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US3990833A Expired / Lapsed US ⏱️ 0.0 years remaining

Switching devices for photoflash unit

Assignee: General Electric Co
•
Filing: 1975-09-29
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Granted: 1976-11-09
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Expires: 1995-09-29
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Abstract

Abstract A photoflash unit is designed to have a plurality of lamps fired individually and in sequence and includes a plurality of switching devices capable of being easily activated by radiant energy generated during flashing of the lamps. Initially, the switches have a high resistance ("off" condition) and after being activated by radiation, they undergo a chemical change to a conductive state ("on" condition). The switches are prepared from compositions which impart improved shelf life to the switches under conditions of high relative humidity.

Inventors

  • 👤 Fred F. Holub
  • 👤 Nicholas Roman
  • 👤 Harold F. Webster

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:20
CPC Classifications
H; H01; H01C; H01C7/00; C; C08; C08K; C08K3/00; C08K3/18; C08K3/24; C08K3/26; C08K5/00; C08K5/04; C08K5/09; C08K5/098; G; G03; G03B; G03B15/00; G03B15/02; G03B15/03; G03B15/04; G03B15/041; G03B15/0426; G03B15/0442; G03B15/0452; G03B15/0457; H05; H05K; H05K1/00; H05K1/02; H05K1/0286; H05K1/0293; H05K2201/00; H05K2201/01; H05K2201/0104; H05K2201/0112; H05K2203/00; H05K2203/17; H05K2203/173

