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US3987141A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for spinning polyurethane-hard polymer conjugate yarn

Assignee: Monsanto Co
•
Filing: 1974-06-24
•
Granted: 1976-10-19
•
Expires: 1994-06-24
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Abstract

Abstract Drawing performance of a conjugated elastomeric polyurethane-hard polymer yarn is improved by critical stoichiometry in preparation of the polyurethane polymer, which is made by reacting together a high molecular weight diol, a low molecular weight diol, and a diisocyanate so that the resulting polyurethane contains between 1 and 45 (preferably between 1 and 27) microequivalents of free isocyanate groups per gram of polymer at the time of melt spinning.

Inventors

  • 👤 Donald H. Martin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 02:23
CPC Classifications
D; D01; D01F; D01F8/00; D01F8/04; D01F8/10; C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/12; C08G18/28; C08G18/65; C08G18/66; C08G18/6603; C08G18/6607; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2929

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 65 words
A process for preparing a conjugate filament, comprising: a. preparing an elastomeric polyurethane polymer having between 1 and 30 microequivalents of free isocyanate per gram of said polyurethane polymer at the time of spinning; b. melt spinning said polyurethane polymer conjugately with a hard polymer to form a conjugate filament; and c. drawing said filament at a draw ratio of at least 2.0 to 1.
Claim 2
Dependent Claim 65 words
A process for preparing a conjugate filament, comprising: a. preparing an elastomeric polyurethane polymer having between 1 and 30 microequivalents of free isocyanate per gram of said polyurethane polymer at the time of spinning; b. melt spinning said polyurethane polymer conjugately with a hard polymer to form a conjugate filament; and c. drawing said filament at a draw ratio of at least 2.0 to 1.
Claim 3
Dependent Claim 65 words
A process for preparing a conjugate filament comprising: a. preparing an elastomeric polyurethane polymer having between 1 and 27 microequivalents of free isocyanate per gram of said polyurethane polymer at the time of spinning; b. melt spinning said polyurethane polymer conjugately with a hard polymer to form a conjugate filament; and c. drawing said filament at a draw ratio of at least 2.0 to 1.
Claim 4
Dependent Claim 65 words
A process for preparing a conjugate filament comprising: a. preparing an elastomeric polyurethane polymer having between 1 and 27 microequivalents of free isocyanate per gram of said polyurethane polymer at the time of spinning; b. melt spinning said polyurethane polymer conjugately with a hard polymer to form a conjugate filament; and c. drawing said filament at a draw ratio of at least 2.0 to 1.
Claim 5
Dependent Claim 75 words
A process for preparing a drawn conjugate filament from a hard polymer and an elastomeric polyurethane polymer, said process comprising: a. measuring the free isocyanate group concentration NCO m at a time T m after said polyurethane polymer was formed; b. melt-spinning said polyurethane polymer conjugately with a hard polymer at a time ##EQU3## to form a conjugate filament; and c. drawing said conjugate filament at a draw ratio of at least 2 to 1.
Claim 6
Dependent Claim 75 words
A process for preparing a drawn conjugate filament from a hard polymer and an elastomeric polyurethane polymer, said process comprising: a. measuring the free isocyanate group concentration NCO m at a time T m after said polyurethane polymer was formed; b. melt-spinning said polyurethane polymer conjugately with a hard polymer at a time ##EQU3## to form a conjugate filament; and c. drawing said conjugate filament at a draw ratio of at least 2 to 1.
Claim 7
Dependent Claim 75 words
A process for preparing a drawn conjugate filament from a hard polymer and an elastomeric polyurethane polymer, said process comprising: a. measuring the free isocyanate group concentration NCO m at a time T m after said polyurethane polymer was formed; b. melt-spinning said polyurethane polymer conjugately with a hard polymer at a time ##EQU4## to form a conjugate filament; and c. drawing said conjugate filament at a draw ratio of at least 2 to 1.
Claim 8
Dependent Claim 75 words
A process for preparing a drawn conjugate filament from a hard polymer and an elastomeric polyurethane polymer, said process comprising: a. measuring the free isocyanate group concentration NCO m at a time T m after said polyurethane polymer was formed; b. melt-spinning said polyurethane polymer conjugately with a hard polymer at a time ##EQU4## to form a conjugate filament; and c. drawing said conjugate filament at a draw ratio of at least 2 to 1.

References Cited (Backward Citations)

US3174949A Cited
US3233025A Cited
US3357954A Cited
US3839284A Cited
US3642964A Cited
US3668185A Cited
US3761348A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-19 1980-04-19 1980-10-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-19 1984-04-19 1984-10-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-19 1988-04-19 1988-10-19 $7700.00 Window Closed / Lapsed

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