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US3976649A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of easily dispersible, high tinctorial strength perylene-3,4,9,10-tetracarboxylic acid diimides

Assignee: BASF SE
•
Filing: 1974-04-01
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Granted: 1976-08-24
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Expires: 1994-04-01
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Abstract

Abstract High tinctorial strength, easily dispersible perylene-3,4,9,10-tetracarboximides and N,N'-dialkylperylene-3,4,9,10-tetracarboximides are produced by introducing a finely ground crude pigment whose primary particle size is not more than 0.05 micron into a primary aliphatic or aromatic amine, into a heterocyclic base, into an aliphatic carboxamide, into a mixture thereof, or into from 75 to 84% by weight sulfuric acid and converting it into pigmentary form at a temperature of from ambient temperature to 160°C. The products are easily dispersible pigments of high tinctorial strength.

Inventors

  • 👤 Wolfgang Fabian
  • 👤 Klaus Schrempp

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 19:05
CPC Classifications
C; C09; C09B; C09B68/00; C09B68/20; C09B68/24; C09B5/00; C09B5/62; C09B67/00; C09B67/0001; C09B67/0096; C09B68/40; C09B68/44; C09B68/443

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 134 words
In a process for the production in pigmentary form of perylene-3,4,9,10-tetracarboxylic acid diimide or the corresponding N-alkyl diimides of one to four carbon atoms in each alkyl, the improvement for producing a pigment which has high tinctorial strength and is easily dispersible which comprises the steps of: grinding the crude pigment until the mean primary particle size is not more than 0.05 micron; introducing the ground material into a treatment medium which consists essentially of an aliphatic primary amine selected from the group consisting of ethylamine, n-propylamine, n-butylamine, n-hexylamine, ethanolamine, 1-aminopropanol, 3-aminopropanol, β-methoxyethylamine, β-ethoxyethylamine, β-butoxyethylamine, γ-methoxypropylamine, γ-ethoxypropylamine, γ-butoxypropylamine or a mixture of the same; mixing the ground pigment in said medium at a temperature of from ambient temperature to 160°C until the pigment has recrystallized; and then separating the pigment from the treatment medium.
Claim 2
Dependent Claim 134 words
In a process for the production in pigmentary form of perylene-3,4,9,10-tetracarboxylic acid diimide or the corresponding N-alkyl diimides of one to four carbon atoms in each alkyl, the improvement for producing a pigment which has high tinctorial strength and is easily dispersible which comprises the steps of: grinding the crude pigment until the mean primary particle size is not more than 0.05 micron; introducing the ground material into a treatment medium which consists essentially of an aliphatic primary amine selected from the group consisting of ethylamine, n-propylamine, n-butylamine, n-hexylamine, ethanolamine, 1-aminopropanol, 3-aminopropanol, β-methoxyethylamine, β-ethoxyethylamine, β-butoxyethylamine, γ-methoxypropylamine, γ-ethoxypropylamine, γ-butoxypropylamine or a mixture of the same; mixing the ground pigment in said medium at a temperature of from ambient temperature to 160°C until the pigment has recrystallized; and then separating the pigment from the treatment medium.
Claim 3
Dependent Claim 18 words
A process as claimed in claim 1 wherein the treatment is carried out at from 50° to 150°C.
Claim 4
Dependent Claim 25 words
A process as claimed in claim 1 wherein the weight of treatment medium used is from 0.5 to 5 times the weight of crude pigment.
Claim 5
Dependent Claim 16 words
A process as claimed in claim 1 wherein the recrystallized pigment is isolated by freeze drying.
Claim 6
Dependent Claim 17 words
A process as claimed in claim 1 wherein perylene-3,4,9,10-tetracarboxylic acid diimide is used as the crude pigment.
Claim 7
Dependent Claim 17 words
A process as claimed in claim 1 wherein N,N'-dimethylperylene-3,4,9,10-tetracarboxylic acid diimide is used as the crude pigment.

References Cited (Backward Citations)

US3043843A Cited
US3615800A Cited
US3752686A Cited
US3842084A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-24 1980-02-23 1980-08-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-24 1984-02-23 1984-08-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-24 1988-02-23 1988-08-24 $7700.00 Window Closed / Lapsed

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