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US3992176A Expired / Lapsed US ⏱️ 0.0 years remaining

Dry scrubbing tar and fluoride laden gases

Assignee: Kaiser Aluminum and Chemical Corp
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Filing: 1974-11-06
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Granted: 1976-11-16
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Expires: 1994-11-06
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Abstract

Abstract This invention relates to a method of treating tar and fluoride laden gases for the removal of tar and fluorides therefrom, particularly the cell off-gases from a Soderberg reduction cell, an anode baking furnace and the like wherein reduction-grade alumina is entrained in the tar and fluoride laden gases and then this mixture is passed through a foraminous plate above which is maintained a turbulent mass of alumina.

Inventors

  • 👤 Philip W. Bohne
  • 👤 Michael R. Cuccia
  • 👤 Tom S. Moughon, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 11:43
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/02; B01D53/06; B01D53/10; B01D53/12

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 121 words
A method of treating a gaseous stream containing fluoride and heavily laden with condensable carbonaceous matter comprising: a. introducing pulverulent alumina into a moving gaseous stream containing gaseous fluoride and heavily laden with condensable carbonaceous matter to entrain therein said alumina and to cause said carbonaceous matter to condense onto said alumina; b. directing said alumina containing gaseous stream into a chamber containing therein a foraminous plate and having pulverulent alumina disposed above said foraminous plate; c. passing said alumina-containing gaseous stream through said foraminous plate so as to maintain the alumina above said plate in a turbulent condition, thereby removing essentially all gaseous fluoride from the gaseous stream; and d. subsequently removing essentially all particulate matter from said gaseous stream.
Claim 2
Independent Claim 121 words
A method of treating a gaseous stream containing fluoride and heavily laden with condensable carbonaceous matter comprising: a. introducing pulverulent alumina into a moving gaseous stream containing gaseous fluoride and heavily laden with condensable carbonaceous matter to entrain therein said alumina and to cause said carbonaceous matter to condense onto said alumina; b. directing said alumina containing gaseous stream into a chamber containing therein a foraminous plate and having pulverulent alumina disposed above said foraminous plate; c. passing said alumina-containing gaseous stream through said foraminous plate so as to maintain the alumina above said plate in a turbulent condition, thereby removing essentially all gaseous fluoride from the gaseous stream; and d. subsequently removing essentially all particulate matter from said gaseous stream.
Claim 3
Independent Claim 124 words
A method of treating a gaseous stream containing fluoride and heavily laden with tar and/or condensable carbonaceous matter comprising: a. introducing pulverulent alumina into a moving gaseous stream of said effluent to entrain therein the pulverulent alumina and to cause said tar and/or carbonaceous matter to deposit and/or condense onto said alumina; b. directing the alumina containing gaseous stream to a chamber containing therein a foraminous plate and having pulverulent alumina disposed above said foraminous plate; c. passing the alumina containing gaseous stream through the foraminous plate so as to maintain the alumina above the plate in a turbulent condition and to thereby remove essentially all gaseous fluoride from the gaseous stream; and d. subsequently removing essentially all particulate matter from the gaseous stream.
Claim 4
Independent Claim 124 words
A method of treating a gaseous stream containing fluoride and heavily laden with tar and/or condensable carbonaceous matter comprising: a. introducing pulverulent alumina into a moving gaseous stream of said effluent to entrain therein the pulverulent alumina and to cause said tar and/or carbonaceous matter to deposit and/or condense onto said alumina; b. directing the alumina containing gaseous stream to a chamber containing therein a foraminous plate and having pulverulent alumina disposed above said foraminous plate; c. passing the alumina containing gaseous stream through the foraminous plate so as to maintain the alumina above the plate in a turbulent condition and to thereby remove essentially all gaseous fluoride from the gaseous stream; and d. subsequently removing essentially all particulate matter from the gaseous stream.
Claim 5
Dependent Claim 40 words
The method of claim 2 including discharging alumina above said foraminous plate from said chamber and recycling from about 10 to 80% of said discharged alumina into the moving gaseous stream before the stream is passed through the foraminous plate.
Claim 6
Dependent Claim 32 words
The method of claim 3 wherein said recycled alumina amounts to about 10 to 100% of the alumina entrained in the moving gaseous stream before the stream passes through the foraminous plate.
Claim 7
Dependent Claim 23 words
The method of claim 2 wherein the particulate matter is removed from the gaseous stream by passing the stream through a filtering surface.
Claim 8
Dependent Claim 24 words
