US3989664A
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Stabilized polyester composition and method for stabilizing polyester
Assignee: Novartis Corp
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Filing: 1975-04-21
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Granted: 1976-11-02
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Expires: 1995-04-21
Abstract
Abstract A method for stabilizing a polyester at least 80% of the recurring units of which in terms of number consist of tetramethylene terephthalate units or tetramethylene-2,6-naphthalate units, by incorporating into said polyester 0.001 to 10% by weight, based on the weight of the polyester, of at least one compound of the following formula (I) ##SPC1## This application is a continuation-in-part of application Ser. No. 548,988, filed Feb. 10, 1975, which in turn is a divisional application of Ser. No. 417,918 filed Nov. 21, 1973, now U.S. Pat. No. 3,904,578.
Inventors
- 👤 Shoji Kawase
- 👤 Hiroo Inata
- 👤 Takeo Shima
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 19:14
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/13; C08K5/134; C08K5/1345
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
215 words
A stabilized polyester composition wherein said polyester is formed by melt-polycondensation comprising a polyester, at least 80% of the recurring units of which in terms of number, consists of tetramethylene terephthalate units or tetramethylene 2,6-naphthalate units, wherein said polyester is derived from the melt state reaction between dicarboxylic acid component, at least 80 mol% of which consists of terephthalic acid, naphthalene-2,6-dicarboxylic acid or their polyester-forming derivatives and up to 20 mol% of a dicarboxylic acid component selected from naphthalene-2,6-dicarboxylic acid when the main component is terephthalic acid, terephthalic acid when the main component is naphthalene-2,6-dicarboxylic acid, isophthalic acid, naphthalene-2,7-dicarboxylic acid, naphthalene-1,5-dicarboxylic acid, 4,4'-diphenyldicarboxylic acid, 4,4'-diphenoxyethanedicarboxylic acid, p-hydroxypenzoic p-hydroxybenzoic sebacic acid, and adipic acid and a glycol component at least 80 mol% of which consists of tetramethylene glycol or its polyester-forming derivatives and not more than 20 mol% of a glycol component selected from alkylene glycol or cycloakylene glycol and 0.001 to 10% by weight, based on the weight of said polyester, of at least one compound selected from compounds of formula (I) ##SPC16## wherein R 1 is a divalent organic group, and R 2 is an alkyl or aryl group, wherein said compound of formula (I) is incorporated into said polymer at any stage before the completion of the melt-polycondensation reaction for forming the polyester.
Claim 2
Dependent Claim
215 words
A stabilized polyester composition wherein said polyester is formed by melt-polycondensation comprising a polyester, at least 80% of the recurring units of which in terms of number, consists of tetramethylene terephthalate units or tetramethylene 2,6-naphthalate units, wherein said polyester is derived from the melt state reaction between dicarboxylic acid component, at least 80 mol% of which consists of terephthalic acid, naphthalene-2,6-dicarboxylic acid or their polyester-forming derivatives and up to 20 mol% of a dicarboxylic acid component selected from naphthalene-2,6-dicarboxylic acid when the main component is terephthalic acid, terephthalic acid when the main component is naphthalene-2,6-dicarboxylic acid, isophthalic acid, naphthalene-2,7-dicarboxylic acid, naphthalene-1,5-dicarboxylic acid, 4,4'-diphenyldicarboxylic acid, 4,4'-diphenoxyethanedicarboxylic acid, p-hydroxypenzoic p-hydroxybenzoic sebacic acid, and adipic acid and a glycol component at least 80 mol% of which consists of tetramethylene glycol or its polyester-forming derivatives and not more than 20 mol% of a glycol component selected from alkylene glycol or cycloakylene glycol and 0.001 to 10% by weight, based on the weight of said polyester, of at least one compound selected from compounds of formula (I) ##SPC16## wherein R 1 is a divalent organic group, and R 2 is an alkyl or aryl group, wherein said compound of formula (I) is incorporated into said polymer at any stage before the completion of the melt-polycondensation reaction for forming the polyester.
Claim 3
Dependent Claim
126 words
The composition of claim 1 wherein R 1 is a member selected from the group consisting of alkylene having 1 to 5 carbon atoms, cycloalkylene having 6 to 12 carbon atoms, xylylene, phenylene, oxyalkylene of formula -O--CH 2 ).sub. m, in which m is an integer of 1 to 6, oxyarylene of formula ##SPC17## wherein R is a hydrogen atom, a halogen atom, nitro or alkyl having 1 to 4 carbon atoms, ##SPC18## in which l is an integer of 1 to 6 and ##SPC19## and R 2 is a member selected from the group consisting of akyl having 1 to 20 carbon atoms, phenyl, phenyl substituted with alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms or hydroxyl, and naphthyl.
