US3984583A
Expired / Lapsed
US
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Electron beam recording method
Assignee: Agfa Gevaert NV
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Filing: 1974-10-22
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Granted: 1976-10-05
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Expires: 1994-10-22
Abstract
Abstract An electron beam-sensitive recording material that has a sensitivity to ultra-violet radiation not high enough to provide an optical density in the visible spectrum range of more than 0.2 when exposed with said radiation under the described test conditions, wherein said material comprises: A. at least one dye precursor compound, which is capable of forming a dye when being in working relationship with an electron beam-exposed compound of the group mentioned here under (B), and B. a halogen-containing polymer undergoing dehydro-halogenation on electron beam impact and/or an organic compound containing one or two halogen atoms linked to a same carbon atom that is further linked to at least one electron-withdrawing group, and/or an organic compound that contains at least one non-halogen carrying carbon atom bound to at least one hydrogen atom and at least two electron-withdrawing groups, and/or a polyhalogenated aromatic hydroxy compound.
Inventors
- 👤 Theofiel Eveline Hermans
- 👤 Gerard Albert Delzenne
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 13:27
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/72; G03C1/73; G03C1/733; Y; Y10; Y10S; Y10S428/00; Y10S428/913
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
48 words
In a method of recording information by scanning an electron beam sensitive recording material with an electron beam modulated in intensity according to the information to be recorded, the improvement wherein said recording material comprises an electrically conductive substrate and superimposed thereon a layer comprising a mixture of:
Claim 2
Dependent Claim
48 words
In a method of recording information by scanning an electron beam sensitive recording material with an electron beam modulated in intensity according to the information to be recorded, the improvement wherein said recording material comprises an electrically conductive substrate and superimposed thereon a layer comprising a mixture of:
Claim 3
Dependent Claim
129 words
at least one dye precursor compound of the group consisting of a sirodibenzopyran, a spirodinaphthopyran, a spirobenzonaphthopyran, a 1,3,3-trimethylindolinobenzospiropyran, a 1,3,3-trimethylindolino-naphthospiropyran, a spiropyran that contains a condensed aromatic nucleus of anthracene or phenanthrene, or a compound having one of the general formulae: ##SPC15## wherein: R 1 represents an alkyl group, a phenyl group, a naphthyl group, or together with R' the necessary atoms to close a cyclohexyl ring, R' represents hydrogen, a C 1 -C 5 alkyl group, a phenyl group or a phenoxy group, Z 1 represents the necessary atoms to close a phenyl or naphthyl nucleus, Z 2 represents the necessary atoms to close a benzene or naphthalene nucleus, R 2 represents a C 1 -C 5 alkyl group, and n represents 1 or 2, and 2.
Claim 4
Dependent Claim
129 words
at least one dye precursor compound of the group consisting of a sirodibenzopyran, a spirodinaphthopyran, a spirobenzonaphthopyran, a 1,3,3-trimethylindolinobenzospiropyran, a 1,3,3-trimethylindolino-naphthospiropyran, a spiropyran that contains a condensed aromatic nucleus of anthracene or phenanthrene, or a compound having one of the general formulae: ##SPC15## wherein: R 1 represents an alkyl group, a phenyl group, a naphthyl group, or together with R' the necessary atoms to close a cyclohexyl ring, R' represents hydrogen, a C 1 -C 5 alkyl group, a phenyl group or a phenoxy group, Z 1 represents the necessary atoms to close a phenyl or naphthyl nucleus, Z 2 represents the necessary atoms to close a benzene or naphthalene nucleus, R 2 represents a C 1 -C 5 alkyl group, and n represents 1 or 2, and 2.
Claim 5
Dependent Claim
97 words
at least one member of the group consisting of an organic compound containing one or two halogen atoms linked to the same carbon atom that is further linked to at least one electron-withdrawing group, an organic compound that contains at least one non-halogen carrying carbon atom bound to at least one hydrogen atom and at least two electron-withdrawing groups, and a polyhalogenated aromatic hydroxy compound, said layer having a sufficiently low sensitivity to ultra-violet radiation that it exhibits an optical density not higher than 0.2 when exposed according to the standard test procedure described in the specification.
Claim 6
Dependent Claim
97 words
at least one member of the group consisting of an organic compound containing one or two halogen atoms linked to the same carbon atom that is further linked to at least one electron-withdrawing group, an organic compound that contains at least one non-halogen carrying carbon atom bound to at least one hydrogen atom and at least two electron-withdrawing groups, and a polyhalogenated aromatic hydroxy compound, said layer having a sufficiently low sensitivity to ultra-violet radiation that it exhibits an optical density not higher than 0.2 when exposed according to the standard test procedure described in the specification.
Claim 7
Dependent Claim
27 words
An electron beam recording method according to claim 1 wherein said mixture of compounds (1) and (2) are contained in a binder layer applied to said substrate.
Claim 8
Dependent Claim
37 words
An electron beam recording method according to claim 1 wherein said mixture of compounds (1) and (2) are contained in a binder layer applied to an electrically conductive interlayer, which is carried on an electrically insulating support.
Claim 9
Dependent Claim
24 words
An electron beam recording method according to claim 1 wherein said substrate has a surface resistance not lower than 1 × 10 7 Ω/sq.cm.
Claim 10
Dependent Claim
17 words
An electron beam recording method according to claim 3 wherein said support is a transparent resin support.
Claim 11
Dependent Claim
56 words
An electron beam recording method according to claim 1 wherein said compound (2) is an organic compound containing one or two halogen atoms linked to the same carbon atom that is further linked to at least one electron-withdrawing group of the class consisting of >C=O, >SO 2 , -C≡N, -NO 2 , -N 3 and phenyl.
Claim 12
Dependent Claim
58 words
An electron beam recording method according to claim 1 wherein said compound (2) is an organic compound containing at least one non-halogen-carrying carbon atom linked to at least one hydrogen atom and at least two electron-withdrawing groups of the class consisting of >C=O, >SO 2 , -C≡N, -N 3 and -O-CO-R in which R is an organic group.
Claim 13
Dependent Claim
27 words
An electron beam recording method according to claim 1 wherein the amount of dye precursor compound per sq.m is in the range of 0.25 to 2 g.
Claim 14
Dependent Claim
30 words
An electron beam recording method according to claim 1 wherein said compound (2) is used with respect to the dye precursor compound in a molar ratio of 2:1 to 20:1.
Claim 15
Dependent Claim
116 words
An electron beam recording method according to claim 1 wherein said precursor is a spiropyran having one of the general formulae: ##SPC16## wherein: R, r 1 , r' 1 , r 2 , r' 2 , r 3 and R' 3 each represent hydrogen, alkyl, alkyl substituted with halogen, alkyl substituted with an ester group, alkyl substituted with a carboxyl group, alkyl substituted with a N-phenylcarbamyl group, a hydroxy group, an alkoxy group, an aryloxy group, a phenyl group, piperidyl, acetyl, halogen, nitro, or R 1 and R' 1 together represent a -(CH 2 ) n - chain wherein n = 2 or 3 to link the carbon atoms in the 3 and 3' positions together.
References Cited (Backward Citations)
US3331076A
Cited
US3331077A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-10-05 | 1980-04-05 | 1980-10-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-10-05 | 1984-04-05 | 1984-10-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-10-05 | 1988-04-05 | 1988-10-05 | $7700.00 | Window Closed / Lapsed |