US3975346A
Expired / Lapsed
US
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Boron-containing, quaternary ammonium salt-containing resin compositions
Assignee: PPG Industries Inc
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Filing: 1974-04-25
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Granted: 1976-08-17
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Expires: 1994-04-25
Abstract
Abstract Synthetic resins which are water-dispersible resins, containing boron and chemically-bound quaternary ammonium base salts, can be dissolved or dispersed in water to provide aqueous coating compositions. The resins are derived from epoxy group containing organic materials and are essentially epoxy group free. When dispersed or dissolved in water, the boron-containing, quaternary ammonium salt-containing resins can be applied to a wide variety of different substrates by electrodeposition, and will deposit on the cathode to provide coatings of unique properties.
Inventors
- 👤 Joseph F. Bosso
- 👤 Marco Wismer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 15:08
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/62; C08G59/64; C08G59/4007; C08G59/4078; C08G59/50; C08G59/52; C08G59/56; C08G59/58; C09; C09D; C09D5/00; C09D5/44; C09D5/4419; C09D5/443; C09D5/4434
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
166 words
An ungelled, water-dispersible composition suitable for use in electrodeposition comprising: A. an essentially epoxy group-free, quaternary ammonium salt-containing resin comprising the reaction product of: 1. an organic epoxide having a 1,2-epoxide equivalent of at least about 1, and 2. an amine acid salt, i. said amine acid salt reacted with said organic epoxide at a temperature of at least room temperature, said temperature being sufficient to form quaternary ammonium salt groups, ii. said amine acid salt reacted with said epoxide in an amount sufficient to form quaternary ammonium salt groups and an essentially epoxy group-free composition, this being accomplished by reacting at least a stoichiometric amount of the amine salt with the organic epoxide, or by post reacting the organic epoxide-amine salt reaction product to remove residual epoxy groups; and B. boron in the form of boric acid, a boron ester, or other compound of boron which forms boric acid in aqueous medium; said boron being present in an amount sufficient to harden an electrodeposited film.
Claim 2
Dependent Claim
166 words
An ungelled, water-dispersible composition suitable for use in electrodeposition comprising: A. an essentially epoxy group-free, quaternary ammonium salt-containing resin comprising the reaction product of: 1. an organic epoxide having a 1,2-epoxide equivalent of at least about 1, and 2. an amine acid salt, i. said amine acid salt reacted with said organic epoxide at a temperature of at least room temperature, said temperature being sufficient to form quaternary ammonium salt groups, ii. said amine acid salt reacted with said epoxide in an amount sufficient to form quaternary ammonium salt groups and an essentially epoxy group-free composition, this being accomplished by reacting at least a stoichiometric amount of the amine salt with the organic epoxide, or by post reacting the organic epoxide-amine salt reaction product to remove residual epoxy groups; and B. boron in the form of boric acid, a boron ester, or other compound of boron which forms boric acid in aqueous medium; said boron being present in an amount sufficient to harden an electrodeposited film.
Claim 3
Dependent Claim
31 words
The composition of claim 1 wherein said resin contains in the resin molecule at least about 0.05 percent by weight of chemically-bound nitrogen in the form of quaternary ammonium base salt.
Claim 4
Dependent Claim
29 words
The composition of claim 2, wherein said quaternary ammonium base salt is the salt of an acid having a dissociation constant greater than about 1 ×10 - 5 .
Claim 5
Dependent Claim
13 words
The composition of claim 3, wherein (B) is chemically-bound to the resin (A).
Claim 6
Dependent Claim
29 words
The composition of claim 3, wherein the resin contains from about 0.05 to about 16 percent by weight of chemically-bound nitrogen in the form of quaternary ammonium base salt.
Claim 7
Dependent Claim
16 words
The composition of claim 5, wherein the acid forming said salt is an organic carboxylic acid.
Claim 8
Dependent Claim
15 words
The composition of claim 3, wherein (B) is in physical admixture with the resin (A).