Claim 4
Dependent Claim
21 words
The composition of claim 1 wherein said composition further contains an additive selected from the group consisting of an ultraviolet ray
Claim 5
Dependent Claim
14 words
The composition of claim 1 which is in the form of a molding solid
Claim 6
Dependent Claim
14 words
The composition of claim 1 which includes from 0.005 to 1% by weight of
Claim 7
Independent Claim
234 words
A method for stabilizing a polyester formed by a melt-polycondensation reaction and increasing the rate of crystallization of said polyester during said melt-poly-condensation reaction, at least 80% of the recurring units of which in terms of number, consist of tetramethylene terephthalate units or tetramethylene 2,6-naphthalate units, wherein said polyester is derived from the melt state reaction between dicarboxylic acid component at least 80mol% of which consists of terephthalic acid, naphthalene-2,6-dicarboxylic acid or their polyester-forming derivatives and up to 20 mol% of a dicarboxylic acid component selected from naphthalene-2,6-dicarboxylic acid when the main component is terephthalic acid, terephthalic acid when the main component is naphthalene-2,6-dicarboxylic acid isophthalic acid, naphthalene-2,7-dicarboxylic acid, naphthalene-1,5-dicarboxylic acid, 4,4'-diphenyldicarboxylic acid, 4,4'-diphenoxyethanedicarboxylic acid, p-hydroxybenzoic acid, sebacic acid, and adipic acid and a glycol component at least 80 mol% of which consists of tetramethylene glycol or its polyester-forming derivatives and not more than 20 mol% of a glycol component selected from alkylene glycol or cycloakylene glycol comprising, incorporating into said polyester prior to the completion of the melt polycondensation reaction of forming said polyester, from 0.001 to 10% by weight, based on the weight of said polyester, of at least one compound of formula (I) ##SPC20## wherein R 1 is a divalent organic group, and R 2 is an alkyl or aryl group, wherein said compound of formula (I) is incorporated into said polyester at any stage before the completion of the melt-polycondensation
Claim 8
Independent Claim
234 words
A method for stabilizing a polyester formed by a melt-polycondensation reaction and increasing the rate of crystallization of said polyester during said melt-poly-condensation reaction, at least 80% of the recurring units of which in terms of number, consist of tetramethylene terephthalate units or tetramethylene 2,6-naphthalate units, wherein said polyester is derived from the melt state reaction between dicarboxylic acid component at least 80mol% of which consists of terephthalic acid, naphthalene-2,6-dicarboxylic acid or their polyester-forming derivatives and up to 20 mol% of a dicarboxylic acid component selected from naphthalene-2,6-dicarboxylic acid when the main component is terephthalic acid, terephthalic acid when the main component is naphthalene-2,6-dicarboxylic acid isophthalic acid, naphthalene-2,7-dicarboxylic acid, naphthalene-1,5-dicarboxylic acid, 4,4'-diphenyldicarboxylic acid, 4,4'-diphenoxyethanedicarboxylic acid, p-hydroxybenzoic acid, sebacic acid, and adipic acid and a glycol component at least 80 mol% of which consists of tetramethylene glycol or its polyester-forming derivatives and not more than 20 mol% of a glycol component selected from alkylene glycol or cycloakylene glycol comprising, incorporating into said polyester prior to the completion of the melt polycondensation reaction of forming said polyester, from 0.001 to 10% by weight, based on the weight of said polyester, of at least one compound of formula (I) ##SPC20## wherein R 1 is a divalent organic group, and R 2 is an alkyl or aryl group, wherein said compound of formula (I) is incorporated into said polyester at any stage before the completion of the melt-polycondensation
Claim 9
Dependent Claim
126 words
The method of claim 5 wherein R 1 is a member selected from the group consisting of alkylene having 1 to 5 carbon atoms, cycloalkylene having 6 to 12 carbon atoms, xylylene, phenylene, oxyalkylene of formula -0--CH 2 ) m , in which m is an integer of 1 to 6, oxyarlyene of formula ##SPC21## wherein R is a hydrogen atom, a halogen atom, nitro or alkyl having 1 to 4 carbon atoms, ##SPC22## in which l is an integer of 1 to 6 and ##SPC23## andR 2 is a member selected from the group consisting of alkyl having 1 to 20 carbon atoms, phenyl, phenyl substituted with alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms or hydroxyl and naphthyl.
Claim 10
Dependent Claim
21 words
The method of claim 5 wherein said composition further contains an additive selected from the group consisting of an ultraviolet ray
Claim 11
Dependent Claim
38 words
The method of claim 6 wherein from 0.005 to 1% by weight of the compound of formula (1), based on the weight of the polyester, is incorporated into the polyester prior to the completion of the melt polycondensation
Claim 12
Dependent Claim
13 words
The composition of claim 1 which is in the form of a melt-shaped
Claim 13
Dependent Claim
19 words
The composition of claim 1 wherein said compound of formula (1) is selected from the group consisting of ##SPC24##
Claim 14
Dependent Claim
19 words
The method of claim 6 wherein said compound of formula (1) is selected from the group consisting of ##SPC25##
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-11-02 | 1980-05-03 | 1980-11-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-11-02 | 1984-05-03 | 1984-11-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-11-02 | 1988-05-03 | 1988-11-02 | $7700.00 | Window Closed / Lapsed |