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US3984443A Expired / Lapsed US ⏱️ 0.0 years remaining

Indamines for dyeing keratinic fibers

Assignee: L'Oréal SA
•
Filing: 1975-02-25
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Granted: 1976-10-05
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Expires: 1995-02-25
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Abstract

Abstract Indamine having the formula WHEREIN R and R' each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms, lower alkoxy having 1-4 carbon atoms, amino, acylamino wherein the acyl moiety has 1 to 4 carbon atoms and hydroxy, with the proviso that one, but not both of R and R' is said amino, acylamino or hydroxy; R1 and R2 each independently represent a member selected from the group consisting of lower alkyl having 1-4 carbon atoms and lower alkyl having 1-4 carbon atoms and substituted with a member selected from the group consisting of hydroxy, acylamino wherein the acyl moiety has 1 to 4 carbon atoms, carbamyl, piperidino, benzoylamino and alkylsulfonamido wherein the alkyl moiety has 1 to 4 carbon atoms; R3, R4, R5, R6, R7 and R8 each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms and lower alkoxy having 1-4 carbon atoms, and the salts formed by these indamines with organic or inorganic acids, in particular, their acetates, hydrochlorides, hydrobromides, persulfates, perchlorates and the double zinc salts of these compounds, which can, of course, be in a tautomeric form of that represented by formula (I), are usefully employed for dyeing keratinous fibers, and, in particular, human hair.

Inventors

  • 👤 Gregoire Kalopissis
  • 👤 Andre Bugaut
  • 👤 Francoise Estradier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 17:29
CPC Classifications
A; A61; A61Q; A61Q5/00; A61Q5/10; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/413; Y; Y10; Y10S; Y10S424/00; Y10S424/01; Y10S424/02

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 171 words
An indamine selected from the group consisting of a. an indamine having the formula ##SPC27## wherein R and R' each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms, lower alkoxy having 1-4 carbon atoms, amino, acetylamino and hydroxy with the proviso that one, but not both of R and R' is said amino, acetylamino or hydroxy; R 1 and R 2 each independently represent a member selected from the group consisting of lower alkyl having 1-4 carbon atoms and lower alkyl having 1-4 carbon atoms and substituted with a member selected from the group consisting of hydroxy, acetylamino, benzoylamino and alkylsulfonamido wherein the alkyl moiety has 1-4 carbon atoms, and R 3 , r 4 , r 5 , r 6 , r 7 and R 8 each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms and lower alkoxy having 1-4 carbon atoms and b. an acid salt of said indamine in (a).
Claim 2
Dependent Claim 171 words
An indamine selected from the group consisting of a. an indamine having the formula ##SPC27## wherein R and R' each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms, lower alkoxy having 1-4 carbon atoms, amino, acetylamino and hydroxy with the proviso that one, but not both of R and R' is said amino, acetylamino or hydroxy; R 1 and R 2 each independently represent a member selected from the group consisting of lower alkyl having 1-4 carbon atoms and lower alkyl having 1-4 carbon atoms and substituted with a member selected from the group consisting of hydroxy, acetylamino, benzoylamino and alkylsulfonamido wherein the alkyl moiety has 1-4 carbon atoms, and R 3 , r 4 , r 5 , r 6 , r 7 and R 8 each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms and lower alkoxy having 1-4 carbon atoms and b. an acid salt of said indamine in (a).
Claim 3
Dependent Claim 47 words
The indamine of claim 1 selected from the group consisting of the hydrochloride of N-[(4'-dimethylamino)phenyl]-3-amino-6-methoxy benzoquinonediimine, N-[(4'-dimethylamino)phenyl]-3-amino-6-methoxy benzoquinonediimine, the persulfate of N-[(4'-dimethylamino)phenyl]-3-acetylamino-6-methyl benzoquinonediimine, N-[(4'-dimethylamino)phenyl]-3-acetylamino-6-methyl benzoquinonediimine, the perchlorate of N-[(2'-amino-4'-dimethylamino)phenyl] benzoquinonediimine, the acetate of N-[(2'-acetylamino-4'-dimethylamino)phenyl]-3-methoxy-6-methyl benzoquinonediimine, the perchlorate of N-[(4'-diethylamino-2'-amino)phenyl]-2,6-dimethyl-3-methoxy benzoquinonediimine and the persulfate of N-[(4'-[ethyl, β-mesylaminoethyl]-amino-2'-methyl)phenyl]-3-acetylamino-6-methyl benzoquinonediimine.
Claim 4
Dependent Claim 10 words
The indamine of claim 1 which is N-[(4'-di-β-hydroxyethylamino) phenyl]-2-methoxy-5-amino benzoquinonediimine.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-05 1980-04-05 1980-10-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-05 1984-04-05 1984-10-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-05 1988-04-05 1988-10-05 $7700.00 Window Closed / Lapsed

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