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 137 words
A photoflash lamp unit comprising a. a pair of flash lamps, b. an electrical circuit into which said lamps are arranged to fire individually and in sequence, and c. a solid state, radiant energy switching device located external of the lamps and forming part of the electrical circuit, said switching device being located adjacent one of said lamps and disposed to receive radiant energy emitted by that lamp, said photoflash unit being characterized by said switching device being a high relative humidity resistant mass of a composition comprising a metallic silver source and a humidity resistant, organic polymer binder selected from the group consisting of cellulose esters, cellulose ethers, polyalkylacrylates, polyalkylmethacrylates, polymethylmethacrylate, polymethylacrylate, polystyrene and polycarbonate, said silver source consisting of at least 70% by weight of a carbon-containing silver salt and further consisting of silver oxide.
Claim 2
Dependent Claim 137 words
A photoflash lamp unit comprising a. a pair of flash lamps, b. an electrical circuit into which said lamps are arranged to fire individually and in sequence, and c. a solid state, radiant energy switching device located external of the lamps and forming part of the electrical circuit, said switching device being located adjacent one of said lamps and disposed to receive radiant energy emitted by that lamp, said photoflash unit being characterized by said switching device being a high relative humidity resistant mass of a composition comprising a metallic silver source and a humidity resistant, organic polymer binder selected from the group consisting of cellulose esters, cellulose ethers, polyalkylacrylates, polyalkylmethacrylates, polymethylmethacrylate, polymethylacrylate, polystyrene and polycarbonate, said silver source consisting of at least 70% by weight of a carbon-containing silver salt and further consisting of silver oxide.
Claim 3
Dependent Claim 26 words
The unit of claim 1, wherein said carbon-containing silver salt is a member selected from the group consisting of silver carbonate, silver pyruvate, and silver acetylacetonate.
Claim 4
Dependent Claim 24 words
The unit of claim 1, wherein said silver source is a mixture of said member with up to 30% by weight of silver oxide.
Claim 5
Dependent Claim 42 words
The unit of claim 1, wherein said silver source is a member selected from the group consisting of silver acetate, silver oxalate, silver citrate, silver behenate, and silver benzoate, and the composition additionally contains up to 5% by weight of carbon powder.
Claim 6
Dependent Claim 15 words
The unit of claim 1, wherein said switching device additionally contains a radiation absorbing additive.
Claim 7
Dependent Claim 25 words
The unit of claim 5, wherein said radiation absorbing additive is a member selected from the group consisting of carbon, copper oxide and stannous oxide.
Claim 8
Dependent Claim 21 words
The unit of claim 1, wherein the switching device bridges between and contacts a pair of terminals in said electrical circuit.
Claim 9
Dependent Claim 18 words
The unit of claim 7, wherein the composition consists essentially of silver carbonate dispersed in an ethyl-cellulose binder.
Claim 10
Dependent Claim 27 words
The unit of claim 7, wherein the composition consists essentially of silver carbonate with up to 30% by weight of silver oxide dispersed in an ethylcellulose binder.
Claim 11
Dependent Claim 18 words
The unit of claim 7, wherein the composition consists essentially of silver pyruvate dispersed in an ethylcellulose binder.
Claim 12
Dependent Claim 20 words
The unit of claim 7, wherein the composition consists essentially of silver acetate and carbon dispersed in an ethylcellulose binder.
Claim 13
Dependent Claim 79 words
A radiation switching device capable of changing from a high electrical resistance to a very low electrical resistance, said device being a high relative humidity resistant mass of a composition comprising a metallic silver source and a water-insoluble organic polymer binder selected from the group consisting of cellulose esters, cellulose ethers, polyalkylacrylates, polyalkylmethacrylates, polymethylmethacrylate, polymethylacrylate, polystyrene and polycarbonate, said silver source consisting of at least 70% by weight of a carbon-containing silver salt and further consisting of silver oxide.
Claim 14
Dependent Claim 79 words
A radiation switching device capable of changing from a high electrical resistance to a very low electrical resistance, said device being a high relative humidity resistant mass of a composition comprising a metallic silver source and a water-insoluble organic polymer binder selected from the group consisting of cellulose esters, cellulose ethers, polyalkylacrylates, polyalkylmethacrylates, polymethylmethacrylate, polymethylacrylate, polystyrene and polycarbonate, said silver source consisting of at least 70% by weight of a carbon-containing silver salt and further consisting of silver oxide.
Claim 15
Dependent Claim 25 words
The device of claim 12, wherein said silver salt is a member selected from the group consisting of silver carbonate, silver pyruvate, and silver acetylacetonate.
Claim 16
Dependent Claim 37 words
The device of claim 12, wherein said silver salt is a member selected from the group consisting of silver acetate, silver oxalate, silver citrate, silver behenate, and silver benzoate, and the composition additionally contains radiation-absorbing carbon powder.
Claim 17
Dependent Claim 15 words
The device of claim 12, wherein said switching device additionally contains a radiation absorbing additive.
Claim 18
Dependent Claim 25 words
The device of claim 15, wherein said radiation absorbing additive is a member selected from the group consisting of carbon, copper oxide and stannous oxide.
Claim 19
Dependent Claim 21 words
The device of claim 12, wherein the switching device extends between and contacts a pair of terminals in said electrical circuit.
Claim 20
Dependent Claim 18 words
The device of claim 17, wherein the composition consists essentially of silver carbonate dispersed in an ethylcellulose binder.
Claim 21
Dependent Claim 76 words
A radiation switch for use with a photoflash unit and capable of changing from a high electrical resistance to a lower electrical resistance when exposed to radiant energy, said switch being a composition comprising a source of metallic silver and a water-insoluble organic polymer binder, said silver source comprising a mixture of a. at least 70% by weight of a carbon-containing silver salt and b. at least some and up to 30% by weight silver oxide.
Claim 22
Dependent Claim 76 words
A radiation switch for use with a photoflash unit and capable of changing from a high electrical resistance to a lower electrical resistance when exposed to radiant energy, said switch being a composition comprising a source of metallic silver and a water-insoluble organic polymer binder, said silver source comprising a mixture of a. at least 70% by weight of a carbon-containing silver salt and b. at least some and up to 30% by weight silver oxide.
Claim 23
Dependent Claim 13 words
The radiation switch of claim 19 in which said salt is silver carbonate.
Claim 24
Dependent Claim 25 words
The radiation switch of claim 19 in which said silver source is approximately 90% by weight silver carbonate and approximately 10% by weight silver oxide.
Claim 25
Dependent Claim 12 words
The radiation switch of claim 21 in which said binder is ethylcellulose.

References Cited (Backward Citations)

US3297846A Cited
US3459488A Cited
US3458270A Cited
US3451813A Cited
US3573230A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-11-09 1980-05-10 1980-11-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-11-09 1984-05-10 1984-11-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-11-09 1988-05-10 1988-11-09 $7700.00 Window Closed / Lapsed

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