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US3989734A Expired / Lapsed US ⏱️ 0.0 years remaining

Slurry phase methanation process

Assignee: United States Department of State
•
Filing: 1974-10-25
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Granted: 1976-11-02
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Expires: 1994-10-25
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Abstract

Abstract A gas stream containing carbon monoxide and hydrogen is methanated by pasg the gas stream upwardly through a suspension of a finely divided hydrogenation catalyst in a fluidizing medium. The reaction takes place at a temperature of from 450 to 950° F.

Inventors

  • 👤 Seymour Bernard Alpert
  • 👤 Martin Barry Sherwin
  • 👤 Neal Paul Cochran

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 02:00
CPC Classifications
C; C07; C07C; C07C1/00; C07C1/02; C07C1/04; C07C1/06; C07C1/063; C07C1/066; C07C2523/00; C07C2523/70; C07C2523/74; C07C2523/755

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 132 words
A process for converting a gas stream containing from 1 to 25 mole % of carbon monoxide and from 2 to 75 mole % of hydrogen to methane which comprises: passing said gas stream and a fluidizing medium which is a chemically stable liquid selected from the group consisting of desulfurized gas oils and paraffins having a boiling point of from 400° to 1000° F. into a reaction zone containing a bed of nickel catalyst particles; maintaining a flow rate of such gas stream and fluidizing medium upwardly through said reaction zone so as to expand the volume of said bed of nickel catalyst particle by at least 5% at a temperature of from 500° to 800° F., said nickel catalyst particles having a particle size of from 0.006 to 0.375 inches.
Claim 2
Dependent Claim 132 words
A process for converting a gas stream containing from 1 to 25 mole % of carbon monoxide and from 2 to 75 mole % of hydrogen to methane which comprises: passing said gas stream and a fluidizing medium which is a chemically stable liquid selected from the group consisting of desulfurized gas oils and paraffins having a boiling point of from 400° to 1000° F. into a reaction zone containing a bed of nickel catalyst particles; maintaining a flow rate of such gas stream and fluidizing medium upwardly through said reaction zone so as to expand the volume of said bed of nickel catalyst particle by at least 5% at a temperature of from 500° to 800° F., said nickel catalyst particles having a particle size of from 0.006 to 0.375 inches.
Claim 3
Dependent Claim 16 words
The process of claim 1 wherein the nickel catalyst is in the form of an extrudate.
Claim 4
Dependent Claim 18 words
The process of claim 1 wherein the space velocity in said reaction is from 500 to 50,000 SCF/CF-hours.

References Cited (Backward Citations)

US2438029A Cited
US2433255A Cited
US2671103A Cited
US2692274A Cited
US2775607A Cited
US2852350A Cited
GB787122A Cited
GB780880A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-11-02 1980-05-03 1980-11-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-11-02 1984-05-03 1984-11-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-11-02 1988-05-03 1988-11-02 $7700.00 Window Closed / Lapsed

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