US3989767A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Powder coating resin compositions of glycidyl copolymers having an internal flowing agent
Assignee: DIC Corp
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Filing: 1975-02-28
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Granted: 1976-11-02
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Expires: 1995-02-28
Abstract
Abstract A powder coating resin composition comprising (A) 10 to 90% by weight of a glycidyl- or methyl glycidyl-containing copolymer and (B) 90 to 10% by weight of a polycarboxylic compound, said copolymer (A) being prepared by polymerizing (1) 5 to 40% by weight of at least one ethylenically unsaturated monomer selected from the group consisting of glycidyl-containing ethylenically unsaturated monomers and methyl glycidyl-containing ethylenically unsaturated monomers and (2) 20 to 90% by weight of at least one other ethylenically unsaturated monomer in the presence of (3) 5 to 40% by weight of a polyester resin containing an ethylenically unsaturated bond and having an acid number of not more than 10 KOH mg/g and a hydroxyl number of 20 to 300 KOH mg/g, said polyester resin being derived from 0.1-10 equivalent percent of an ethylenically unsaturated polycarboxylic acid, 30 to 49.9 equivalent percent of a polycarboxylic acid not containing an ethylenically unsaturated bond and 50 to 65 equivalent percent of a polyhydric alcohol.
Inventors
- 👤 Minoru Homma
- 👤 Akio Shoji
- 👤 Hidehisa Nakamura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 02:36
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/32; C08G59/3209; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/14
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
164 words
A powder coating resin composition comprising (A) 10 to 90% by weight of a glycidyl- or methyl glycidyl-containing copolymer and (B) 90 to 10% by weight of a polycarboxylic compound, said copolymer (A) being prepared by polymerizing (1) 5 to 40% by weight of at least one ethylenically unsaturated monomer selected from the group consisting of glycidyl-containing ethylenically unsaturated monomers and methyl glycidyl-containing ethylenically unsaturated monomers and (2) 20 to 90% by weight of at least one other ethylenically unsaturated monomer in the presence of (3) 5 to 40% by weight of a polyester resin containing an ethylenically unsaturated bond and having an acid number of not more than 10 KOH mg/g and a hydroxyl number of 20 to 300 KOH mg/g, said polyester resin being derived from 0.1 - 10 equivalent % of an ethylenically unsaturated polycarboxylic acid, 30 to 49.9 equivalent % of a polycarboxylic acid not containing an ethylenically unsaturated bond and 50 to 65 equivalent % of a polyhydric alcohol.
Claim 2
Dependent Claim
164 words
A powder coating resin composition comprising (A) 10 to 90% by weight of a glycidyl- or methyl glycidyl-containing copolymer and (B) 90 to 10% by weight of a polycarboxylic compound, said copolymer (A) being prepared by polymerizing (1) 5 to 40% by weight of at least one ethylenically unsaturated monomer selected from the group consisting of glycidyl-containing ethylenically unsaturated monomers and methyl glycidyl-containing ethylenically unsaturated monomers and (2) 20 to 90% by weight of at least one other ethylenically unsaturated monomer in the presence of (3) 5 to 40% by weight of a polyester resin containing an ethylenically unsaturated bond and having an acid number of not more than 10 KOH mg/g and a hydroxyl number of 20 to 300 KOH mg/g, said polyester resin being derived from 0.1 - 10 equivalent % of an ethylenically unsaturated polycarboxylic acid, 30 to 49.9 equivalent % of a polycarboxylic acid not containing an ethylenically unsaturated bond and 50 to 65 equivalent % of a polyhydric alcohol.
Claim 3
Dependent Claim
24 words
The powder coating resin composition of claim 1 wherein said polycarboxylic compound (B) is an aliphatic dicarboxylic acid containing 4 to 22 carbon atoms.
Claim 4
Dependent Claim
27 words
The powder coating resin composition of claim 1 wherein said polycarboxylic compound (B) is a carboxyl-terminated polyester resin derived from a polyhydric alcohol and a polycarboxylic acid.
Claim 5
Dependent Claim
31 words
The powder coating resin composition of claim 1 which further contains (C) 1 to 25 parts by weight, per 100 parts by weight of said copolymer (A), of an amino resin.
Claim 6
Dependent Claim
31 words
The powder coating resin composition of claim 1 which further contains (D) 1 to 30 parts by weight per 100 parts by weight of said copolymer (A), of a blocked polyisocyanate.
Claim 7
Dependent Claim
109 words
The powder coating resin composition of claim 1 wherein said polyester resin is derived from an ethylenically unsaturated polycarboxylic acid selected from the group consisting of maleic acid, fumaric acid, and itaconic acid or the anhydrides of these acids; a polycarboxylic acid not containing an ethylenically unsaturated bond selected from the group consisting of aromatic carboxylic acids, methylester of aromatic carboxylic acid, aliphatic carboxylic acid, and alicyclic carboxylic acid and the anhydrides of said carboxylic acids and a polyhydric alcohol containing no ethylenically unsaturated bonds selected from the group consisting of ethylene glycol, propylene glycol, 1,4-butyleneglycol, diethylenetrimethylolethane, trimethylolpropane, ethylene oxide adduct of hydrogenated bisphenol A and hydrogenated bisphenol A.
Claim 8
Dependent Claim
86 words
The powder coating resin composition of claim 1 wherein said copolymer (A) is prepared by polymerizing (1) a mixture of said glycidyl-containing ethylenically unsaturated monomer and said methylglycidyl-containing ethylenically unsaturated monomer and (2) an ethylenically unsaturated monomer selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, butyl acrylate, butyl methacrylate, β-hydroxyethyl acrylate, β-hydroxyethyl methacrylate, β-hydroxypropyl acrylate, β-hydroxypropyl methacrylate, dimethyl maleate, diethyl fumarate, dipropyl itaconate, styrene, vinyl toluene, vinyl acetate, vinyl chloride, allyl alcohol and methallyl alcohol and (3) said polyester resin.
Claim 9
Dependent Claim
37 words
The powder coating resin composition of claim 7 wherein said copolymer (A) has a number average molecular weight of 3,000 to 30,000, and a softening point, measured by a ring ball method, of 80° to 150° C.
Claim 10
Dependent Claim
25 words
The powder coating resin composition of claim 4 wherein said amino resin (C) is selected from the group consisting of hexamethoxymethyl melamine and tetrabutoxymethyl benzoguanamine.
Claim 11
Dependent Claim
62 words
The powder coating resin composition of claim 1 wherein copolymer (A) is the reaction product of (1) glycidyl methacrylate and methyl glycidyl methacrylate with (2) styrene, 2-ethylhexylacrylate and isobutylmethacrylate and (3) an unsaturated polyester resin which is the reaction product of isophthalic acid, adipic acid, trimethylol propane, neopentyl glycol and maleic anhydride, and wherein said polycarboxylic compound (B) is 1, 10-decanedicarboxylic acid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-11-02 | 1980-05-03 | 1980-11-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-11-02 | 1984-05-03 | 1984-11-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-11-02 | 1988-05-03 | 1988-11-02 | $7700.00 | Window Closed / Lapsed |