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US3988229A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilized photopolymerizable polymeric compositions containing a photoinitiator and a nitrone derivative

Assignee: Eastman Kodak Co
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Filing: 1975-08-28
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Granted: 1976-10-26
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Expires: 1995-08-28
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Abstract

Abstract The invention relates to stabilized photopolymerizable or photocrosslinkable polymeric compositions having improved storage stability. These compositions are useful as coating and moldable compositions which are hardenable by ultraviolet radiation. These coating and moldable compositions comprise mixtures of photopolymerizable or photocrosslinkable unsaturated compounds, at least one photoinitiator and a particular nitrone.

Inventors

  • 👤 James G. Pacifici
  • 👤 Gordon C. Newland

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 23:51
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; C08K; C08K5/00; C08K5/16; C08K5/32; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/12

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 62 words
A stabilized radiation-curable coating composition comprising: a. at least one ethylenically unsaturated compound, b. at least one photoinitiator, and c. from about 0.001 to about 0.3 weight percent of a nitrone having the formula: ##EQU1## wherein R 1 is aryl or substituted aryl; R 2 is H, alkyl, cycloalkyl, araallyl, aryl or substituted aryl; and R 3 is tertiary alkyl or aryl.
Claim 2
Dependent Claim 62 words
A stabilized radiation-curable coating composition comprising: a. at least one ethylenically unsaturated compound, b. at least one photoinitiator, and c. from about 0.001 to about 0.3 weight percent of a nitrone having the formula: ##EQU1## wherein R 1 is aryl or substituted aryl; R 2 is H, alkyl, cycloalkyl, araallyl, aryl or substituted aryl; and R 3 is tertiary alkyl or aryl.
Claim 3
Dependent Claim 14 words
A stabilized radiation-curable coating composition according to claim 1 wherein said nitrone is N,a-diphenylnitrone.
Claim 4
Dependent Claim 15 words
A stabilized radiation curable coating composition according to claim 1 wherein said nitrone is α-4-carbomethoxyphenyl-N-phenylnitrone.
Claim 5
Dependent Claim 14 words
A stabilized radiation-curable coating composition according to claim 1 wherein said nitrone is α-carbomethoxyphenyl-N-t-butylnitrone.
Claim 6
Dependent Claim 15 words
A stabilized radiation curable coating composition according to claim 1 wherein said nitrone is α-4-nitrophenyl-N-t-butylnitrone.
Claim 7
Dependent Claim 14 words
A stabilized radiation-curable coating composition according to claim 1 wherein said nitrone is α,α-(1,4-phenylene)-N-t-butyldinitrone.
Claim 8
Dependent Claim 15 words
A stabilized radiation curable coating composition according to claim 1 wherein said nitrone is α-4-carboxyphenyl-N-t-butylnitrone.
Claim 9
Dependent Claim 15 words
A stabilized radiation curable coating composition according to claim 1 wherein said nitrone is α-phenyl-N-t-butylnitrone.

References Cited (Backward Citations)

US3481739A Cited
US3914128A Cited
US3901705A Cited
US3885964A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-26 1980-04-26 1980-10-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-26 1984-04-26 1984-10-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-26 1988-04-26 1988-10-26 $7700.00 Window Closed / Lapsed

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