US3976598A
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Zeolite synthesis
Assignee: Mobil Oil AS
•
Filing: 1974-03-29
•
Granted: 1976-08-24
•
Expires: 1994-03-29
Abstract
Abstract Process for synthesizing crystalline aluminosilicates of the molecular sieve type wherein smectite which has undergone fusion with sodium chloride is employed as a source of silica and alumina.
Inventors
- 👤 John C. Daviditz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 11:15
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/084; B01J29/40; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/42; Y; Y10; Y10S; Y10S423/00; Y10S423/21; Y10S423/22
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
242 words
In a process for synthesizing a crystalline molecular sieve type aluminosilicate-containing product comprising zeolite Y or zeolite ZSM-5 by preparation of a reaction mixture containing, for zeolite Y, sodium oxide, silica, alumina and water and having a composition falling within one of the following ranges: Na.sub.2 O/SiO.sub.2
SiO.sub.2 /Al.sub.2 O.sub.3
H.sub.2 O/Na.sub.2 O
______________________________________
Range 1 0.20 to 0.40 10 to 40 25 to 60
Range 2 0.41 to 0.60 10 to 30 20 to 60
Range 3 0.61 to 0.80 7 to 30 20 to 60
Range 4 0.6 to 1.0 8 to 30 12 to 90
Range 5 1.5 to 1.7 10 to 30 20 to 90
Range 6 1.9 to 2.1 about 10 40 to 90
Range 7 0.70 to 0.90 10 to 25 12 to 90
Range 8 0.28 to 0.30 8 to 10 30 to 50
______________________________________ and, for zeolite ZSM-5, a tetrapropyl ammonium compound, sodium oxide, silica, alumina and water and having a composition falling within the following ranges: Particularly
Broad Preferred Preferred
______________________________________
OH.sup.-/SiO.sub.2
0.07-1.0 0.1-0.8 0.2-0.75
R.sub.4 N.sup.+/(R.sub.4 N.sup.+ + Na.sup.+)
0.2-0.95 0.3-0.9 0.4-0.9
H.sub.2 O/OH.sup.-
10-300 10-300 10-300
SiO.sub.2 /Al.sub.2 O.sub.3
5-100 10-60 10-40
______________________________________ where R is propyl, maintaining the mixture at an elevated temperature until said product is formed, separating and recovering said product; the improvement which comprises utilizing as the principal source of silica and alumina in said reaction mixture a smectite clay which has undergone fusion with sodium chloride.
Claim 2
Dependent Claim
242 words
In a process for synthesizing a crystalline molecular sieve type aluminosilicate-containing product comprising zeolite Y or zeolite ZSM-5 by preparation of a reaction mixture containing, for zeolite Y, sodium oxide, silica, alumina and water and having a composition falling within one of the following ranges: Na.sub.2 O/SiO.sub.2
SiO.sub.2 /Al.sub.2 O.sub.3
H.sub.2 O/Na.sub.2 O
______________________________________
Range 1 0.20 to 0.40 10 to 40 25 to 60
Range 2 0.41 to 0.60 10 to 30 20 to 60
Range 3 0.61 to 0.80 7 to 30 20 to 60
Range 4 0.6 to 1.0 8 to 30 12 to 90
Range 5 1.5 to 1.7 10 to 30 20 to 90
Range 6 1.9 to 2.1 about 10 40 to 90
Range 7 0.70 to 0.90 10 to 25 12 to 90
Range 8 0.28 to 0.30 8 to 10 30 to 50
______________________________________ and, for zeolite ZSM-5, a tetrapropyl ammonium compound, sodium oxide, silica, alumina and water and having a composition falling within the following ranges: Particularly
Broad Preferred Preferred
______________________________________
OH.sup.-/SiO.sub.2
0.07-1.0 0.1-0.8 0.2-0.75
R.sub.4 N.sup.+/(R.sub.4 N.sup.+ + Na.sup.+)
0.2-0.95 0.3-0.9 0.4-0.9
H.sub.2 O/OH.sup.-
10-300 10-300 10-300
SiO.sub.2 /Al.sub.2 O.sub.3
5-100 10-60 10-40
______________________________________ where R is propyl, maintaining the mixture at an elevated temperature until said product is formed, separating and recovering said product; the improvement which comprises utilizing as the principal source of silica and alumina in said reaction mixture a smectite clay which has undergone fusion with sodium chloride.
Claim 3
Dependent Claim
16 words
The process of claim 1 wherein the crystalline aluminosilicate molecular sieve type zeolite is zeolite Y.
Claim 4
Dependent Claim
16 words
The process of claim 1 wherein the crystalline aluminosilicate molecular sieve type zeolite is zeolite ZSM-5.
Claim 5
Dependent Claim
34 words
The process of claim 1 wherein the smectite clay and sodium chloride are present in a weight ratio of approximately 80 to 99.5 percent smectite clay and approximately 0.5 to 20 percent sodium chloride.
Claim 6
Dependent Claim
22 words
The process of claim 1 wherein said fusion is carried out at a temperature within the approximate range of 500° to 1000°C.
Claim 7
Dependent Claim
28 words
The process of claim 1 wherein the crystalline aluminosilicate molecular sieve type product is contained in a matrix derived from said smectite clay which has undergone said fusion.
Claim 8
Dependent Claim
30 words
The process of claim 1 wherein the crystalline aluminosilicate molecular sieve type product is zeolite Y contained in a matrix derived from said smectite clay which has undergone said fusion.
Claim 9
Dependent Claim
27 words
The process of claim 1 wherein the crystalline aluminosilicate product is zeolite ZSM-5 contained in a matrix derived from said smectite clay which has undergone said fusion.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-24 | 1980-02-23 | 1980-08-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-24 | 1984-02-23 | 1984-08-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-24 | 1988-02-23 | 1988-08-24 | $7700.00 | Window Closed / Lapsed |