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US3989662A Expired / Lapsed US ⏱️ 0.0 years remaining

Single component polyurethane varnish of long shelf life

Assignee: Veba Oel AG
•
Filing: 1974-03-27
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Granted: 1976-11-02
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Expires: 1994-03-27
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Abstract

Abstract Single-component polyurethane varnishes having long shelf life containing conventional solvents and the reaction product of 3-isocyanatomethyl-3,5,5-trimethylcyclohexylisocyanate (IPDI) and branched polyesters containing terminal hydroxyl groups. The polyesters contain intermolecular tin and are based on mixtures of aliphatic and aromatic dicarboxylic acids, 15 to 85 mole percent of the acids being aliphatic, the balance aromatic. The polyester and IPDI are reacted without catalysts at temperatures of 10° to 35° C and in such quantities that there are two isocyanate group for each --OH group.

Inventors

  • 👤 Karl Schmitt
  • 👤 Josef Disteldorf
  • 👤 Werner Flakus

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 21:39
CPC Classifications
C; C09; C09D; C09D175/00; C09D175/04; C09D175/06; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/42; C08G18/4205; C08G18/4208; C08G18/4211; C08G18/4216; C08G18/70; C08G18/72; C08G18/74; C08G18/75; C08G18/751; C08G18/752; C08G18/753; C08G18/755

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 86 words
Single-component polyurethane varnishes having long shelf life comprising polyurethane solvents and the reaction product of 3-isocyanatomethyl-3,5,5-trimethylcyclohexylisocyanate with branched, hydroxyl-terminal-group-containing polyesters, said polyesters having tin incorporated in the molecule and being based on mixtures of aliphatic and aromatic dicarboxylic acids with 15 to 85 mole-% of the dicarboxylic acids being aliphatic acids and the remainder aromatic acids, said polyester and said isocyanate being reacted without the addition of catalyst at 10° to 35° C and in such quantities that there are two isocyanate groups per OH group.
Claim 2
Dependent Claim 86 words
Single-component polyurethane varnishes having long shelf life comprising polyurethane solvents and the reaction product of 3-isocyanatomethyl-3,5,5-trimethylcyclohexylisocyanate with branched, hydroxyl-terminal-group-containing polyesters, said polyesters having tin incorporated in the molecule and being based on mixtures of aliphatic and aromatic dicarboxylic acids with 15 to 85 mole-% of the dicarboxylic acids being aliphatic acids and the remainder aromatic acids, said polyester and said isocyanate being reacted without the addition of catalyst at 10° to 35° C and in such quantities that there are two isocyanate groups per OH group.
Claim 3
Dependent Claim 8 words
Varnishes of claim 1 containing dry commercial pigments.
Claim 4
Dependent Claim 19 words
Varnishes of claim 1 wherein the aliphatic dicarboxylic acids are aliphatic hydrocarbon acids having at least 4 carbon atoms.
Claim 5
Dependent Claim 26 words
Varnishes of claim 3 wherein said acids are selected from the group of succinic acid, glutaric acid, adipic acid, suberic acid, sebacid acid, and azelaic acid.
Claim 6
Dependent Claim 22 words
Varnishes of claim 1 wherein said aromatic dicarboxylic acids are selected from the group of phthalic acid, isophthalic acid and terephthalic acid.
Claim 7
Dependent Claim 26 words
Varnishes of claim 1 wherein compounds for the incorporation of tin into said polyesters are tin esters, tin ester oxides, tin alkyl esters or tin halides.
Claim 8
Dependent Claim 27 words
Varnishes of claim 6 wherein said tin compounds are selected from the group of di-n-butyl tin oxide, di-n-butyltindilaurate, tin tetrachloride, tin dichloride, tin diisooctate, and tin diformiate.
Claim 9
Dependent Claim 29 words
Varnishes of claim 6, wherein said tin compounds are used in quantities such that the branched polyester contains tin in an amount of from 0.1% to 0.5% by weight.

References Cited (Backward Citations)

US3055867A Cited
US3057824A Cited
US3157618A Cited
US3208978A Cited
US3194791A Cited
US3352830A Cited
US3425994A Cited
US3549569A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-11-02 1980-05-03 1980-11-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-11-02 1984-05-03 1984-11-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-11-02 1988-05-03 1988-11-02 $7700.00 Window Closed / Lapsed

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