← Back to Patent Explorer
US3976581A Expired / Lapsed US ⏱️ 0.0 years remaining

Surface treating compositions containing ammonioamidate compounds

Assignee: Procter and Gamble Co
•
Filing: 1973-06-28
•
Granted: 1976-08-24
•
Expires: 1993-06-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Surface-treating compositions containing ammonioamidate surface-active compounds able to exist in either cationic or zwitterionic form are disclosed. The compositions which contain a buffering agent to control pH and the cationic or zwitterionic character of the ammonioamidates are effective in the treatment of fabric or hard surfaces. Hair treating compositions and processes are disclosed. Methods of treating fabric and hard surfaces to provide fabric softening and soil-release properties are also disclosed.

Inventors

  • 👤 Terence James Rose

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 14:49
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/416; A61K8/42; A61Q; A61Q5/00; A61Q5/12; C; C11; C11D; C11D1/00; C11D1/88; C11D1/883; D; D06; D06M; D06M13/00; D06M13/322; D06M13/46; D06M13/463

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 254 words
A surface-treating composition suitable for hair and fabric softening consisting essentially of: a. a substituted ammonioamidate having the formula R.sub.1 CO N.sup.- N.sup.+ R.sub.2 R.sub.3 R.sub.4 or a cationic adduct thereof having the formula R.sub.1 CO NH N R.sub.2 R.sub.3 R.sub.4 .sup.+ X.sup.- wherein X is an anion; R 1 is an alkyl, phenyl, or alkylphenyl group having 1 to 25 carbon atoms; each of R 2 and R 3 is a methyl, ethyl, hydroxymethyl, hydroxyethyl or cyanoethyl group; and R 4 is either an alkyl having 1 to 25 carbon atoms or: ##EQU1## wherein each of R 5 and R 6 is a hydrogen or an alkyl group with 1 to 4 carbon atoms, and R 7 is a group defined as R 1 , benzyl or hydrogen, provided that at least one of R 1 and R 4 contains an alkyl group with at least 8 carbon atoms, said compound having a pKa value of from about 5 to about 7; and b. a pH buffering compound selected from the group consisting of: i. the alkali metal acid salts of phosphoric acid, and the polyphosphoric acids; ii. the acids and corresponding alkali metal salts of weak organic acids, and; iii. boric acid and borates; or mixtures thereof in an amount sufficient to maintain the pH of a solution containing component (a) at a level of from about 0.001 to about 0.5 percent by weight at less than, equal to, or not greater than 2 pH units above the pKa of component (a).
Claim 2
Dependent Claim 254 words
A surface-treating composition suitable for hair and fabric softening consisting essentially of: a. a substituted ammonioamidate having the formula R.sub.1 CO N.sup.- N.sup.+ R.sub.2 R.sub.3 R.sub.4 or a cationic adduct thereof having the formula R.sub.1 CO NH N R.sub.2 R.sub.3 R.sub.4 .sup.+ X.sup.- wherein X is an anion; R 1 is an alkyl, phenyl, or alkylphenyl group having 1 to 25 carbon atoms; each of R 2 and R 3 is a methyl, ethyl, hydroxymethyl, hydroxyethyl or cyanoethyl group; and R 4 is either an alkyl having 1 to 25 carbon atoms or: ##EQU1## wherein each of R 5 and R 6 is a hydrogen or an alkyl group with 1 to 4 carbon atoms, and R 7 is a group defined as R 1 , benzyl or hydrogen, provided that at least one of R 1 and R 4 contains an alkyl group with at least 8 carbon atoms, said compound having a pKa value of from about 5 to about 7; and b. a pH buffering compound selected from the group consisting of: i. the alkali metal acid salts of phosphoric acid, and the polyphosphoric acids; ii. the acids and corresponding alkali metal salts of weak organic acids, and; iii. boric acid and borates; or mixtures thereof in an amount sufficient to maintain the pH of a solution containing component (a) at a level of from about 0.001 to about 0.5 percent by weight at less than, equal to, or not greater than 2 pH units above the pKa of component (a).
Claim 3
Dependent Claim 68 words
The composition of claim 1 wherein R 1 is an alkyl group having 9 to 21 carbon atoms or an alkyl phenyl group having 8 to 15 carbon atoms in the alkyl chain, and R 4 is an alkyl group having 1 to 4 carbon atoms, or ##STR6## wherein R 7 is an alkyl group having 1 to 4 carbon atoms, a phenyl or benzyl group or hydrogen.
Claim 4
Dependent Claim 16 words
The composition of claim 2 wherein R 1 is an alkyl group having 15-19 carbon atoms.
Claim 5
Dependent Claim 21 words
