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US3978150A Expired / Lapsed US ⏱️ 0.0 years remaining

Continuous paraffin dehydrogenation process

Assignee: Universal Oil Products Co
•
Filing: 1975-03-03
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Granted: 1976-08-31
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Expires: 1995-03-03
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Abstract

Abstract Continuous operation and a high rate of conversion are obtained in a normal paraffin dehydrogenation process through the use of a moving bed non-fluidized reaction zone operated at a subatmospheric pressure. Quantities of catalyst are periodically removed from the reaction zone, passed through regeneration and reducing zones operated at superatmospheric pressures and returned to the top of a reaction zone.

Inventors

  • 👤 Frederick G. McWilliams, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 16:51
CPC Classifications
C; C07; C07C; C07C5/00; C07C5/32; C07C5/327; C07C5/333; B; B01; B01J; B01J8/00; B01J8/08; B01J8/12; Y; Y10; Y10S; Y10S585/00; Y10S585/8995; Y10S585/906

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 177 words
A catalytic dehydrogenation process which comprises the steps of: a. passing a feed stream comprising saturated normal paraffins into a reaction zone maintained at dehydrogenation conditions including a temperature in excess of 1000°F. and a subatmospheric pressure, contacting the feed stream with a bed of dehydrogenation catalyst and effecting the formation of a reaction zone effluent stream comprising olefinic hydrocarbons and hydrogen; b. intermittently removing a quantity of used catalyst from the bottom of the bed of dehydrogenation catalyst, and intermittently adding a quantity of active catalyst to the top of the catalyst bed, and effecting a gradual movement of catalyst downward through the reaction zone; c. passing catalyst removed from the reaction zone into a regeneration zone operated at regeneration conditions which include the presence of an oxygen-containing gas stream and a superatmospheric pressure and effecting the production of regenerated catalyst; and, d. passing regenerated catalyst into a reducing zone operated at reduction conditions which include the presence of a reducing gas and effecting the production of active catalyst which is added to the catalyst bed.
Claim 2
Dependent Claim 177 words
A catalytic dehydrogenation process which comprises the steps of: a. passing a feed stream comprising saturated normal paraffins into a reaction zone maintained at dehydrogenation conditions including a temperature in excess of 1000°F. and a subatmospheric pressure, contacting the feed stream with a bed of dehydrogenation catalyst and effecting the formation of a reaction zone effluent stream comprising olefinic hydrocarbons and hydrogen; b. intermittently removing a quantity of used catalyst from the bottom of the bed of dehydrogenation catalyst, and intermittently adding a quantity of active catalyst to the top of the catalyst bed, and effecting a gradual movement of catalyst downward through the reaction zone; c. passing catalyst removed from the reaction zone into a regeneration zone operated at regeneration conditions which include the presence of an oxygen-containing gas stream and a superatmospheric pressure and effecting the production of regenerated catalyst; and, d. passing regenerated catalyst into a reducing zone operated at reduction conditions which include the presence of a reducing gas and effecting the production of active catalyst which is added to the catalyst bed.
Claim 3
Dependent Claim 20 words
The process of claim 1 further characterized in that normal paraffins have from 2 to 6 carbon atoms per molecule.
Claim 4
Dependent Claim 87 words
The process of claim 1 further characterized in that the reaction zone is maintained at a subatmospheric pressure through the use of a fluid jet ejector, which ejector is operated with a temperature and a pressure differential which produces an expanded driving fluid having a lower temperature than the reaction zone effluent stream as it leaves the reaction zone, and admixing the expanded driving fluid with the effluent stream and effecting a reduction in the temperature of the effluent stream by passage through the fluid jet ejector.
Claim 5
Dependent Claim 22 words
The process of claim 3 further characterized in that the driving fluid used in the ejector comprises hydrogen and a vaporized hydrocarbon.
Claim 6
Dependent Claim 31 words
The process of claim 4 further characterized in that the driving fluid is derived from a stream removed from a fractionation zone in which the reaction zone effluent stream is separated.

References Cited (Backward Citations)

US3754051A Cited
US3785963A Cited
US3838038A Cited
US3838039A Cited
US3795607A Cited
US3799866A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-31 1980-03-01 1980-08-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-31 1984-03-01 1984-08-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-31 1988-03-01 1988-08-31 $7700.00 Window Closed / Lapsed

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