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US3984335A Expired / Lapsed US ⏱️ 0.0 years remaining

Compositions for souring and softening laundered textile materials and stock solutions prepared therefrom

Assignee: Diversey Wyandotte Corp
•
Filing: 1975-01-16
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Granted: 1976-10-05
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Expires: 1995-01-16
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Abstract

Abstract Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile materials. When in the form of a stable homogeneous liquid, the composition may contain a quaternized fatty amide, a quaternized fatty amine, an aqueous emulsion of partially oxidized polyethylene or a fatty amphoteric compound as a softening agent, a water soluble organic acid containing about 1-20 carbon atoms and having a primary ionization constant between 10.sup. -1 and 10.sup. -5 as the souring agent, and water. When in the form of a stable dry solid, the composition may contain a quaternized fatty amide, a quaternized fatty amine or a fatty amphoteric compound as the softening agent, and a dry solid water soluble organic acid containing 2-20 carbon atoms and having a primary ionization constant between 10.sup. -1 and 10.sup. -5 as the souring agent. Stable homogeneous stock solutions are also prepared from the novel liquid or solid compositions of the invention.

Inventors

  • 👤 John D. Ciko
  • 👤 John J. Cramer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:26
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/38; C11D1/62; C11D1/88; C11D1/94; C11D3/00; C11D3/0005; C11D3/001; C11D3/0015; C11D3/16; C11D3/37; C11D3/3746; C11D3/3749; D; D06; D06M; D06M13/00; D06M13/322; D06M13/46; D06M13/461; D06M13/463

