffs being from among those which are converted to the vapour state at atmospheric pressure and at a temperature of between 150° C and 220° C, and there is present in the composition at least one organic compound as transfer promotor having a vapour pressure higher than 10 - Torr at 200° C and being selected from the group of a. A compound of the formula ##STR72## b. A compound of the formula ##STR73## wherein "alkylene" is of 1 to 4 carbon atoms, R represents alkyl of 1 to 4 carbon atoms, α-hydroxyethyl, α-acetoxyethyl, cyclohexyl, phenyl, methylphenyl, dimethylphenyl, chlorophenyl, or formyl, and c. A compound of the formula ##STR74## wherein X represents oxygen or sulfur, Y represents alkylene which bonds the group ##STR75## to a ring with 5 to 7 members, and "alkylene" is of 1 to 4 carbon atoms.
Claim 11
Dependent Claim 20 words
A carrier according to claim 8 wherein the printing ink composition contains a cellulose ether or cellulose ester as binder.
Claim 12
Dependent Claim 21 words
A carrier according to claim 8 wherein the printing ink composition is an aqueous composition which contains polyvinyl alcohol as binder.

References Cited (Backward Citations)

US2589208A Cited
US2952653A Cited
US2963507A Cited
US3020310A Cited
US3051736A Cited
US3114588A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-07 1980-06-07 1980-12-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-07 1984-06-07 1984-12-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-07 1988-06-07 1988-12-07 $7700.00 Window Closed / Lapsed

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