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US3989678A Expired / Lapsed US ⏱️ 0.0 years remaining

Hot melt adhesives comprising copolymeric polyamides

Assignee: Toyobo Co Ltd
•
Filing: 1973-09-13
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Granted: 1976-11-02
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Expires: 1993-09-13
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Abstract

Abstract A hot melt adhesive which comprises a copolyamide consisting essentialy of (1) ε-caprolactam, (2)(a) hexamethylenediamine and (b) at least one straight chain, saturated aliphatic dicarboxylic acid having 6 to 20 carbon atoms in a substantially equimolar ratio and (3)(a) at least one of 2,2,4-trimethylhexamethylenediamine and 2,4,4-trimethylhexamethylenediamine and (b) at least one straight chain, saturated aliphatic dicarboxylic acid having 6 to 20 carbon atoms in a substantially equimolar ratio, the proportion of [A] the constituent unit essentially consisting of the component (1), [B] the contituent unit essentially consisting of the components (2)(a) and (2)(b) and [C] the constituent unit essentially consisting of the components (3)(a) and (3)(b) therein being within a pentagon circumscribed by the lines connecting the points P (82/17/1), Q (52/47/1), R (0/65/35), S (0/50/50) and T (86/7/7) in the graph as shown in FIG. 1 of the accompanying drawing (the numerals in the parenthesis following P, Q, R, S and T indicating the molar percentages of the constituent units [A], [B] and [C], respectively).

Inventors

  • 👤 Kaoru Furukawa
  • 👤 Shinichiro Seki
  • 👤 Takashi Akiyama
  • 👤 Singo Ueda
  • 👤 Hideo Ikeda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 22:16
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/36

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 186 words
A copolyamide useful as a hot melt adhesive, and having improved tear strength, washability and dry-cleanability properties, consisting essentially of units derived from the polycondensation of (1) ε-caprolactam, (2) (a) hexamethylenediamine and (b) an aliphatic dicarboxylic acid selected from the group consisting of azelaic acid, sebacic acid and dodecanedioic acid in a substantially equimolar ratio and (3) (a) at least one of 2,2,4-trimethylhexamethylenediamine and 2,4,4-trimethylhexamethylenediamine and (b) an aliphatic dicarboxylic acid selected from the group consisting of azelaic acid, sebacic acid and dodecanedioic acid in a substantially equimolar ratio, the proportion of the constituent unit A essentially consisting of the component (1), the constituent unit B essentially consisting of the components (2) (a) and (2) (b) and the constituent unit C essentially consisting of the components (3) (a) and (3) (b) being within the tetragon circumscribed by the lines connecting the points P (82/17/1), Q (52/47/1), U (10/46/44) and T (86/7/7) in the graph shown in FIG. 2 of the accompanying drawing, the numerals in the parentheses following P, Q, U and T indicating the molar percentages of the constituent units A, B and C, respectively.
Claim 2
Dependent Claim 186 words
A copolyamide useful as a hot melt adhesive, and having improved tear strength, washability and dry-cleanability properties, consisting essentially of units derived from the polycondensation of (1) ε-caprolactam, (2) (a) hexamethylenediamine and (b) an aliphatic dicarboxylic acid selected from the group consisting of azelaic acid, sebacic acid and dodecanedioic acid in a substantially equimolar ratio and (3) (a) at least one of 2,2,4-trimethylhexamethylenediamine and 2,4,4-trimethylhexamethylenediamine and (b) an aliphatic dicarboxylic acid selected from the group consisting of azelaic acid, sebacic acid and dodecanedioic acid in a substantially equimolar ratio, the proportion of the constituent unit A essentially consisting of the component (1), the constituent unit B essentially consisting of the components (2) (a) and (2) (b) and the constituent unit C essentially consisting of the components (3) (a) and (3) (b) being within the tetragon circumscribed by the lines connecting the points P (82/17/1), Q (52/47/1), U (10/46/44) and T (86/7/7) in the graph shown in FIG. 2 of the accompanying drawing, the numerals in the parentheses following P, Q, U and T indicating the molar percentages of the constituent units A, B and C, respectively.
Claim 3
Dependent Claim 27 words
The copolyamide according to claim 1, wherein (1) is selected from the group consisting of ε-caprolactam itself, a low molecular weight polymer of ε-caprolactam and ω-aminocaproic acid.
Claim 4
Dependent Claim 15 words
A hot melt adhesive comprising the copolyamide acording to claim 1 as a main component.
Claim 5
Dependent Claim 21 words
The hot melt adhesive according to claim 3, prepared in the form of a powder, film, sheet, nonwoven web or fabric.

References Cited (Backward Citations)

US2252555A Cited
US3322731A Cited
US3703595A Cited
US3734887A Cited
US3839121A Cited
US3784495A Cited
US3850887A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-11-02 1980-05-03 1980-11-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-11-02 1984-05-03 1984-11-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-11-02 1988-05-03 1988-11-02 $7700.00 Window Closed / Lapsed

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