Claims Analysis

Total Claims: 46
Claim 1
Independent Claim 329 words
A stable homogeneous liquid composition for souring laundered textile materials and imparting softness thereto comprising: I. about 0.5-25% by weight of a softening agent for textile materials selected from the group consisting of A. quaternized fatty amides corresponding to the following structural formulae ##EQU1## wherein R is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 8-22 carbon atoms, R' is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 1-3 carbon atoms, Z is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 1-22 carbon atoms, n is about 1-6, X is an anion selected from the group consisting of halide, sulfate, phosphate, alkyl sulfates having about 1-3 carbon atoms in the alkyl group and alkyl phosphates having about 1-3 carbon atoms in the alkyl group, and Y is an integer having a numerical value equivalent to the valency of X; B. quaternized fatty amines corresponding to the following structural formula ##EQU2## wherein R, R', X and Y are as defined in (A) above; C. An aqueous emulsion of partially oxidized emulsifiable polyethylene having a molecular weight of about 1000-10,000, and D. fatty amphoteric compounds corresponding to the structural formula ##EQU3## wherein R, R' and n are as defined in (A) above, the said amphoteric compounds having non-acidic isoelectric ranges; Ii. about 7.5-75% by weight of an acidic souring agent for laundered textile materials, the souring agent being a water soluble organic carboxylic acid containing about 2-10 carbon atoms and having a primary ionization constant between 10.sup. -1 and 10.sup. -5 , and Iii. about 0-92% by weight of water; the said ingredients I and II being present in amounts whereby laundered textile materials are effectively softened and simultaneously soured upon treatment with the said liquid composition, and the said ingredients I, II and III being present in amounts whereby a stable homogeneous liquid composition is produced.
Claim 2
Dependent Claim 329 words
A stable homogeneous liquid composition for souring laundered textile materials and imparting softness thereto comprising: I. about 0.5-25% by weight of a softening agent for textile materials selected from the group consisting of A. quaternized fatty amides corresponding to the following structural formulae ##EQU1## wherein R is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 8-22 carbon atoms, R' is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 1-3 carbon atoms, Z is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 1-22 carbon atoms, n is about 1-6, X is an anion selected from the group consisting of halide, sulfate, phosphate, alkyl sulfates having about 1-3 carbon atoms in the alkyl group and alkyl phosphates having about 1-3 carbon atoms in the alkyl group, and Y is an integer having a numerical value equivalent to the valency of X; B. quaternized fatty amines corresponding to the following structural formula ##EQU2## wherein R, R', X and Y are as defined in (A) above; C. An aqueous emulsion of partially oxidized emulsifiable polyethylene having a molecular weight of about 1000-10,000, and D. fatty amphoteric compounds corresponding to the structural formula ##EQU3## wherein R, R' and n are as defined in (A) above, the said amphoteric compounds having non-acidic isoelectric ranges; Ii. about 7.5-75% by weight of an acidic souring agent for laundered textile materials, the souring agent being a water soluble organic carboxylic acid containing about 2-10 carbon atoms and having a primary ionization constant between 10.sup. -1 and 10.sup. -5 , and Iii. about 0-92% by weight of water; the said ingredients I and II being present in amounts whereby laundered textile materials are effectively softened and simultaneously soured upon treatment with the said liquid composition, and the said ingredients I, II and III being present in amounts whereby a stable homogeneous liquid composition is produced.
Claim 3
Dependent Claim 20 words
The liquid composition of claim 1 wherein the softening agent is present in an amount of about 1-15% by weight.
Claim 4
Dependent Claim 20 words
The liquid composition of claim 1 wherein the souring agent is present in an amount of about 7.5-55% by weight.
Claim 5
Dependent Claim 45 words
The liquid composition of claim 1 wherein the softening agent is present in an amount of about 1-15% by weight, the souring agent is present in an amount of about 7.5-55% by weight, and water is present in an amount of about 30-91.5% by weight.
Claim 6
Dependent Claim 15 words
The liquid composition of claim 1 wherein the softening agent is a quaternized fatty amine.
Claim 7
Dependent Claim 32 words
The liquid composition of claim 1 wherein the souring agent is selected from the group consisting of acetic acid, citric acid, glycolic acid, maleic acid, malonic acid, oxalic acid and tartaric acid.
Claim 8
Dependent Claim 13 words
The liquid composition of claim 1 wherein the souring agent is glycolic acid.
Claim 9
Dependent Claim 22 words
The liquid composition of claim 1 wherein the softening agent is a quaternized fatty amine and the souring agent is glycolic acid.
Claim 10
Dependent Claim 18 words
The liquid composition of claim 1 wherein R is a monovalent alkyl radical containing about 12-18 carbon atoms.
Claim 11
Dependent Claim 17 words
The liquid composition of claim 1 wherein R' is a monovalent alkyl radical containing one carbon atom.
Claim 12
Dependent Claim 28 words
The liquid composition of claim 1 wherein Z is selected from the group consisting of monovalent alkyl radicals containing about one carbon atom and about 12-18 carbon atoms.
Claim 13
Dependent Claim 11 words
The liquid composition of claim 1 wherein n is about 1-3.
Claim 14
Dependent Claim 10 words
The liquid composition of claim 1 wherein X is halide.
Claim 15
Dependent Claim 57 words
The liquid composition of claim 1 wherein R is a monovalent alkyl radical containing about 12-18 carbon atoms, R' is a monovalent alkyl radical containing about one carbon atom, Z is selected from the group consisting of alkyl radicals containing about one carbon atom and about 12-18 carbon atoms, n is about 1 and X is chloride.
Claim 16
Dependent Claim 29 words
The liquid composition of claim 1 wherein the softening agent is an emulsion of partially oxidized polyethylene and the molecular weight of the partially oxidized polyethylene is about 1400-5000.
Claim 17
Dependent Claim 18 words
The liquid composition of claim 15 wherein the molecular weight of the partially oxidized polyethylene is about 2500.
Claim 18
Dependent Claim 30 words
The liquid composition of claim 1 wherein the softening agent is (A), (B), or (D), or admixtures of two or more thereof, and the resulting liquid composition is freeze-thaw stable.
Claim 19
Dependent Claim 13 words
The liquid composition of claim 17 wherein the souring agent is glycolic acid.
Claim 20
Dependent Claim 24 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by diluting the liquid composition of claim 1 with water.
Claim 21
Dependent Claim 24 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by diluting the liquid composition of claim 5 with water.
Claim 22
Dependent Claim 24 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by diluting the liquid composition of claim 7 with water.
Claim 23
Dependent Claim 24 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by diluting the liquid composition of claim 8 with water.
Claim 24
