US3977900A
Expired / Lapsed
US
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Thermally activated electrochemical cell including an alkali metal salt solvate electrolyte
Assignee: Michigan Technological University
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Filing: 1975-06-05
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Granted: 1976-08-31
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Expires: 1995-06-05
Abstract
Abstract The thermally activated electrochemical cell includes a cathode, an anode and a solid electrolyte which is non-conductive at ambient temperatures and is capable of becoming an ionically conductive liquid upon being heated above its melting point. The electrolyte is an organic solvent solvate of certain alkali metal salts which is formed by coordinating the salt with a polar organic solvent preferably having a Gutmann donor number greater than 18 and a dielectric constant of at least 20.
Inventors
- 👤 Dean C. Luehrs
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 06:26
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/14; H01M6/16; H01M6/162; H01M6/30; H01M6/36
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
135 words
A thermally activated electrochemical cell including a cathode, an anode, and an electrolyte which is disposed between said cathode and anode, is an electrically non-conductive solid at ambient temperatures and is capable of becoming an ionically conductive liquid upon being heated above its melting point, said electrolyte comprising a crystalline coordination compound formed by the solvation of an alkali metal salt selected from the group consisting of the bromides, iodides, thiocyanates, perchlorates, chlorates, nitrates, acetates, tetrafluoroborates, hexafluorophosphates, and hexafluoroantimonates of lithium and sodium, lithium chloride, potassium iodide, and potassium thiocyanate with a polar organic solvent selected from the group consisting of hexamethylphosphoramide, formamide, N-methylformamide, dimethylformamide, N-ethylformamide, diethylformamide, tetramethylurea, trimethylphosphate, triethylphosphate, tripropylphosphate, tributylphosphate, acetamide, dimethylacetamide, diethylacetamide, acetonitrile, acetone, pyridine, dimethylsulfoxide, diethylsulfoxide, dipropylsulfoxide, ethylene glycol, propylene carbonate, and lower alkyl alcohols containing 1 to 4 carbon atoms.
Claim 2
Dependent Claim
135 words
A thermally activated electrochemical cell including a cathode, an anode, and an electrolyte which is disposed between said cathode and anode, is an electrically non-conductive solid at ambient temperatures and is capable of becoming an ionically conductive liquid upon being heated above its melting point, said electrolyte comprising a crystalline coordination compound formed by the solvation of an alkali metal salt selected from the group consisting of the bromides, iodides, thiocyanates, perchlorates, chlorates, nitrates, acetates, tetrafluoroborates, hexafluorophosphates, and hexafluoroantimonates of lithium and sodium, lithium chloride, potassium iodide, and potassium thiocyanate with a polar organic solvent selected from the group consisting of hexamethylphosphoramide, formamide, N-methylformamide, dimethylformamide, N-ethylformamide, diethylformamide, tetramethylurea, trimethylphosphate, triethylphosphate, tripropylphosphate, tributylphosphate, acetamide, dimethylacetamide, diethylacetamide, acetonitrile, acetone, pyridine, dimethylsulfoxide, diethylsulfoxide, dipropylsulfoxide, ethylene glycol, propylene carbonate, and lower alkyl alcohols containing 1 to 4 carbon atoms.
Claim 3
Dependent Claim
28 words
A thermally activated electrochemical cell according to claim 1 wherein said solvent has a Gutmann donor number greater than 18 and a dielectric constant of at least 20.
Claim 4
Dependent Claim
20 words
A thermally activated electrochemical cell according to claim 1 wherein said alkali metal salt is lithium chloride or lithium perchlorate.
Claim 5
Dependent Claim
24 words
A thermally activated electrochemical cell according to claim 1 wherein said solvent is selected from the group consisting of dimethylsulfoxide, dimethylacetamide, hexamethylphosphoramide and dimethylformamide.
Claim 6
Dependent Claim
35 words
A thermally activated electrochemical cell according to claim 1 wherein said alkali metal salt is lithium chloride or lithium perchlorate and said solvent is selected from the group consisting of dimethylsulfoxide, dimethylacetamide, hexamethylphosphoramide and dimethylformamide.
Claim 7
Dependent Claim
17 words
A thermally activated electrochemical cell according to claim 5 wherein said alkali metal salt is lithium chloride.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-31 | 1980-03-01 | 1980-08-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-31 | 1984-03-01 | 1984-08-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-31 | 1988-03-01 | 1988-08-31 | $7700.00 | Window Closed / Lapsed |