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US3979535A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the spray application of aqueous paints by controlling the temperature of the air in the paint spray zone

Assignee: EIDP Inc
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Filing: 1975-07-30
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Granted: 1976-09-07
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Expires: 1995-07-30
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Abstract

Abstract The process is directed towards an improvement in the application of an aqueous paint to a substrate by air spraying the paint with a spray gun utilizing atomizing air at a flow rate of about 5-40 cubic feet per minute at an air pressure of 30-95 pounds per square inch at the spray gun and paint flow rate of about 5-30 ounces per minute, wherein the air atomized paint is applied to the substrate and baked to form a uniform finish on the substrate; The improvement that is used with this process comprises spraying atomized paint in an atmosphere that is controlled at a temperature of about 15°-40°C. and at such a relative humidity that the air has a drive force value with the range of 0.002 to 0.004 humidity units (pounds of water/pound of dry air) which is constantly maintained at a set value within this range to initially dry the paint at a uniform rate to form a finish that has a uniform appearance after being baked; The improved process is particularly useful for applying an exterior aqueous finish on automobile and truck bodies to form a high quality finish of uniform color, hue and appearance.

Inventors

  • 👤 Tirunillayi S. Govindan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 09:03
CPC Classifications
B; B05; B05D; B05D1/00; B05D1/02; B05B; B05B16/00; B05B16/60; B05D2401/00; B05D2401/20; B05D2502/00; B05D3/00; B05D3/04; B05D3/0486

