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US3981852A Expired / Lapsed US ⏱️ 0.0 years remaining

Polytetrafluoroethylene molding powder

Assignee: EIDP Inc
•
Filing: 1974-06-17
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Granted: 1976-09-21
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Expires: 1994-06-17
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Abstract

Abstract Finely divided polytetrafluoroethylene molding powder is disclosed having a remarkable combination of high apparent density and high moldability, the latter being reflected as a small difference in specific gravity (ΔSG) of standard moldings molded at high and low preform pressures. For example, molding powders having an average particle diameter (d 50 ) of no greater than 60, a ΔSG 5 -1 of no greater than 30 and apparent density of at least 600 g/l are disclosed. These molding powders are obtained from unique process steps involving either the fine powder type of polytetrafluoroethylene or the granular type of polytetrafluoroethylene as the starting material. The fine powder type is compacted to a high degree, followed by partially decompacting the resultant compacted fine powder to the molding powder particle size desired. When the granular type is the starting material, this is comminuted to the molding powder particle size desired, followed by separating the molding powder into hard and soft material fractions, followed by re-grinding the relatively coarse, hard fraction by itself to an average particle size of at least as small as the original combined fractions. The resultant molding powder is useful in the manner of previous polytetrafluoroethylene molding powders with the advantage of requiring reduced mold height and molding pressure to achieve equivalent quality moldings.

Inventors

  • 👤 Carl Harding Manwiller
  • 👤 Carleton Angelo Sperati

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 10:15
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/12; C08J2327/00; C08J2327/02; C08J2327/12; C08J2327/18

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 130 words
Polytetrafluoroethylene molding powder having a. a specific surface area of at least 1.5 m 2 /g, b. an average particle diameter of less than 100 microns; c. an apparent density of at least 500 g/l, with the proviso that the apparent density is at least as great as the value calculated from the equation apparent density = 500 g/l + 3.00 (ΔSG.sub.5.sub.-1) wherein ΔSG 5 -1 is 1000 times the difference in specific gravities of sintered moldings made at preform pressures of 1000 psi and 5000 psi wherein said ΔSG 5 -1 is no greater than 75, d. a tensile strength of at least 245 kg/cm 2 at 70 kg/cm 2 preform pressure, e. a porosity of less than 0.20, and f. a ΔSG 5 -1 no greater than 75.
Claim 2
Dependent Claim 130 words
Polytetrafluoroethylene molding powder having a. a specific surface area of at least 1.5 m 2 /g, b. an average particle diameter of less than 100 microns; c. an apparent density of at least 500 g/l, with the proviso that the apparent density is at least as great as the value calculated from the equation apparent density = 500 g/l + 3.00 (ΔSG.sub.5.sub.-1) wherein ΔSG 5 -1 is 1000 times the difference in specific gravities of sintered moldings made at preform pressures of 1000 psi and 5000 psi wherein said ΔSG 5 -1 is no greater than 75, d. a tensile strength of at least 245 kg/cm 2 at 70 kg/cm 2 preform pressure, e. a porosity of less than 0.20, and f. a ΔSG 5 -1 no greater than 75.
Claim 3
Dependent Claim 13 words
The polytetrafluoroethylene molding powder of claim 1 wherein ΔSG 5 -1 is zero.
Claim 4
Dependent Claim 16 words
The polytetrafluoroethylene molding powder of claim 1 wherein ΔSG 5 -1 is no greater than 30.
Claim 5
Dependent Claim 16 words
The polytetrafluoroethylene molding powder of claim 3 wherein the apparent density is at least 600 g/l.
Claim 6
Dependent Claim 16 words
The polytetrafluoroethylene molding powder of claim 1 wherein said apparent density is at least 600 g/l.
Claim 7
Dependent Claim 30 words
The polytetrafluoroethylene molding powder of claim 5 wherein said apparent density is at least as great as the value calculated from equation Apparent density ≧ 600 g/l + 3.00 (ΔSG.sub.5.sub.-1)
Claim 8
Dependent Claim 24 words
The polytetrafluoroethylene molding powder of claim 1 having a porosity of no greater than 0.20 and an (S) absolute value of less than 0.80.
Claim 9
Dependent Claim 16 words
The polytetrafluoroethylene molding powder of claim 1 having a % S (1000) of less than 8.0.
Claim 10
Dependent Claim 20 words
The polytetrafluoroethylene molding powder of claim 1 wherein the individual particles thereof exhibit birefringence when viewed microsopically with polarized light.
Claim 11
Dependent Claim 24 words
The polytetrafluoroethylene molding powder of claim 1 in the form of free-flowing agglomerates having an average agglomerate diameter of from 300 to 1000 microns.
Claim 12
Dependent Claim 17 words
The polytetrafluoroethylene molding powder of claim 1 having an average particle diameter of at least 10 microns.
Claim 13
Dependent Claim 15 words
The polytetrafluoroethylene molding powder of claim 11 having ΔSG 5 -1 of less than 15.
Claim 14
Dependent Claim 17 words
The polytetrafluoroethylene molding powder of claim 12 having an average particle diameter of 10 to 20 microns.

References Cited (Backward Citations)

US2573639A Cited
US3087921A Cited
US3674762A Cited
US3690569A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-09-21 1980-03-22 1980-09-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-09-21 1984-03-22 1984-09-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-09-21 1988-03-22 1988-09-21 $7700.00 Window Closed / Lapsed

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