Claim 9
Dependent Claim
17 words
The composition of claim 3, wherein the acid salt is in the form of an internal Zwitterion.
Claim 10
Dependent Claim
16 words
The composition of claim 1, wherein said organic epoxide is a polyglycidal ether of a polyphenol.
Claim 11
Dependent Claim
130 words
An aqueous dispersion suitable for use in electrodeposition comprising: A. an essentially epoxy group-free, quaternary ammonium salt-containing resin comprising the ungelled reaction product of: 1. an organic epoxide having a 1,2-epoxide equivalent of at least about 1, and 2. an amine acid salt, i. said amine acid salt reacted with the organic epoxide at at least room temperature, said temperature being sufficient to form quaternary ammonium salt groups, ii. said amine acid salt reacted with said organic epoxide in an amount sufficient to form quaternary ammonium salt groups and an essentially epoxy group-free composition, this being accomplished by reacting at least a stoichiometric amount of amine salt with the organic epoxide, or by post reacting the organic epoxide-amine salt reaction product to remove residual epoxy groups; and B. boric acid.
Claim 12
Dependent Claim
130 words
An aqueous dispersion suitable for use in electrodeposition comprising: A. an essentially epoxy group-free, quaternary ammonium salt-containing resin comprising the ungelled reaction product of: 1. an organic epoxide having a 1,2-epoxide equivalent of at least about 1, and 2. an amine acid salt, i. said amine acid salt reacted with the organic epoxide at at least room temperature, said temperature being sufficient to form quaternary ammonium salt groups, ii. said amine acid salt reacted with said organic epoxide in an amount sufficient to form quaternary ammonium salt groups and an essentially epoxy group-free composition, this being accomplished by reacting at least a stoichiometric amount of amine salt with the organic epoxide, or by post reacting the organic epoxide-amine salt reaction product to remove residual epoxy groups; and B. boric acid.
Claim 13
Dependent Claim
32 words
The aqueous dispersion of claim 10, wherein said resin contains in the resin molecule at least about 0.05 percent by weight of chemically-bound nitrogen in the form of quaternary ammonium base salt.
Claim 14
Dependent Claim
31 words
The aqueous dispersion of claim 11, wherein said quaternary ammonium base salt is the salt of an acid having a dissociation constant greater than about 1 × 10 - 5 .
Claim 15
Dependent Claim
18 words
The aqueous dispersion of claim 12 wherein the acid salt is in the form of an internal Zwitterion.
Claim 16
Dependent Claim
30 words
The aqueous dispersion of claim 12, wherein the resin contains from about 0.05 to about 16 percent by weight of chemically-bound nitrogen in the form of quaternary ammonium base salt.
Claim 17
Dependent Claim
17 words
The aqueous dispersion of claim 14 wherein the acid forming said salt is an organic carboxylic acid.
Claim 18
Dependent Claim
17 words
The aqueous dispersion of claim 10, wherein said organic epoxide is a polyglycidyl ether of a polyphenol.
Claim 19
Dependent Claim
40 words
The ungelled, water-dispersible composition of claim 1 in which the amine acid salt is reacted with the organic epoxide at a temperature over the range of room temperature to 110°C., said temperature being sufficient to form quaternary ammonium salt groups.
Claim 20
Dependent Claim
23 words
The ungelled, water-dispersible composition of claim 1 in which the organic epoxide is reacted with at least a stoichiometric amount of amine salt.
Claim 21
Dependent Claim
39 words
The aqueous dispersion of claim 10 in which the amine acid salt is reacted with the organic epoxide at a temperature over the range of room temperature to 110°C., said temperature being sufficient to form quaternary ammonium salt groups.
Claim 22
Dependent Claim
22 words
The aqueous dispersion of claim 10 in which the organic epoxide is reacted with at least a stoichiometric amount of amine salt.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-17 | 1980-02-16 | 1980-08-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-17 | 1984-02-16 | 1984-08-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-17 | 1988-02-16 | 1988-08-17 | $7700.00 | Window Closed / Lapsed |