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US3979267A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrolytic method

Assignee: Individual
•
Filing: 1973-05-15
•
Granted: 1976-09-07
•
Expires: 1993-05-15
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Abstract

Abstract It has been known that metals of groups IV-B, V-B, and VI-B of the periodic table, namely chromium, hafnium, molybdenum, niobium, tantalum, titanium, tungsten, vanadium, and zirconium and alloys thereof can be electrodeposited as dense, structurally coherent plates from a solution of the refractory metal flouride in a molten alkali-fluoride mixture in which the concentration of oxygen is reduced to and maintained at a sufficiently low level. It is shown that niobium may be plated at a lower temperature and a higher rate when the oxygen concentration is reduced to lower levels than previously attainable. The concurrent steps of electrolysis to a carbon anode, and evacuation whereby gases released from the melt at the carbon are withdrawn are shown to prepare a salt bath, and to be usable concurrently with the plating of pure niobium at a cathode, the metal depleted from the melt being replenished from a body of niobium of lesser purity maintained at a potential intermediate the potentials of the carbon anode and the niobium cathode.

Inventors

  • 👤 Douglas W. Townsend

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 07:31
CPC Classifications
C; C25; C25D; C25D21/00; C25D21/04; C25D3/00; C25D3/66; C25D5/00; C25D5/003

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 100 words
For removing substantially all oxygen from a electrolytic melt consisting essentially of at least one fluoride selected from the group of alkali metal fluorides and alkaline earth metal fluorides, the process comprising the steps of: A. maintaining said melt above its melting temperature; B. maintaining the ambient pressure on said melt at less than one-third atmosphere; C. providing in said melt an anode comprised essentially of carbon, and D. maintaining a positive potential of about 1 to 3 volts on said anode relative to said melt sufficient to remove oxygen but less than the potential at which anode effect occurs.
Claim 2
Dependent Claim 100 words
For removing substantially all oxygen from a electrolytic melt consisting essentially of at least one fluoride selected from the group of alkali metal fluorides and alkaline earth metal fluorides, the process comprising the steps of: A. maintaining said melt above its melting temperature; B. maintaining the ambient pressure on said melt at less than one-third atmosphere; C. providing in said melt an anode comprised essentially of carbon, and D. maintaining a positive potential of about 1 to 3 volts on said anode relative to said melt sufficient to remove oxygen but less than the potential at which anode effect occurs.
Claim 3
Dependent Claim 122 words
The process as defined by claim 1 E. wherein said melt includes a substantial concentration of cations of metals from the group consisting of the metals of Groups IV-B, V-B, and VI-B of the periodic table, with the further steps of F. providing in said melt a cathode, and G. applying to said cathode a potential relative to said melt sufficient to cause to be deposited on said cathode a metal from the group consisting of (I) metals selected from groups IV-B, V-B, VI-B of the periodic table; (II) alloys of at least two metals of (I) and (III) alloys and compounds of at least one metal of (I) with other metals which form a structurally coherent deposit of metals of (I).
Claim 4
Dependent Claim 16 words
The process as defined by claim 2 H. said pressure being less than one mm. Hg.
Claim 5
Dependent Claim 24 words
The process as defined by claim 3 I. the temperature at which said melt is maintained being at least 10°C above its melting point.
Claim 6
Dependent Claim 28 words
The process as defined by claim 2 H. where in said cations are of the group consisting of titanium, niobium, tungsten, chromium, hafnium, molybdenum, tantalum, vanadium, and zirconium.
Claim 7
Dependent Claim 21 words
The process as defined by claim 2 H. wherein said cations are of the group consisting of tantalum, niobium, and tungsten.
Claim 8
Dependent Claim 14 words
The process as defined by claim 2 H. wherein said cations are of niobium.
Claim 9
Dependent Claim 26 words
The process as defined by claim 2 H. wherein said cations are of the group consisting of niobium, tungsten, chromium, hafnium, molybdenum, tantalum, vanadium, and zirconium.
Claim 10
Dependent Claim 20 words
The process as defined by claim 2 H. the temperature at which said melt is maintained being less than 600°C.
Claim 11
Dependent Claim 27 words
The process as defined by claim 1 wherein said melt consists of at least one fluoride from the group of alkali metal fluorides and alkaline-earth metal fluorides.
Claim 12
Dependent Claim 23 words
The process as defined by claim 1 wherein said melt consists of at least one fluoride from the group of alkali metal fluorides.

References Cited (Backward Citations)

US2786809A Cited
US3024176A Cited
US3479158A Cited
US3489659A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-09-07 1980-03-08 1980-09-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-09-07 1984-03-08 1984-09-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-09-07 1988-03-08 1988-09-07 $7700.00 Window Closed / Lapsed

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