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US3974202A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of preparing arylacetic acid alkyl esters

Assignee: Dynamit Nobel AG
•
Filing: 1973-08-10
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Granted: 1976-08-10
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Expires: 1993-08-10
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Abstract

Abstract In a process of producing an alkyl ester of a substituted or unsubstituted arylacetic acid wherein a substituted or unsubstituted aromatic halogen methyl compound is reacted with carbon monoxide and an alcohol having an alkoxy group the same as that of said ester, the improvement which comprises carrying out said reaction in a basic reaction medium in the presence as catalyst of:

Inventors

  • 👤 Moustafa El-Chahawi
  • 👤 Hermann Richtzenhain

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 01:29
CPC Classifications
C; C07; C07C; C07C67/00; C07C67/36; C07C69/00; C07C69/612; C07C69/614

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 90 words
In a process of producing an alkyl ester of a substituted or unsubstituted arylacetic acid wherein a correspondingly substituted or unsubstituted benzyl halide is reacted with carbon monoxide and an alcohol having an alkoxy group the same as that of said ester, the improvement which comprises carrying out said reaction in a basic reaction medium at a temperature of about 10°-100°C, and a carbon monoxide pressure of about 0.1-25 atmospheres in the presence as catalyst of which is at least one of Co 2 (CO) 8 and Fe(CO) 5 .
Claim 2
Dependent Claim 90 words
In a process of producing an alkyl ester of a substituted or unsubstituted arylacetic acid wherein a correspondingly substituted or unsubstituted benzyl halide is reacted with carbon monoxide and an alcohol having an alkoxy group the same as that of said ester, the improvement which comprises carrying out said reaction in a basic reaction medium at a temperature of about 10°-100°C, and a carbon monoxide pressure of about 0.1-25 atmospheres in the presence as catalyst of which is at least one of Co 2 (CO) 8 and Fe(CO) 5 .
Claim 3
Dependent Claim 15 words
Process according to claim 1, wherein carbon monoxide is added in admixture with another gas.
Claim 4
Dependent Claim 15 words
Process according to claim 1, the metal carbonyl compound being Co 2 (CO) 8 .
Claim 5
Dependent Claim 13 words
Process according to claim 1, the metal carbonyl compound being Fe(CO) 5 .
Claim 6
Dependent Claim 12 words
Process according to claim 1, wherein the benzyl halide is benzyl chloride.
Claim 7
Dependent Claim 32 words
Process according to claim 1, wherein the benzylhalide is unsubstituted or substituted by chlorine, alkyl of 1-6 carbon atoms or alkoxy of 1 to 6 carbon atoms; or condensed with another ring.

References Cited (Backward Citations)

US2739169A Cited
US2542767A Cited
DE1914391A1 Cited
GB1264940A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-10 1980-02-09 1980-08-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-10 1984-02-09 1984-08-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-10 1988-02-09 1988-08-10 $7700.00 Window Closed / Lapsed

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