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 249 words
In a process for applying an aqueous dispersion or solution paint to a substrate by air-spraying the paint with a spray gun utilizing atomizing air at a flow rate of 5-40 cubic feet per minute and at an air pressure of 30-95 pounds per square inch at the spray gun and a paint flow rate of 5-30 ounces per minute which forms an air atomized paint spray which is applied to the substrate and baked at about 75° to 200°C. to form a uniform finish on the substrate, the improvement in use therewith comprising: spraying the atomized paint in an air atmosphere that is controlled by the addition of steam or water at a temperature of 15°-40°C. and at such a relative humidity that the air has a driving force value in the range of 0.002 to 0.004 humidity units which is constantly maintained at a set value within this range, thereby providing an atmosphere for initally drying the aqueous paint during the spraying at a uniform rate to provide a finish that has a uniform appearance after being baked; wherein the paint is an aqueous thermosetting acrylic enamel in which the film-forming constituents of the enamel comprise: 1. an acrylic polymer of styrene, methyl methacrylate or a mixture thereof, an alkyl acrylate or an alkyl methacrylate having 2-12 carbon atoms in the alkyl group, optionally a hydroxy alkyl acrylate or a hydroxy alkyl methacrylate and an α,β-unsaturated carboxylic acid; and 2. a water soluble or water-dispersible cross-linking agent.
Claim 2
Dependent Claim 249 words
In a process for applying an aqueous dispersion or solution paint to a substrate by air-spraying the paint with a spray gun utilizing atomizing air at a flow rate of 5-40 cubic feet per minute and at an air pressure of 30-95 pounds per square inch at the spray gun and a paint flow rate of 5-30 ounces per minute which forms an air atomized paint spray which is applied to the substrate and baked at about 75° to 200°C. to form a uniform finish on the substrate, the improvement in use therewith comprising: spraying the atomized paint in an air atmosphere that is controlled by the addition of steam or water at a temperature of 15°-40°C. and at such a relative humidity that the air has a driving force value in the range of 0.002 to 0.004 humidity units which is constantly maintained at a set value within this range, thereby providing an atmosphere for initally drying the aqueous paint during the spraying at a uniform rate to provide a finish that has a uniform appearance after being baked; wherein the paint is an aqueous thermosetting acrylic enamel in which the film-forming constituents of the enamel comprise: 1. an acrylic polymer of styrene, methyl methacrylate or a mixture thereof, an alkyl acrylate or an alkyl methacrylate having 2-12 carbon atoms in the alkyl group, optionally a hydroxy alkyl acrylate or a hydroxy alkyl methacrylate and an α,β-unsaturated carboxylic acid; and 2. a water soluble or water-dispersible cross-linking agent.
Claim 3
Dependent Claim 18 words
The process of claim 1 in which the air has a driving force value of 0.003 humidity units.
Claim 4
Dependent Claim 210 words
The process of claim 1 in which the acrylic enamel comprises 10 to 60% by weight of film-forming constituents and correspondingly 90 -40% by weight of water and up to 20% by weight of a solvent for the film-forming constituents; wherein the film-forming constituents consist essentially of: 1. 60-90% by weight, based on the weight of the film-forming constituents, of an acrylic polymer that consists essentially of: a. 20-60% by weight, based on the weight of the acrylic polymer, of a hard constituent which is either methyl methacrylate, styrene, or a blend of methyl methacrylate and styrene; b. 20-40% by weight, based on the weight of the acrylic polymer, of a soft constituent that is either an alkyl acrylate having 2-12 carbon atoms in the alkyl group or an alkyl methacrylate having 4-12 carbon atoms in the alkyl group or a mixture of the above acrylate and methacrylate; c. 4 to 20% by weight, based on the weight of the acrylic polymer, of a hydroxy containing constituent which is either a hydroxy alkyl methacrylate, or a hydroxy alkyl acrylate, or a mixture thereof in which the alkyl groups have 2-4 carbon atoms; d. 4-20% by weight, based on the weight of the acrylic polymer, of an α,β-ethylenically unsaturated carboxylic acid;
Claim 5
Dependent Claim 40 words
10-40% by weight, based on the weight of the film-forming constituents, of a water-dispersible alkylated melamine formaldehyde resin having 1-4 carbon atoms in the alkyl groups; and the composition contains sufficient water-soluble amine to provide a pH of about 6-10.
Claim 6
Dependent Claim 40 words
10-40% by weight, based on the weight of the film-forming constituents, of a water-dispersible alkylated melamine formaldehyde resin having 1-4 carbon atoms in the alkyl groups; and the composition contains sufficient water-soluble amine to provide a pH of about 6-10.
Claim 7
Dependent Claim 75 words
The process of claim 3 in which the acrylic polymer of the enamel consists essentially of 50-60% by weight of methyl methacrylate, 30-40% by weight of butyl acrylate, 5-10% by weight of hydroxyethyl acrylate, and 4-12% by weight of acrylic acid and the polymer has an acid number of about 35-100 and a carboxyl to hydroxyl ratio of about 1:0.3 to 1:1.5, then the acrylic polymer has a weight average molecular weight of about 10,000-50,000.
Claim 8
Dependent Claim 75 words
The process of claim 3 in which the acrylic polymer of the enamel consists essentially of 28-32% by weight of styrene, 22-26% by weight of methyl methacrylate, 30-35% by weight of butyl acrylate, 7-9% by weight of hydroxyethyl acrylate, 4-6% by weight of acrylic acid and has an acid number of about 30-50 and a carboxyl to hydroxyl ratio of 1:0.4 to 1:1.5 and the polymer has a weight average molecular weight of about 10,000-50,000.
Claim 9
Dependent Claim 16 words
The process of claim 1 in which the atomizing air is heated to 40°C. to 150°C.
Claim 10
Dependent Claim 15 words
The process of claim 1 in which the spray gun is a hand spray gun.
Claim 11
Dependent Claim 15 words
The process of claim 1 in which the spray gun is an automatic spray gun.
Claim 12
Dependent Claim 11 words
The process of claim 1 in which the substrate is steel.
Claim 13
Dependent Claim 18 words
The process of claim 1 in which the substrate is a steel substrate coated with a primer composition.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-09-07 1980-03-08 1980-09-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-09-07 1984-03-08 1984-09-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-09-07 1988-03-08 1988-09-07 $7700.00 Window Closed / Lapsed

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