The method of claim 2 wherein said alumina containing gaseous stream is maintained at a velocity of about 50 to 150 feet per second.
Claim 9
Dependent Claim 29 words
The method of claim 2 wherein said gaseous stream containing fluoride and condensable carbonaceous matter is the off-gas from an aluminum reduction cell having a horizontal stud Soderberg anode.
Claim 10
Dependent Claim 28 words
The method of claim 2 wherein the particulate matter removed from said gaseous stream is returned to the turbulent mass of pulverulent alumina maintained above the foraminous plate.
Claim 11
Dependent Claim 35 words
The method of claim 2 wherein at least a portion of the aluminum above said plate is removed therefrom and treated at high temperature and under oxidizing conditions to remove carbonaceous matter from said alumina.
Claim 12
Independent Claim 151 words
A method of removing essentially all of the fluoride and tar and/or condensable carbonaceous matter from gaseous effluent from an aluminum reduction cell having a Soderberg-type electrode comprising a. withdrawing from the reduction cell a stream of gaseous effluent containing fluoride and tar and/or condensable carbonaceous matter; b. entraining pulverulent alumina into the essentially untreated gaseous stream withdrawn from the reduction cell to cause at least pat of the tar and/or carbonaceous matter therein to deposit and/or condense onto said entrained alumina; c. directing the alumina-containing gaseous stream to a chamber containing therein a foraminous plate and having pulverulent alumina disposed above the foraminous plate; d. passing the alumina-containing gaseous stream through the foraminous plate so as to maintain the alumina above the plate in a turbulent condition and thereby remove essentially all gaseous fluoride from the gaseous stream; and e. subsequently removing essentially all particulate matter from the gaseous stream.
Claim 13
Independent Claim 151 words
A method of removing essentially all of the fluoride and tar and/or condensable carbonaceous matter from gaseous effluent from an aluminum reduction cell having a Soderberg-type electrode comprising a. withdrawing from the reduction cell a stream of gaseous effluent containing fluoride and tar and/or condensable carbonaceous matter; b. entraining pulverulent alumina into the essentially untreated gaseous stream withdrawn from the reduction cell to cause at least pat of the tar and/or carbonaceous matter therein to deposit and/or condense onto said entrained alumina; c. directing the alumina-containing gaseous stream to a chamber containing therein a foraminous plate and having pulverulent alumina disposed above the foraminous plate; d. passing the alumina-containing gaseous stream through the foraminous plate so as to maintain the alumina above the plate in a turbulent condition and thereby remove essentially all gaseous fluoride from the gaseous stream; and e. subsequently removing essentially all particulate matter from the gaseous stream.
Claim 14
Independent Claim 148 words
A method of removing essentially all of the fluoride and tar and/or condensable carbonaceous matter from gaseous effluent from an anode baking furnace comprising a. withdrawing from the anode baking furnace a stream of gaseous effluent containing fluoride and tar and/or condensable carbonaceous matter; b. entraining pulverulent alumina into the essentially untreated gaseous stream withdrawn from the anode baking furnace to cause at least part of the tar and/or carbonaceous matter to deposit and/or condense onto said entrained alumina; c. directing the alumina-containing gaseous stream to a chamber containing therein a foraminous plate and having pulverulent alumina disposed above the foraminous plate; d. passing the alumina-containing gaseous stream through the foraminous plate so as to maintain the alumina above the plate in a turbulent condition and thereby remove essentially all gaseous fluorides from the gaseous stream; and e. subsequently removing essentially all particulate matter from the gaseous stream.
Claim 15
Independent Claim 148 words
A method of removing essentially all of the fluoride and tar and/or condensable carbonaceous matter from gaseous effluent from an anode baking furnace comprising a. withdrawing from the anode baking furnace a stream of gaseous effluent containing fluoride and tar and/or condensable carbonaceous matter; b. entraining pulverulent alumina into the essentially untreated gaseous stream withdrawn from the anode baking furnace to cause at least part of the tar and/or carbonaceous matter to deposit and/or condense onto said entrained alumina; c. directing the alumina-containing gaseous stream to a chamber containing therein a foraminous plate and having pulverulent alumina disposed above the foraminous plate; d. passing the alumina-containing gaseous stream through the foraminous plate so as to maintain the alumina above the plate in a turbulent condition and thereby remove essentially all gaseous fluorides from the gaseous stream; and e. subsequently removing essentially all particulate matter from the gaseous stream.

References Cited (Backward Citations)

US3503184A Cited
US3827955A Cited
US3790143A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-11-16 1980-05-17 1980-11-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-11-16 1984-05-17 1984-11-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-11-16 1988-05-17 1988-11-16 $7700.00 Window Closed / Lapsed

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