Hydrotreating of petroleum distillates using shaped catalyst particles

Claim 2

A process for hydrotreating a petroleum distillate to remove sulfur-containing and nitrogen-containing components with a porous catalyst particle of given length and polylobal cross-sectional shape characterized by a concavity index of greater than 1.0, a void fraction in the range of about 0.25 to 0.60; said particle having a ratio of geometric volume to geometric surface in the range of about 0.001 to 0.042 inch; a catalytic surface area greater than about 100 square meter per gram; a catalytic pore volume of between about 0.35 and 0.85 cubic centimeters per gram, said pore volume resulting from a major portion of pores of diameter in the range of about 40 to 90 angstrom units when measured with mercury up to 50,000 pounds per square inch absolute pressure and a contact angle of 140° , and a composition comprising a major portion of alumina, from about 5 to 25 weight percent of molybdenum oxide and from about 1 to 8 weight percent of an oxide selected from cobalt and nickel oxides and mixtures thereof: said process comprising contacting said distillate with said catalyst particle and hydrogen at a hydrogen flow rate of about 100 to 10000 standard cubic feet per barrel of distillate at a liquid hourly space velocity of about 0.5 to 25 reciprocal hour, a temperature in the range of about 500° to 800° F. and a total pressure in the range of about 100 to 3000 pounds per square inch gauge.

Claim 3

A process for hydrotreating a petroleum distillate to remove sulfur-containing and nitrogen-containing components with a porous catalyst particle of given length and polylobal cross-sectional shape characterized by a concavity index of greater than 1.0, a void fraction in the range of about 0.25 to 0.60, and when containing more than two lobes at least 15% of the points within said particle being greater than about 0.015 inch from the particle surface; said particle having a ratio of geometric volume to geometric surface in the range of about 0.01 to 0.042 inch; a catalytic surface area greater than about 100 square meter per gram; a catalytic pore volume of between about 0.35 and 0.85 cubic centimeters per gram, said pore volume resulting from a major portion of pores of diameter in the range of about 40 to 90 angstrom units when measured with mercury up to 50,000 pounds per square inch absolute pressure and a contact angle of 140° , and a composition comprising a major portion of alumina, from about 5 to 25 weight percent of molybdenum oxide and from about 1 to 8 weight percent of an oxide selected from cobalt and nickel oxides and mixtures thereof: said process comprising contacting said distillate with said catalyst particle and hydrogen at a hydrogen flow rate of about 100 to 10000 standard cubic feet per barrel of distillate at a liquid hourly space velocity of about 0.5 to 25 reciprocal hour, a temperature in the range of about 500° to 800° F., and a total pressure in the range of about 100 to 3000 pounds per square inch gauge.

Claim 4

A process for hydrotreating a petroleum distillate to remove sulfur-containing and nitrogen-containing components with a porous catalyst particle of given length and polylobal cross-sectional shape characterized by a concavity index of greater than 1.0, a void fraction in the range of about 0.25 to 0.60, and when containing more than two lobes at least 15% of the points within said particle being greater than about 0.015 inch from the particle surface; said particle having a ratio of geometric volume to geometric surface in the range of about 0.01 to 0.042 inch; a catalytic surface area greater than about 100 square meter per gram; a catalytic pore volume of between about 0.35 and 0.85 cubic centimeters per gram, said pore volume resulting from a major portion of pores of diameter in the range of about 40 to 90 angstrom units when measured with mercury up to 50,000 pounds per square inch absolute pressure and a contact angle of 140° , and a composition comprising a major portion of alumina, from about 5 to 25 weight percent of molybdenum oxide and from about 1 to 8 weight percent of an oxide selected from cobalt and nickel oxides and mixtures thereof: said process comprising contacting said distillate with said catalyst particle and hydrogen at a hydrogen flow rate of about 100 to 10000 standard cubic feet per barrel of distillate at a liquid hourly space velocity of about 0.5 to 25 reciprocal hour, a temperature in the range of about 500° to 800° F., and a total pressure in the range of about 100 to 3000 pounds per square inch gauge.

Claim 5

The process of claim 1 wherein said hydrogen flow rate is 200-2000 standard cubic feet per barrel of distillate.

Claim 6

The process of claim 1 wherein said liquid hourly space velocity is 2 reciprocal hours.

Claim 7

The process of claim 1 wherein said temperature is 650° F.

Claim 8

The process of claim 1 wherein said temperature is 725° F.

Claim 9

The process of claim 1 wherein said total pressure is 750 pounds per square inch gauge.

Claim 10

The process of claim 1 wherein said hydrogen flow rate is 6000 standard cubic feet per barrel of distillate, said liquid hourly space velocity is 2 reciprocal hours, said temperature is 625° F., and said total pressure is 750 pounds per square inch gauge.

Claim 11

The process of claim 1 wherein said hydrogen flow rate is 6000 standard cubic feet per barrel of distillate, said liquid hourly space velocity is 2 reciprocal hours, said temperature is 725° F., and said total pressure is 750 pounds per square inch gauge.

Claim 12

The process of claim 1 wherein said catalyst particle is of three-leaf clover cross-sectional shape.

Claim 13

The process of claim 1 wherein said catalyst particle is of dumbbell cross-sectional shape.