US3984604A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Aromatic polysulphone coated article and bonded structure
Assignee: Imperial Chemical Industries Ltd
•
Filing: 1974-04-16
•
Granted: 1976-10-05
•
Expires: 1994-04-16
Abstract
Abstract A solid surface is coated with an adhesive composition comprising an aromatic polysulphone which has a reduced viscosity of at least 0.3 and which contains at least 0.2 (desirably 0.5 to 3.5) hydroxyl groups per 100 polymer repeat units and has been heated at 330 DEG to 450 DEG C in the presence of oxygen.
Inventors
- 👤 Terence King
- 👤 John Brewster Rose
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 03:49
CPC Classifications
C; C09; C09J; C09J181/00; C09J181/06; A; A47; A47J; A47J36/00; A47J36/02; B; B05; B05D; B05D3/00; B05D3/02; B05D3/0254; B05D3/06; B05D3/061; B05D3/065; B05D3/068; B05D5/00; B05D5/08; B05D5/083; C09D; C09D127/00; C09D127/02; C09D127/12; C09D181/00; C09D181/06; B05D2202/00; B05D2202/20; B05D2202/25; B05D3/04; B05D3/0486; C08; C08L; C08L81/00; C08L81/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31544; Y10T428/31678
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
187 words
A solid surface hving a baked on, substantially crosslinked coating formed from an adhesive composition comprising an aromatic polysulphone whose number average molecular weight is sufficiently high to give a reduced viscosity of at least 0.3 (measured at 25°C on a solution in dimethyl formamide containing 1 g of polymer in 100 cm 3 of solution) and which contains at least 0.2 aromatically bound hydroxy end-groups per 100 polymer repeat units, said coating being characterized by its increased adhesion to said surface as evidenced by increased shear strength compared with the case where said coating is formed from a similar polysulphone with less than the indicated number of aromatically bound hydroxyl groups, the polysulphone being crosslinked at the molecular weight thereof being increased subsequent to coating by baking the coating in the presence of oxygen, said increased molecular weight and substantial crosslinking being evidenced by the insolubility of the baked polysulphone coating in dimethyl fomamide at 25°C compared with the solubility of the aromatic polysulphone in the non-baked coating and the solubility of the aromatic polysulphone when baked in the absence of air under otherwise comparable conditions.
Claim 2
Dependent Claim
187 words
A solid surface hving a baked on, substantially crosslinked coating formed from an adhesive composition comprising an aromatic polysulphone whose number average molecular weight is sufficiently high to give a reduced viscosity of at least 0.3 (measured at 25°C on a solution in dimethyl formamide containing 1 g of polymer in 100 cm 3 of solution) and which contains at least 0.2 aromatically bound hydroxy end-groups per 100 polymer repeat units, said coating being characterized by its increased adhesion to said surface as evidenced by increased shear strength compared with the case where said coating is formed from a similar polysulphone with less than the indicated number of aromatically bound hydroxyl groups, the polysulphone being crosslinked at the molecular weight thereof being increased subsequent to coating by baking the coating in the presence of oxygen, said increased molecular weight and substantial crosslinking being evidenced by the insolubility of the baked polysulphone coating in dimethyl fomamide at 25°C compared with the solubility of the aromatic polysulphone in the non-baked coating and the solubility of the aromatic polysulphone when baked in the absence of air under otherwise comparable conditions.
Claim 3
Dependent Claim
26 words
A solid surface according to claim 1 in which the molecular weight of the aromatic polysulphone was increased by heating at temperatures of 350° to 450°C.
Claim 4
Dependent Claim
17 words
A solid surface according to claim 1 in which said surface is the non-cooking surface of cookware.
Claim 5
Dependent Claim
14 words
A solid surface according to claim 1 in which the aromatic polysulphone contains pigment.
Claim 6
Dependent Claim
43 words
A solid surface according to claim 1 in which the aromatic polysulphone is based on repeat units having the formula I or II either alone or in combination with each other and/or with up to 80% of units having the formula III ##SPC15##
Claim 7
Dependent Claim
25 words
A solid surface according to claim 1 in which the aromatic polysulphone contains 0.5 to 3.0 aromatically bound hydroxyl groups per 100 polymer repeat units.
Claim 8
Dependent Claim
49 words
A solid surface according to claim 1 in which the aromatic polysulphone is blended with at least one fluorocarbon polymer so as to form a coating mixture which comprises 10 to 90% of at least one thermoplastic aromatic polysulphone and 90 to 10% of at least one fluorocarbon polymer.
Claim 9
Dependent Claim
14 words
A solid surface according to claim 7 in which the fluorocarbon polymer is poly(tetrafluoroethylene).
Claim 10
Dependent Claim
17 words
A solid surface according to claim 7 in which said surface is the cooking surface of cookware.
Claim 11
Dependent Claim
17 words
A solid surface according to claim 1 in which the coating was baked at 330° to 450°C.
References Cited (Backward Citations)
GB1060546A
Cited
GB1153035A
Cited
US3499780A
Cited
US3471587A
Cited
US3542574A
Cited
US3674738A
Cited
US3769150A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-10-05 | 1980-04-05 | 1980-10-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-10-05 | 1984-04-05 | 1984-10-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-10-05 | 1988-04-05 | 1988-10-05 | $7700.00 | Window Closed / Lapsed |