Dependent Claim 24 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by diluting the liquid composition of claim 17 with water.
Claim 25
Dependent Claim 24 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by diluting the liquid composition of claim 18 with water.
Claim 26
Dependent Claim 324 words
A stable dry solid composition for souring laundered textile materials and imparting softness thereto comprising: I. about 5-50% by weight of a softening agent for textile materials selected from the group consisting of A. quaternized fatty amides corresponding to the following structural formulae ##STR4## wherein R is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 8-22 carbon atoms, R' is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 1-3 carbon atoms, Z is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 1-22 carbon atoms, n is about 1-6, X is an anion selected from the group consisting of halide, sulfate, phosphate, alkyl sulfates having about 1-3 carbon atoms in the alkyl group and alkyl phosphates having about 1-3 carbon atoms in the alkyl group, and Y is an integer having a numerical value equivalent to the valency of X; B. quaternized fatty amines corresponding to the following structural formula ##STR5## wherein R, R', X and Y are as defined in (A) above, and C. Fatty amphoteric compounds corresponding to the structural formula ##STR6## wherein R, R' and n are as defined in (A) above, the said amphoteric compounds having non-acidic isoelectric ranges, and Ii. about 95-50% by weight of an acidic souring agent for laundered textile materials, the souring agent being a dry solid water soluble organic carboxylic acid containing about 2-10 carbon atoms and having a primary ionization constant between 10.sup. -1 and 10.sup. -5 , the said ingredients I and II being present in amounts whereby laundered textile materials are effectively softened and simultaneously soured upon treatment with an aqueous solution for souring textile materials containing the said dry solid composition, and the said ingredients I and II being present in amounts whereby a stable solid composition is produced for souring laundered textile materials and imparting softness thereto.
Claim 27
Dependent Claim 324 words
A stable dry solid composition for souring laundered textile materials and imparting softness thereto comprising: I. about 5-50% by weight of a softening agent for textile materials selected from the group consisting of A. quaternized fatty amides corresponding to the following structural formulae ##STR4## wherein R is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 8-22 carbon atoms, R' is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 1-3 carbon atoms, Z is selected from the group consisting of monovalent alkyl radicals and sulfonated monovalent alkyl radicals containing about 1-22 carbon atoms, n is about 1-6, X is an anion selected from the group consisting of halide, sulfate, phosphate, alkyl sulfates having about 1-3 carbon atoms in the alkyl group and alkyl phosphates having about 1-3 carbon atoms in the alkyl group, and Y is an integer having a numerical value equivalent to the valency of X; B. quaternized fatty amines corresponding to the following structural formula ##STR5## wherein R, R', X and Y are as defined in (A) above, and C. Fatty amphoteric compounds corresponding to the structural formula ##STR6## wherein R, R' and n are as defined in (A) above, the said amphoteric compounds having non-acidic isoelectric ranges, and Ii. about 95-50% by weight of an acidic souring agent for laundered textile materials, the souring agent being a dry solid water soluble organic carboxylic acid containing about 2-10 carbon atoms and having a primary ionization constant between 10.sup. -1 and 10.sup. -5 , the said ingredients I and II being present in amounts whereby laundered textile materials are effectively softened and simultaneously soured upon treatment with an aqueous solution for souring textile materials containing the said dry solid composition, and the said ingredients I and II being present in amounts whereby a stable solid composition is produced for souring laundered textile materials and imparting softness thereto.
Claim 28
Dependent Claim 27 words
The dry solid composition of claim 25 wherein about 15-30% by weight of the softening agent and about 70-85% by weight of the souring agent are present.
Claim 29
Dependent Claim 16 words
The dry solid composition of claim 25 wherein the softening agent is a quaternized fatty amine.
Claim 30
Dependent Claim 33 words
The dry solid composition of claim 25 wherein the souring agent is selected from the group consisting of citric acid, fumaric acid, glycolic acid, maleic acid, malonic acid, oxalic acid and tartaric acid.
Claim 31
Dependent Claim 14 words
The dry solid composition of claim 25 wherein the souring agent is citric acid.
Claim 32
Dependent Claim 14 words
The dry solid composition of claim 25 wherein the souring agent is glycolic acid.
Claim 33
Dependent Claim 23 words
The dry solid composition of claim 25 wherein the softening agent is a quaternized fatty amine and the souring agent is citric acid.
Claim 34
Dependent Claim 23 words
The dry solid composition of claim 25 wherein the softening agent is a quaternized fatty amine and the souring agent is glycolic acid.
Claim 35
Dependent Claim 19 words
The dry solid composition of claim 25 wherein R is a monovalent alkyl radical containing about 12-18 carbon atoms.
Claim 36
Dependent Claim 18 words
The dry solid composition of claim 25 wherein R' is a monovalent alkyl radical containing one carbon atom.
Claim 37
Dependent Claim 29 words
The dry solid composition of claim 25 wherein Z is selected from the group consisting of monovalent alkyl radicals containing about one carbon atom and about 12-18 carbon atoms.
Claim 38
Dependent Claim 12 words
The dry solid composition of claim 25 wherein n is about 1-3.
Claim 39
Dependent Claim 11 words
The dry solid composition of claim 25 wherein X is halide.
Claim 40
Dependent Claim 58 words
The dry solid composition of claim 25 wherein R is a monovalent alkyl radical containing about 12-18 carbon atoms, R' is a monovalent alkyl radical containing about one carbon atom, Z is selected from the group consisting of alkyl radicals containing about one carbon atom and about 12-18 carbon atoms, n is about 1 and X is chloride.
Claim 41
Dependent Claim 25 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by admixing the dry solid composition of claim 25 with water.
Claim 42
Dependent Claim 25 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by admixing the dry solid composition of claim 27 with water.
Claim 43
Dependent Claim 25 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by admixing the dry solid composition of claim 29 with water.
Claim 44
Dependent Claim 25 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by admixing the dry solid composition of claim 30 with water.
Claim 45
Dependent Claim 25 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by admixing the dry solid composition of claim 31 with water.
Claim 46
Dependent Claim 25 words
A stable homogeneous aqueous stock solution for souring and softening laundered textile materials prepared by admixing the dry solid composition of claim 32 with water.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-05 1980-04-05 1980-10-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-05 1984-04-05 1984-10-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-05 1988-04-05 1988-10-05 $7700.00 Window Closed / Lapsed

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