The composition of claim 3 wherein R 4 is methyl or ethyl or ##STR7## wherein R 7 is methyl or ethyl.
Claim 6
Dependent Claim 59 words
The composition of claim 1 wherein R 1 is an alkyl group having 1 to 4 carbon atoms or a phenyl group and R 4 is an alkyl group having 8-25 carbon atoms, or ##STR8## wherein R 7 is an alkyl group having 8-25 carbon atoms or an alkyl benzyl group having 8-15 carbon atoms in the alkyl chain.
Claim 7
Dependent Claim 31 words
The composition of claim 5 wherein the group R 4 is an alkyl group having 16-20 carbon atoms, or ##STR9## wherein R 7 is an alkyl group having 16-20 carbon atoms.
Claim 8
Dependent Claim 12 words
The composition of claim 6 wherein R 1 is methyl or ethyl.
Claim 9
Dependent Claim 19 words
The composition of claim 7 wherein each of R 2 and R 3 is a methyl or ethyl group.
Claim 10
Dependent Claim 18 words
The composition of claim 8 wherein R 5 and R 6 if present, are each a hydrogen atom.
Claim 11
Dependent Claim 26 words
The composition of claim 1 wherein said buffering compounds are selected from the group consisting of water-soluble citrates and borates, the corresponding acids and mixtures thereof.
Claim 12
Dependent Claim 18 words
The composition of claim 10 which which also contains one or more nonionic or zwitterionic surface active agents.
Claim 13
Dependent Claim 247 words
A fabric softening composition consisting essentially of: a. a substituted ammonioamidate having the formula R.sub.1 CO N.sup.- N.sup.+ R.sub.2 R.sub.3 R.sub.4 or a cationic adduct thereof having the formula R.sub.1 CO NH N R.sub.2 R.sub.3 R.sub.4 .sup.+ X.sup.- wherein X is an anion; R 1 is an alkyl, phenyl, or alkylphenyl group having 1 to 25 carbon atoms; each of R 2 and R 3 is a methyl, ethyl, hydroxymethyl, hydroxyethyl or cyanoethyl group; and R 4 is either an alkyl having 1 to 25 carbon atoms or: ##EQU2## wherein each of R 5 and R 6 is a hydrogen or an alkyl group with 1 to 4 carbon atoms, and R 7 is a group defined as R 1 , provided that at least one of R 1 and R 4 contains an alkyl group with at least 8 carbon atoms, said compound having a pKa value of from about 5 to about 7; and b. a pH buffering compound selected from the group consisting of the acids and corresponding alkali metal salts of citric acid, lactic acid, glycolic acid, malic acid, tartaric acid, acetic acid, capric acid, benzoic acid, and adipic acid; or mixtures thereof wherein the buffering compound is present in amount sufficient to maintain the pH of a solution containing component (a) at a level of from about 0.02 to about 0.2 percent by weight at less than, equal to, or not greater than 2 pH units above the pKa of component (a).
Claim 14
Dependent Claim 247 words
A fabric softening composition consisting essentially of: a. a substituted ammonioamidate having the formula R.sub.1 CO N.sup.- N.sup.+ R.sub.2 R.sub.3 R.sub.4 or a cationic adduct thereof having the formula R.sub.1 CO NH N R.sub.2 R.sub.3 R.sub.4 .sup.+ X.sup.- wherein X is an anion; R 1 is an alkyl, phenyl, or alkylphenyl group having 1 to 25 carbon atoms; each of R 2 and R 3 is a methyl, ethyl, hydroxymethyl, hydroxyethyl or cyanoethyl group; and R 4 is either an alkyl having 1 to 25 carbon atoms or: ##EQU2## wherein each of R 5 and R 6 is a hydrogen or an alkyl group with 1 to 4 carbon atoms, and R 7 is a group defined as R 1 , provided that at least one of R 1 and R 4 contains an alkyl group with at least 8 carbon atoms, said compound having a pKa value of from about 5 to about 7; and b. a pH buffering compound selected from the group consisting of the acids and corresponding alkali metal salts of citric acid, lactic acid, glycolic acid, malic acid, tartaric acid, acetic acid, capric acid, benzoic acid, and adipic acid; or mixtures thereof wherein the buffering compound is present in amount sufficient to maintain the pH of a solution containing component (a) at a level of from about 0.02 to about 0.2 percent by weight at less than, equal to, or not greater than 2 pH units above the pKa of component (a).

References Cited (Backward Citations)

GB1003926A Cited
US3410880A Cited
US3546115A Cited
US3649569A Cited
US3485806A Cited
US3697452A Cited
DE2055685A1 Cited
US3795611A Cited
DE2213556A1 Cited
US3897348A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-24 1980-02-23 1980-08-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-24 1984-02-23 1984-08-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-24 1988-02-23 1988-08-24 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag