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US3986892A Expired / Lapsed US ⏱️ 0.0 years remaining

Porous cobalt electrodes for alkaline accumulators and hybrid cell therewith and air electrode

Assignee: Individual
•
Filing: 1973-12-10
•
Granted: 1976-10-19
•
Expires: 1993-12-10
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Abstract

Abstract A porous, preferably negative, electrode for alkaline accumulators, characterized by the fact that its electro-chemically active inner surface amounts to between 1 and 20 sp.m. per gram for a volume porosity of between 30 and 85% and that its pore interval ranges between 0.15 and 1.0 μm.

Inventors

  • 👤 Henning H. Ewe
  • 👤 Eduard W. Justi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 05:40
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/24; H01M2004/026; H01M2004/027; H01M4/04; H01M4/043; H01M4/0471; H01M4/64; H01M4/66; H01M4/661; H01M4/70; H01M4/76; H01M4/762; H01M50/00; H01M50/40; H01M50/46; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12014; Y10T428/12028; Y10T428/12042; Y10T428/12063; Y10T428/12097; Y10T428/12493; Y10T428/12771; Y10T428/12861

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 47 words
A porous negative cobalt electrode for alkaline accumulators, characterized by the fact that its electro-chemically active inner surface amounts to between 1 and 20 sq.m. per gram with a volume porosity of between 30 and 85% and that its pore interval ranges between 0.15 and 1.0 μm.
Claim 2
Dependent Claim 47 words
A porous negative cobalt electrode for alkaline accumulators, characterized by the fact that its electro-chemically active inner surface amounts to between 1 and 20 sq.m. per gram with a volume porosity of between 30 and 85% and that its pore interval ranges between 0.15 and 1.0 μm.
Claim 3
Dependent Claim 36 words
The porous negative electrode in accordance with claim 1, wherein said pore interval ranges from between two times and about three times the maximum thickness of the cobalt hydroxide layer produced during discharge of the electrode.
Claim 4
Dependent Claim 21 words
The porous negative electrode in accordance with claim 2, wherein said maximum thickness comprises about 500 molecular layers of cobalt hydroxide.
Claim 5
Dependent Claim 79 words
A porous negative cobalt electrode for alkaline accumulators, characterized by the fact that its electro-chemically active inner surface amounts to between 1 and 20 sq.m. per gram with a volume porosity of between 30 and 85%, that its pore interval ranges between 0.15 and 1.0 μm and that it is built up of cobalt granules which have been obtained by the reduction of highly dispersed low-alkali cobalt oxides in a stream of hydrogen at between 500° and 700° C.
Claim 6
Dependent Claim 79 words
A porous negative cobalt electrode for alkaline accumulators, characterized by the fact that its electro-chemically active inner surface amounts to between 1 and 20 sq.m. per gram with a volume porosity of between 30 and 85%, that its pore interval ranges between 0.15 and 1.0 μm and that it is built up of cobalt granules which have been obtained by the reduction of highly dispersed low-alkali cobalt oxides in a stream of hydrogen at between 500° and 700° C.
Claim 7
Dependent Claim 40 words
The porous negative electrode in accordance with claim 4, characterised by the fact that the cobalt powder according to the invention is contained without the addition of conducting substance in perforated tubes or boxes made of nickel plated sheet steel.
Claim 8
Dependent Claim 25 words
The porous negative electrode in accordance with claim 4, characterised by the fact that it comprises cobalt powder which is compacted without frame or stays.
Claim 9
Dependent Claim 31 words
The porous negative electrode in accordance with claim 6, characterised by the fact that it contains in its interior a nickel gauze or mesh which is connected with a current discharge.
Claim 10
Dependent Claim 29 words
Alkaline accumulator comprising one or more negative electrodes in accordance with claim 4 and one or more positive electrodes of the nickel hydroxide type combined with said negative electrodes.
Claim 11
Dependent Claim 54 words
Alkaline hybrid battery comprising as negative accumulator electrode, an electrode according to claim 4 a separator of thin porous plastic foil encasing said negative electrode, as positive discharge electrode, two air-breathing cathodes and as positive charging electrodes, two nickel gauzes, said gauzes being arranged between the negative storage electrode and the positive discharge electrode.
Claim 12
Dependent Claim 25 words
The porous negative electrode in accordance with claim 4, wherein said electro-chemically active inner surface area is between about 1 and 10 m 2 /g.
Claim 13
Dependent Claim 49 words
A method for fabricating the porous negative electrode of claim 1, comprising the steps of reducing a highly-dispersed low-alkali cobalt oxide in a stream of hydrogen at a temperature between 500° and 700° C., whereby cobalt is produced and shaping said cobalt into a configuration suitable for said electrode.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-19 1980-04-19 1980-10-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-19 1984-04-19 1984-10-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-19 1988-04-19 1988-10-19 $7700.00 Window Closed / Lapsed

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