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US3985577A Expired / Lapsed US ⏱️ 0.0 years remaining

Lithium/fluorographite primary cell with improved electrolyte

Assignee: Eagle Picher Industries Inc
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Filing: 1974-09-12
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Granted: 1976-10-12
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Expires: 1994-09-12
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Abstract

Abstract A primary cell having a lithium anode, a fluorographite cathode, and an electrolyte of dimethyl sulfite containing dissolved lithium hexafluoroarsenate demonstrates discharge characteristics in excess of theoretical. For low temperature operation, an electrolyte employing a mixture of dimethyl sulfite and methyl formate solvents gives results superior to either solvent used independently.

Inventors

  • 👤 Jerry L. Russell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 22:25
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/14; H01M6/16; H01M6/162; H01M6/164

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 99 words
A primary cell comprising, a lithium anode, a cathode having as the active component thereof a fluorographite of the type (CF x ) n where x is greater than about 0.5 and n is an indefinitely large number, and an electrolyte comprising a solvent and a solute, the said solvent consisting of an organic liquid which is a member of the class consisting of dimethyl sulfite and mixtures of dimethyl sulfite and methyl formate, the said solute consisting of lithium hexafluoroarsenate dissolved in said solvent, the said cell having a yield efficiency which is substantially in excess of 100%.
Claim 2
Dependent Claim 99 words
A primary cell comprising, a lithium anode, a cathode having as the active component thereof a fluorographite of the type (CF x ) n where x is greater than about 0.5 and n is an indefinitely large number, and an electrolyte comprising a solvent and a solute, the said solvent consisting of an organic liquid which is a member of the class consisting of dimethyl sulfite and mixtures of dimethyl sulfite and methyl formate, the said solute consisting of lithium hexafluoroarsenate dissolved in said solvent, the said cell having a yield efficiency which is substantially in excess of 100%.
Claim 3
Dependent Claim 11 words
The primary cell of claim 1 wherein x is about 1.0.
Claim 4
Dependent Claim 12 words
The primary cell of claim 1 wherein said solvent is dimethyl sulfite.
Claim 5
Dependent Claim 13 words
The primary cell of claim 3 wherein the solvent is saturated with solute.
Claim 6
Dependent Claim 38 words
The primary cell of claim 1 wherein said solvent is a mixture of dimethyl sulfite and methyl formate, and wherein the methyl formate content of said mixture is in the range of about 25 to 75% by volume.
Claim 7
Dependent Claim 20 words
The primary cell of claim 5 wherein the volume ratio of the two solvents to one another is about 1:1.
Claim 8
Dependent Claim 14 words
The primary cell of claim 5 wherein the solute concentration is about 1.5 molar.
Claim 9
Dependent Claim 25 words
The primary cell of claim 1 wherein the proportion of electrolyte to fluorographite is about 2 to 3 cc of electrolyte per gram of fluorographite.

References Cited (Backward Citations)

US3415687A Cited
US3536532A Cited
US3514337A Cited
US3579384A Cited
US3681144A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-12 1980-04-12 1980-10-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-12 1984-04-12 1984-10-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-12 1988-04-12 1988-10-12 $7700.00 Window Closed / Lapsed

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