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US3984604A Expired / Lapsed US ⏱️ 0.0 years remaining

Aromatic polysulphone coated article and bonded structure

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1974-04-16
•
Granted: 1976-10-05
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Expires: 1994-04-16
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Abstract

Abstract A solid surface is coated with an adhesive composition comprising an aromatic polysulphone which has a reduced viscosity of at least 0.3 and which contains at least 0.2 (desirably 0.5 to 3.5) hydroxyl groups per 100 polymer repeat units and has been heated at 330 DEG to 450 DEG C in the presence of oxygen.

Inventors

  • 👤 Terence King
  • 👤 John Brewster Rose

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 03:49
CPC Classifications
C; C09; C09J; C09J181/00; C09J181/06; A; A47; A47J; A47J36/00; A47J36/02; B; B05; B05D; B05D3/00; B05D3/02; B05D3/0254; B05D3/06; B05D3/061; B05D3/065; B05D3/068; B05D5/00; B05D5/08; B05D5/083; C09D; C09D127/00; C09D127/02; C09D127/12; C09D181/00; C09D181/06; B05D2202/00; B05D2202/20; B05D2202/25; B05D3/04; B05D3/0486; C08; C08L; C08L81/00; C08L81/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31544; Y10T428/31678

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 187 words
A solid surface hving a baked on, substantially crosslinked coating formed from an adhesive composition comprising an aromatic polysulphone whose number average molecular weight is sufficiently high to give a reduced viscosity of at least 0.3 (measured at 25°C on a solution in dimethyl formamide containing 1 g of polymer in 100 cm 3 of solution) and which contains at least 0.2 aromatically bound hydroxy end-groups per 100 polymer repeat units, said coating being characterized by its increased adhesion to said surface as evidenced by increased shear strength compared with the case where said coating is formed from a similar polysulphone with less than the indicated number of aromatically bound hydroxyl groups, the polysulphone being crosslinked at the molecular weight thereof being increased subsequent to coating by baking the coating in the presence of oxygen, said increased molecular weight and substantial crosslinking being evidenced by the insolubility of the baked polysulphone coating in dimethyl fomamide at 25°C compared with the solubility of the aromatic polysulphone in the non-baked coating and the solubility of the aromatic polysulphone when baked in the absence of air under otherwise comparable conditions.
Claim 2
Dependent Claim 187 words
A solid surface hving a baked on, substantially crosslinked coating formed from an adhesive composition comprising an aromatic polysulphone whose number average molecular weight is sufficiently high to give a reduced viscosity of at least 0.3 (measured at 25°C on a solution in dimethyl formamide containing 1 g of polymer in 100 cm 3 of solution) and which contains at least 0.2 aromatically bound hydroxy end-groups per 100 polymer repeat units, said coating being characterized by its increased adhesion to said surface as evidenced by increased shear strength compared with the case where said coating is formed from a similar polysulphone with less than the indicated number of aromatically bound hydroxyl groups, the polysulphone being crosslinked at the molecular weight thereof being increased subsequent to coating by baking the coating in the presence of oxygen, said increased molecular weight and substantial crosslinking being evidenced by the insolubility of the baked polysulphone coating in dimethyl fomamide at 25°C compared with the solubility of the aromatic polysulphone in the non-baked coating and the solubility of the aromatic polysulphone when baked in the absence of air under otherwise comparable conditions.
Claim 3
Dependent Claim 26 words
A solid surface according to claim 1 in which the molecular weight of the aromatic polysulphone was increased by heating at temperatures of 350° to 450°C.
Claim 4
Dependent Claim 17 words
A solid surface according to claim 1 in which said surface is the non-cooking surface of cookware.
Claim 5
Dependent Claim 14 words
A solid surface according to claim 1 in which the aromatic polysulphone contains pigment.
Claim 6
Dependent Claim 43 words
A solid surface according to claim 1 in which the aromatic polysulphone is based on repeat units having the formula I or II either alone or in combination with each other and/or with up to 80% of units having the formula III ##SPC15##
Claim 7
Dependent Claim 25 words
A solid surface according to claim 1 in which the aromatic polysulphone contains 0.5 to 3.0 aromatically bound hydroxyl groups per 100 polymer repeat units.
Claim 8
Dependent Claim 49 words
A solid surface according to claim 1 in which the aromatic polysulphone is blended with at least one fluorocarbon polymer so as to form a coating mixture which comprises 10 to 90% of at least one thermoplastic aromatic polysulphone and 90 to 10% of at least one fluorocarbon polymer.
Claim 9
Dependent Claim 14 words
A solid surface according to claim 7 in which the fluorocarbon polymer is poly(tetrafluoroethylene).
Claim 10
Dependent Claim 17 words
A solid surface according to claim 7 in which said surface is the cooking surface of cookware.
Claim 11
Dependent Claim 17 words
A solid surface according to claim 1 in which the coating was baked at 330° to 450°C.

References Cited (Backward Citations)

GB1060546A Cited
GB1153035A Cited
US3499780A Cited
US3471587A Cited
US3542574A Cited
US3674738A Cited
US3769150A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-05 1980-04-05 1980-10-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-05 1984-04-05 1984-10-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-05 1988-04-05 1988-10-05 $7700.00 Window Closed / Lapsed

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