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US3984493A Expired / Lapsed US ⏱️ 0.0 years remaining

Homogeneous blend of vinyl chloride polymer with thermoplastic polyester-urethane

Assignee: Kao Corp
•
Filing: 1975-01-23
•
Granted: 1976-10-05
•
Expires: 1995-01-23
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Abstract

Abstract A non-crystalline resin composition possessing rubberlike elasticity, prepared by homogeneously mixing (1) 100 parts by weight of a vinyl chloride polymer, with (2) 110 to 160 parts by weight of a thermoplastic polyester-urethane formed by reacting an organic diisocyanate with a polyester diol having a molecular weight of at least 4000, said polyester diol having been formed by reacting a polyol component comprising 1,6-hexanediol and a low molecular weight diol having a side-chain methyl group at a mixing molar ratio of from 70 : 30 to 90 : 10, with a saturated aliphatic dicarboxylic acid having 5 to 8 carbon atoms.

Inventors

  • 👤 Yoshiteru Kazama
  • 👤 Yasuo Miura
  • 👤 Yuji Suzuki
  • 👤 Kazuo Iguchi
  • 👤 Kenji Kawabuchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 06:31
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/42; C08G18/4236; C08G18/4238; C08L; C08L75/00; C08L75/04; C08L75/06; C08G2170/00; C08G2170/90

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 169 words
A non-crystalline elastomeric resin composition having a glass transition temperature of from about -3° to -10°C, consisting essentially of a homogeneous blend of I. polyvinyl chloride or a copolymer of from 85 to 99.9 percent by weight of vinyl chloride and the balance is at least one monomer copolymerizable with vinyl chloride, and Ii. a thermoplastic polyester-urethane obtained by reacting an organic urethane-forming diisocyanate with a polyester diol having a molecular weight of from 6000 to 10000, said polyester diol having been obtained by reacting a saturated aliphatic dicarboxylic acid having from 5 to 8 carbon atoms, with a polyol component consisting essentially of a mixture of (a) 1,6-hexanediol and (b) at least one diol selected from the group consisting of propylene glycol, 1,3-butylene glycol, neopentyl glycol and trimethylpentane diol, the molar ratio of (a) : (b) being in the range of from 70 : 30 to 90 : 10, the composition containing from 110 to 160 parts by weight of II, per 100 parts by weight of I.
Claim 2
Dependent Claim 169 words
A non-crystalline elastomeric resin composition having a glass transition temperature of from about -3° to -10°C, consisting essentially of a homogeneous blend of I. polyvinyl chloride or a copolymer of from 85 to 99.9 percent by weight of vinyl chloride and the balance is at least one monomer copolymerizable with vinyl chloride, and Ii. a thermoplastic polyester-urethane obtained by reacting an organic urethane-forming diisocyanate with a polyester diol having a molecular weight of from 6000 to 10000, said polyester diol having been obtained by reacting a saturated aliphatic dicarboxylic acid having from 5 to 8 carbon atoms, with a polyol component consisting essentially of a mixture of (a) 1,6-hexanediol and (b) at least one diol selected from the group consisting of propylene glycol, 1,3-butylene glycol, neopentyl glycol and trimethylpentane diol, the molar ratio of (a) : (b) being in the range of from 70 : 30 to 90 : 10, the composition containing from 110 to 160 parts by weight of II, per 100 parts by weight of I.
Claim 3
Dependent Claim 19 words
A composition according to claim 1 in which component I has a degree of polymerization of at least 600.
Claim 4
Dependent Claim 29 words
A composition according to claim 1 in which said saturated aliphatic dicarboxylic acid is selected from the group consisting of adipic acid, pimelic acid, suberic acid and methyladipic acid.
Claim 5
Dependent Claim 16 words
A composition according to claim 1, in which said saturated aliphatic dicarboxylic acid is adipic acid.
Claim 6
Dependent Claim 13 words
A composition according to claim 4, in which said diisocyanate is 4,4'-diphenylmethane diisocyanate.
Claim 7
Dependent Claim 13 words
A composition according to claim 4, in which said diisocyanate is 4,4'-diphenyl isocyanate.
Claim 8
Dependent Claim 13 words
A composition according to claim 4, in which said diisocyanate is 2,4-tolylene diisocyanate.
Claim 9
Dependent Claim 13 words
A composition according to claim 4, in which said diisocyanate is 2,6-tolylene diisocyanate.
Claim 10
Dependent Claim 13 words
A composition according to claim 4, in which said diisocyanate is 1,5-naphthylene diisocyanate.
Claim 11
Dependent Claim 16 words
A composition according to claim 4, in which said diisocyanate is o-, m- or p-xylylene diisocyanate.

References Cited (Backward Citations)

GB844240A Cited
US3444266A Cited
US3381056A Cited
US3467731A Cited
US3763054A Cited
US3718622A Cited
US3905929A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-05 1980-04-05 1980-10-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-05 1984-04-05 1984-10-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-05 1988-04-05 1988-10-05 $7700.00 Window Closed / Lapsed

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